Preprints
https://doi.org/10.5194/gchron-2021-30
https://doi.org/10.5194/gchron-2021-30

  05 Nov 2021

05 Nov 2021

Review status: this preprint is currently under review for the journal GChron.

Technical note: Accelerator mass spectrometry of 10Be and 26Al at low nuclide concentrations

Klaus M. Wilcken1, Alexandru T. Codilean2,3, Réka-H. Fülöp1,2, Steven Kotevski1, Anna H. Rood4, Dylan H. Rood4, Alexander J. Seal4, and Krista Simon1 Klaus M. Wilcken et al.
  • 1Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights, NSW 2234, Australia
  • 2School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, NSW 2522, Australia
  • 3ARC Centre of Excellence for Australian Biodiversity and Heritage (CABAH), University of Wollongong, Wollongong, NSW 2522, Australia
  • 4Department of Earth Science and Engineering, Royal School of Mines, Imperial College London, London SW7 2AZ, UK

Abstract. Accelerator Mass Spectrometry (AMS) is currently the standard technique to measure cosmogenic 10Be and 26Al concentrations, but the challenge with measuring low nuclide concentrations is to combine high AMS measurement efficiency with low backgrounds. The current standard measurement setup at ANSTO uses the 3+ charge state with Ar stripper gas at 6 MV for Be and 4 MV for Al, achieving ion transmission through the accelerator for 10Be3+ and 26Al3+ of around 35 % and 40 %, respectively. Traditionally, 26Al measurement uncertainties are larger than those for 10Be. Here, however, we show that 26Al can be measured to similar precision as 10Be even for samples with 26Al / 27Al ratios in the range of 10−15, provided that measurement times are sufficiently long. For example, we can achieve uncertainties of 5 % for 26Al / 27Al ratios around 1 × 10−14, typical for samples of late-Holocene age or samples with long burial histories. We also provide empirical functions between the isotope ratio and achievable measurement precision, which allow predictive capabilities for future projects and serve as a benchmark for inter-laboratory comparisons. For the smallest signals, not only is understanding the source of 10Be or 26Al background events required to select the most appropriate blank correction method but also the impact of the data reduction algorithms on the obtained nuclide concentration becomes pronounced. Here we discuss approaches to background correction and recommend quality assurance practices that guide the most appropriate background correction method. Our sensitivity analysis demonstrates a 30 % difference between different background correction methods for samples with 26Al / 27Al ratios below 10−14. Finally, we show that when the measured signal is small and the number of rare isotope counts is also low, differing 26Al or 10Be concentrations may be obtained from the same data if alternate data reduction algorithms are used. Differences in the resulting isotope concentration can be 50 % or more if only very few ( 10) counts were recorded or about 30 % if single measurement is shorter than 10 min. Our study presents a comprehensive method for analysis of cosmogenic 10Be and 26Al samples down to isotope concentrations of few thousand atoms per gram of sample, which opens the door to new and more varied applications of cosmogenic nuclide analysis.

Klaus M. Wilcken et al.

Status: open (until 23 Dec 2021)

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Klaus M. Wilcken et al.

Klaus M. Wilcken et al.

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Short summary
Cosmogenic nuclides are now widely applied in the Earth sciences, however more recent applications often push the analytical limits of the technique. Our study presents a comprehensive method for analysis of cosmogenic 10Be and 26Al samples down to isotope concentrations of few thousand atoms per gram of sample, which opens the door to new and more varied applications of cosmogenic nuclide analysis.