Articles | Volume 6, issue 3
https://doi.org/10.5194/gchron-6-449-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-6-449-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Aug 2024
Research article |
| 05 Aug 2024
| 05 Aug 2024
Revising chronological uncertainties in marine archives using global anthropogenic signals: a case study on the oceanic 13C Suess effect
Department of Earth Science, University of Bergen and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
Ulysses S. Ninnemann
Department of Earth Science, University of Bergen and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
Are Olsen
Geophysical Institute, University of Bergen and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
Neil L. Rose
Department of Geography, University College London, London, WC1E 6BT, UK
David J. R. Thornalley
Department of Geography, University College London, London, WC1E 6BT, UK
Tor L. Mjell
Department of Earth Science, University of Bergen and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
now at: Slåtthaug School, Bergen kommune, Bergen, 5020, Norway
François Counillon
Geophysical Institute, University of Bergen and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
Nansen Environmental and Remote Sensing Centre and Bjerknes Centre for Climate Research, Bergen, 5007, Norway
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Elwyn de la Vega, Markus Raitzsch, Gavin Foster, Jelle Bijma, Ulysses Silas Ninnemann, Michal Kucera, Tali Lea Babila, Jessica Crumpton Banks, Mohamed M. Ezat, and Audrey Morley
EGUsphere, https://doi.org/10.5194/egusphere-2025-2443, https://doi.org/10.5194/egusphere-2025-2443, 2025
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The boron isotopic composition (δ11B) of foraminifera shells is an established proxy for the reconstruction of ocean pH. Applications to the Arctic oceans are however limited as robust calibrations in these regions are lacking. Here, we present a new calibration linking δ11B measured in two high-latitude foraminifera species to seawater pH. We show that the δ11B of the species analysed is well correlated with seawater pH and that this calibration can be applied to the paleorecord.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255, https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
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This review article provides an overview of 60 existing ocean carbonate chemistry data products, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Yiguo Wang, François Counillon, Lea Svendsen, Ping-Gin Chiu, Noel Keenlyside, Patrick Laloyaux, Mariko Koseki, and Eric de Boisseson
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-127, https://doi.org/10.5194/essd-2025-127, 2025
Revised manuscript accepted for ESSD
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CoRea1860+ is a new climate dataset that reconstructs past climate conditions from 1860 to today. By using advanced modeling techniques and incorporating sea surface temperature observations, it provides a consistent picture of long-term climate variability. The dataset captures key ocean, sea ice and atmosphere changes, helping scientists understand past climate changes and variability.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique M. Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda R. Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Xin Lan, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick C. McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
Earth Syst. Sci. Data, 17, 965–1039, https://doi.org/10.5194/essd-17-965-2025, https://doi.org/10.5194/essd-17-965-2025, 2025
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The Global Carbon Budget 2024 describes the methodology, main results, and datasets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2024). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Nicholas Williams, Yiguo Wang, and François Counillon
EGUsphere, https://doi.org/10.5194/egusphere-2025-104, https://doi.org/10.5194/egusphere-2025-104, 2025
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We assimilate satellite observations of Arctic sea ice thickness to create a skillful initial sea ice state, assimilating ENVISAT-derived sea ice thickness for the first time. We produce a reanalysis and seasonal hindcasts showing that sea ice thickness and volume estimates are significantly improved in both reanalysis and prediction. Predictions of summer sea ice extent in our model are also substantially improved by reducing the high sea ice thickness bias.
Lilian Garcia-Oliva, Alberto Carrassi, and François Counillon
EGUsphere, https://doi.org/10.5194/egusphere-2024-1843, https://doi.org/10.5194/egusphere-2024-1843, 2024
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We used a simple coupled model and a data assimilation method to find the correct initialisation for climate predictions. We aim to clarify when weakly or strongly coupled data assimilation (WCDA or SCDA) is best, depending on the system's dynamical characteristics (spatio-temporal) and data coverage.
We found that WCDA is better in full data coverage. When we have a partially observed system, SCDA is better. This result depends on the temporal and spatial scale of the observed quantity.
We found that WCDA is better in full data coverage. When we have a partially observed system, SCDA is better. This result depends on the temporal and spatial scale of the observed quantity.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Akhilesh Sivaraman Nair, François Counillon, and Noel Keenlyside
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-217, https://doi.org/10.5194/gmd-2023-217, 2024
Publication in GMD not foreseen
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This study demonstrates the importance of soil moisture (SM) in subseasonal-to-seasonal predictions. To addess this, we introduce the Norwegian Climate Prediction Model Land (NorCPM-Land), a land data assimilation system developed for the NorCPM. NorCPM-Land reduces error in SM by 10.5 % by assimilating satellite SM products. Enhanced land initialisation improves predictions up to a 3.5-month lead time for SM and a 1.5-month lead time for temperature and precipitation.
