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<front>
<journal-meta>
<journal-id journal-id-type="publisher">GChronD</journal-id>
<journal-title-group>
<journal-title>Geochronology Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">GChronD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Geochronology Discuss.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">2628-3735</issn>
<publisher><publisher-name></publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/gchron-2023-15</article-id>
<title-group>
<article-title>Constraints on average alpha recoil distance during &lt;sup&gt;238&lt;/sup&gt;U decay in baddeleyite (ZrO&lt;sub&gt;2&lt;/sub&gt;) from atom probe tomography</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Davis</surname>
<given-names>Donald Wayne</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Denyszyn</surname>
<given-names>Steven</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Fougerouse</surname>
<given-names>Denis</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Earth Sciences, University of Toronto, Toronto, M5S 3B1, Canada</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Earth Sciences, Memorial University of Newfoundland, St. John’s, A1A 0G3, Canada</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Geoscience atom probe facility, John de Laeter Centre and School of Earth and Planetary Sciences, Curtin University, Perth Australia</addr-line>
</aff>
<pub-date pub-type="epub">
<day>28</day>
<month>06</month>
<year>2023</year>
</pub-date>
<volume>2023</volume>
<fpage>1</fpage>
<lpage>26</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2023 Donald Wayne Davis et al.</copyright-statement>
<copyright-year>2023</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://gchron.copernicus.org/preprints/gchron-2023-15/">This article is available from https://gchron.copernicus.org/preprints/gchron-2023-15/</self-uri>
<self-uri xlink:href="https://gchron.copernicus.org/preprints/gchron-2023-15/gchron-2023-15.pdf">The full text article is available as a PDF file from https://gchron.copernicus.org/preprints/gchron-2023-15/gchron-2023-15.pdf</self-uri>
<abstract>
<p>&lt;p&gt;Atom probe tomography of &lt;sup&gt;238&lt;/sup&gt;U and &lt;sup&gt;206&lt;/sup&gt;Pb has been applied to baddeleyite crystals from the Hart Dolerite (1791 &amp;plusmn; 1 Ma) and the Great Dyke of Mauritania (2732 &amp;plusmn; 2 Ma) in an effort to constrain the average nuclear recoil distance of U-series daughter nuclei and thereby correct U-Pb ages determined on small baddeleyite crystals for alpha-recoil loss of Pb. Both crystals were thought to expose natural crystal surfaces providing a boundary where maximum recoil loss could be observed, but both surfaces showed no adjacent variations in Pb concentrations. However, the Great Dyke sample shows U zoning and the associated &lt;sup&gt;206&lt;/sup&gt;Pb zoning is affected by alpha recoil. A forward modelling approach was used where &lt;sup&gt;206&lt;/sup&gt;Pb redistribution functions were determined for a range of possible alpha recoil distances and synthetic &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U profiles were determined from the convolution of the observed U profile with the redistribution functions. These can be compared to the observed &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U profile. A complication is that the 400 nm range of sampling is lower than the range of possible alpha recoil redistribution effects. In order to get a realistic match to the observed &lt;sup&gt;206&lt;/sup&gt;Pb/&lt;sup&gt;238&lt;/sup&gt;U profile, it was necessary to extrapolate the observed zoning as an oscillatory pattern. This gives a best estimate for the average alpha recoil distance of about 40 nm.&lt;/p&gt;</p>
</abstract>
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