Michelle J. Curran, Christophe Colin, Megan Murphy O’Connor, Ulysses S. Ninnemann, and Audrey Morley
Clim. Past Discuss., https://doi.org/10.5194/cp-2023-101, https://doi.org/10.5194/cp-2023-101, 2024
Revised manuscript not accepted
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Our multi-proxy examination of an abrupt climate event during peak MIS11 reveals new evidence that the reorganisation of Polar and Atlantic Waters at subpolar latitudes is central mechanistically for the stability of North Atlantic Deep Water formation. We conclude that high-magnitude AMOC variability is possible without the addition of freshwater or Icebergs to deep water formation regions challenging established knowledge of AMOC sensitivity and stability during warm climates.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
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The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Zhiyi Jiang, Chris Brierley, David Thornalley, and Sophie Sax
Clim. Past, 19, 107–121, https://doi.org/10.5194/cp-19-107-2023, https://doi.org/10.5194/cp-19-107-2023, 2023
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This work looks at a series of model simulations of two past warm climates. We focus on the deep overturning circulation in the Atlantic Ocean. We show that there are no robust changes in the overall strength of the circulation. We also show that the circulation hardly plays a role in changes in the surface climate across the globe.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
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The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Filippa Fransner, Friederike Fröb, Jerry Tjiputra, Nadine Goris, Siv K. Lauvset, Ingunn Skjelvan, Emil Jeansson, Abdirahman Omar, Melissa Chierici, Elizabeth Jones, Agneta Fransson, Sólveig R. Ólafsdóttir, Truls Johannessen, and Are Olsen
Biogeosciences, 19, 979–1012, https://doi.org/10.5194/bg-19-979-2022, https://doi.org/10.5194/bg-19-979-2022, 2022
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Ocean acidification, a direct consequence of the CO2 release by human activities, is a serious threat to marine ecosystems. In this study, we conduct a detailed investigation of the acidification of the Nordic Seas, from 1850 to 2100, by using a large set of samples taken during research cruises together with numerical model simulations. We estimate the effects of changes in different environmental factors on the rate of acidification and its potential effects on cold-water corals.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Steve D. Jones, Maren K. Karlsen, Claire Lo Monaco, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, https://doi.org/10.5194/essd-13-5565-2021, 2021
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2021 is the third update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 989 hydrographic cruises covering the world's oceans from 1972 to 2020.
Ingo Bethke, Yiguo Wang, François Counillon, Noel Keenlyside, Madlen Kimmritz, Filippa Fransner, Annette Samuelsen, Helene Langehaug, Lea Svendsen, Ping-Gin Chiu, Leilane Passos, Mats Bentsen, Chuncheng Guo, Alok Gupta, Jerry Tjiputra, Alf Kirkevåg, Dirk Olivié, Øyvind Seland, Julie Solsvik Vågane, Yuanchao Fan, and Tor Eldevik
Geosci. Model Dev., 14, 7073–7116, https://doi.org/10.5194/gmd-14-7073-2021, https://doi.org/10.5194/gmd-14-7073-2021, 2021
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The Norwegian Climate Prediction Model version 1 (NorCPM1) is a new research tool for performing climate reanalyses and seasonal-to-decadal climate predictions. It adds data assimilation capability to the Norwegian Earth System Model version 1 (NorESM1) and has contributed output to the Decadal Climate Prediction Project (DCPP) as part of the sixth Coupled Model Intercomparison Project (CMIP6). We describe the system and evaluate its baseline, reanalysis and prediction performance.
Anne L. Morée, Jörg Schwinger, Ulysses S. Ninnemann, Aurich Jeltsch-Thömmes, Ingo Bethke, and Christoph Heinze
Clim. Past, 17, 753–774, https://doi.org/10.5194/cp-17-753-2021, https://doi.org/10.5194/cp-17-753-2021, 2021
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This modeling study of the Last Glacial Maximum (LGM, ~ 21 000 years ago) ocean explores the biological and physical changes in the ocean needed to satisfy marine proxy records, with a focus on the carbon isotope 13C. We estimate that the LGM ocean may have been up to twice as efficient at sequestering carbon and nutrients at depth as compared to preindustrial times. Our work shows that both circulation and biogeochemical changes must have occurred between the LGM and preindustrial times.
Meike Becker, Are Olsen, Peter Landschützer, Abdirhaman Omar, Gregor Rehder, Christian Rödenbeck, and Ingunn Skjelvan
Biogeosciences, 18, 1127–1147, https://doi.org/10.5194/bg-18-1127-2021, https://doi.org/10.5194/bg-18-1127-2021, 2021
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We developed a simple method to refine existing open-ocean maps towards different coastal seas. Using a multi-linear regression, we produced monthly maps of surface ocean fCO2 in the northern European coastal seas (the North Sea, the Baltic Sea, the Norwegian Coast and the Barents Sea) covering a time period from 1998 to 2016. Based on this fCO2 map, we calculate trends in surface ocean fCO2, pH and the air–sea gas exchange.
Are Olsen, Nico Lange, Robert M. Key, Toste Tanhua, Henry C. Bittig, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Camilla S. Landa, Siv K. Lauvset, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, and Ryan J. Woosley
Earth Syst. Sci. Data, 12, 3653–3678, https://doi.org/10.5194/essd-12-3653-2020, https://doi.org/10.5194/essd-12-3653-2020, 2020
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by chemical analysis of water bottle samples at scientific cruises. GLODAPv2.2020 is the second update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 946 hydrographic cruises covering the world's oceans from 1972 to 2019.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Corinne Le Quéré, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone Alin, Luiz E. O. C. Aragão, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Alice Benoit-Cattin, Henry C. Bittig, Laurent Bopp, Selma Bultan, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Wiley Evans, Liesbeth Florentie, Piers M. Forster, Thomas Gasser, Marion Gehlen, Dennis Gilfillan, Thanos Gkritzalis, Luke Gregor, Nicolas Gruber, Ian Harris, Kerstin Hartung, Vanessa Haverd, Richard A. Houghton, Tatiana Ilyina, Atul K. Jain, Emilie Joetzjer, Koji Kadono, Etsushi Kato, Vassilis Kitidis, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Andrew Lenton, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Gregg Marland, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Adam J. P. Smith, Adrienne J. Sutton, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Guido van der Werf, Nicolas Vuichard, Anthony P. Walker, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Xu Yue, and Sönke Zaehle
Earth Syst. Sci. Data, 12, 3269–3340, https://doi.org/10.5194/essd-12-3269-2020, https://doi.org/10.5194/essd-12-3269-2020, 2020
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The Global Carbon Budget 2020 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Chris M. Brierley, Anni Zhao, Sandy P. Harrison, Pascale Braconnot, Charles J. R. Williams, David J. R. Thornalley, Xiaoxu Shi, Jean-Yves Peterschmitt, Rumi Ohgaito, Darrell S. Kaufman, Masa Kageyama, Julia C. Hargreaves, Michael P. Erb, Julien Emile-Geay, Roberta D'Agostino, Deepak Chandan, Matthieu Carré, Partrick J. Bartlein, Weipeng Zheng, Zhongshi Zhang, Qiong Zhang, Hu Yang, Evgeny M. Volodin, Robert A. Tomas, Cody Routson, W. Richard Peltier, Bette Otto-Bliesner, Polina A. Morozova, Nicholas P. McKay, Gerrit Lohmann, Allegra N. Legrande, Chuncheng Guo, Jian Cao, Esther Brady, James D. Annan, and Ayako Abe-Ouchi
Clim. Past, 16, 1847–1872, https://doi.org/10.5194/cp-16-1847-2020, https://doi.org/10.5194/cp-16-1847-2020, 2020
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This paper provides an initial exploration and comparison to climate reconstructions of the new climate model simulations of the mid-Holocene (6000 years ago). These use state-of-the-art models developed for CMIP6 and apply the same experimental set-up. The models capture several key aspects of the climate, but some persistent issues remain.
Daniel Broullón, Fiz F. Pérez, Antón Velo, Mario Hoppema, Are Olsen, Taro Takahashi, Robert M. Key, Toste Tanhua, J. Magdalena Santana-Casiano, and Alex Kozyr
Earth Syst. Sci. Data, 12, 1725–1743, https://doi.org/10.5194/essd-12-1725-2020, https://doi.org/10.5194/essd-12-1725-2020, 2020
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This work offers a vision of the global ocean regarding the carbon cycle and the implications of ocean acidification through a climatology of a changing variable in the context of climate change: total dissolved inorganic carbon. The climatology was designed through artificial intelligence techniques to represent the mean state of the present ocean. It is very useful to introduce in models to evaluate the state of the ocean from different perspectives.
Are Olsen, Nico Lange, Robert M. Key, Toste Tanhua, Marta Álvarez, Susan Becker, Henry C. Bittig, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Steve D. Jones, Sara Jutterström, Maren K. Karlsen, Alex Kozyr, Siv K. Lauvset, Claire Lo Monaco, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Maciej Telszewski, Bronte Tilbrook, Anton Velo, and Rik Wanninkhof
Earth Syst. Sci. Data, 11, 1437–1461, https://doi.org/10.5194/essd-11-1437-2019, https://doi.org/10.5194/essd-11-1437-2019, 2019
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by chemical analysis of water bottle samples at scientific cruises. GLODAPv2.2019 is the first update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 840 hydrographic cruises covering the world's oceans from 1972 to 2017.
Daniel Broullón, Fiz F. Pérez, Antón Velo, Mario Hoppema, Are Olsen, Taro Takahashi, Robert M. Key, Toste Tanhua, Melchor González-Dávila, Emil Jeansson, Alex Kozyr, and Steven M. A. C. van Heuven
Earth Syst. Sci. Data, 11, 1109–1127, https://doi.org/10.5194/essd-11-1109-2019, https://doi.org/10.5194/essd-11-1109-2019, 2019
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In this work, we are contributing to the knowledge of the consequences of climate change in the ocean. We have focused on a variable related to this process: total alkalinity. We have designed a monthly climatology of total alkalinity using artificial intelligence techniques, that is, a representation of the average capacity of the ocean in the last decades to decelerate the consequences of climate change. The climatology is especially useful to infer the evolution of the ocean through models.
Augustin Kessler, Eirik Vinje Galaasen, Ulysses Silas Ninnemann, and Jerry Tjiputra
Clim. Past, 14, 1961–1976, https://doi.org/10.5194/cp-14-1961-2018, https://doi.org/10.5194/cp-14-1961-2018, 2018
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We analyze the changes in oceanic carbon dynamics, using a state-of-the-art Earth system model, by comparing two quasi-equilibrium states: the early, warm Eemian (125 ka) versus the cooler, late Eemian (115 ka). Our results suggest a considerably weaker ocean dissolved inorganic carbon storage at 125 ka, an alteration of the deep-water geometry and ventilation in the South Atlantic, and heterogeneous changes in phosphate availability and carbon export between the Pacific and Atlantic basins.
Corinne Le Quéré, Robbie M. Andrew, Pierre Friedlingstein, Stephen Sitch, Judith Hauck, Julia Pongratz, Penelope A. Pickers, Jan Ivar Korsbakken, Glen P. Peters, Josep G. Canadell, Almut Arneth, Vivek K. Arora, Leticia Barbero, Ana Bastos, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Philippe Ciais, Scott C. Doney, Thanos Gkritzalis, Daniel S. Goll, Ian Harris, Vanessa Haverd, Forrest M. Hoffman, Mario Hoppema, Richard A. Houghton, George Hurtt, Tatiana Ilyina, Atul K. Jain, Truls Johannessen, Chris D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Peter Landschützer, Nathalie Lefèvre, Sebastian Lienert, Zhu Liu, Danica Lombardozzi, Nicolas Metzl, David R. Munro, Julia E. M. S. Nabel, Shin-ichiro Nakaoka, Craig Neill, Are Olsen, Tsueno Ono, Prabir Patra, Anna Peregon, Wouter Peters, Philippe Peylin, Benjamin Pfeil, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Matthias Rocher, Christian Rödenbeck, Ute Schuster, Jörg Schwinger, Roland Séférian, Ingunn Skjelvan, Tobias Steinhoff, Adrienne Sutton, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco N. Tubiello, Ingrid T. van der Laan-Luijkx, Guido R. van der Werf, Nicolas Viovy, Anthony P. Walker, Andrew J. Wiltshire, Rebecca Wright, Sönke Zaehle, and Bo Zheng
Earth Syst. Sci. Data, 10, 2141–2194, https://doi.org/10.5194/essd-10-2141-2018, https://doi.org/10.5194/essd-10-2141-2018, 2018
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The Global Carbon Budget 2018 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Jiping Xie, François Counillon, and Laurent Bertino
The Cryosphere, 12, 3671–3691, https://doi.org/10.5194/tc-12-3671-2018, https://doi.org/10.5194/tc-12-3671-2018, 2018
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We use the winter sea-ice thickness dataset CS2SMOS merged from two satellites SMOS and CryoSat-2 for assimilation into an ice–ocean reanalysis of the Arctic, complemented by several other ocean and sea-ice measurements, using an Ensemble Kalman Filter. The errors of sea-ice thickness are reduced by 28% and the improvements persists through the summer when observations are unavailable. Improvements of ice drift are however limited to the Central Arctic.
Lourdes Arellano, Pilar Fernández, Barend L. van Drooge, Neil L. Rose, Ulrike Nickus, Hansjoerg Thies, Evzen Stuchlík, Lluís Camarero, Jordi Catalan, and Joan O. Grimalt
Atmos. Chem. Phys., 18, 16081–16097, https://doi.org/10.5194/acp-18-16081-2018, https://doi.org/10.5194/acp-18-16081-2018, 2018
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Mountain areas are key for studying the impact of diffuse pollution due to human activities on the continental areas. Polycyclic aromatic hydrocarbons (PAHs), human carcinogens with increased levels since the 1950s, are significant constituents of this pollution. We determined PAHs in monthly atmospheric deposition collected in European high mountain areas. The number of sites, period of study and sampling frequency provide the most comprehensive description of PAH fallout at remote sites.
Bryan C. Lougheed, Brett Metcalfe, Ulysses S. Ninnemann, and Lukas Wacker
Clim. Past, 14, 515–526, https://doi.org/10.5194/cp-14-515-2018, https://doi.org/10.5194/cp-14-515-2018, 2018
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Palaeoclimate reconstructions from deep-sea sediment archives provide valuable insight into past rapid climate change, but only a small proportion of the ocean is suitable for such reconstructions using the existing state of the art, i.e. the age–depth approach. We use dual radiocarbon (14C) and stable isotope analysis on single foraminifera to bypass the long-standing age–depth approach, thus facilitating past ocean chemistry reconstructions from vast, previously untapped ocean areas.
Sayaka Yasunaka, Eko Siswanto, Are Olsen, Mario Hoppema, Eiji Watanabe, Agneta Fransson, Melissa Chierici, Akihiko Murata, Siv K. Lauvset, Rik Wanninkhof, Taro Takahashi, Naohiro Kosugi, Abdirahman M. Omar, Steven van Heuven, and Jeremy T. Mathis
Biogeosciences, 15, 1643–1661, https://doi.org/10.5194/bg-15-1643-2018, https://doi.org/10.5194/bg-15-1643-2018, 2018
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We estimated monthly air–sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014, after mapping pCO2 in the surface water using a self-organizing map technique. The addition of Chl a as a parameter enabled us to improve the estimate of pCO2 via better representation of its decline in spring. The uncertainty in the CO2 flux estimate was reduced, and a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C y−1 was determined to be significant.
Friederike Fröb, Are Olsen, Fiz F. Pérez, Maribel I. García-Ibáñez, Emil Jeansson, Abdirahman Omar, and Siv K. Lauvset
Biogeosciences, 15, 51–72, https://doi.org/10.5194/bg-15-51-2018, https://doi.org/10.5194/bg-15-51-2018, 2018
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On long timescales, the inventory of total dissolved inorganic carbon in the ocean is mainly driven by the increase in anthropogenic CO2 emitted to the atmosphere due to human activities. On short timescales, however, the anthropogenic signal can be masked by the variability in natural inorganic carbon, shown in this study based on Irminger Sea cruise data from 1991 to 2015. In order to estimate oceanic carbon budgets, we suggest jointly assessing natural, anthropogenic and total carbon.
Jiping Xie, Laurent Bertino, François Counillon, Knut A. Lisæter, and Pavel Sakov
Ocean Sci., 13, 123–144, https://doi.org/10.5194/os-13-123-2017, https://doi.org/10.5194/os-13-123-2017, 2017
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The Arctic Ocean plays an important role in the global climate system, but the concerned interpretation about its changes is severely hampered by the sparseness of the observations of sea ice and ocean. The focus of this study is to provide a quantitative assessment of the performance of the TOPAZ4 reanalysis for ocean and sea ice variables in the pan-Arctic region (north of 63 °N) in order to guide the user through its skills and limitations.
Jiping Xie, François Counillon, Laurent Bertino, Xiangshan Tian-Kunze, and Lars Kaleschke
The Cryosphere, 10, 2745–2761, https://doi.org/10.5194/tc-10-2745-2016, https://doi.org/10.5194/tc-10-2745-2016, 2016
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As a potentially operational daily product, the SMOS-Ice can improve the statements of sea ice thickness and concentration. In this study, focusing on the SMOS-Ice data assimilated into the TOPAZ system, the quantitative evaluation for the impacts and the concerned comparison with the present observation system are valuable to understand the further improvement of the accuracy of operational ocean forecasting system.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
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Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Are Olsen, Robert M. Key, Steven van Heuven, Siv K. Lauvset, Anton Velo, Xiaohua Lin, Carsten Schirnick, Alex Kozyr, Toste Tanhua, Mario Hoppema, Sara Jutterström, Reiner Steinfeldt, Emil Jeansson, Masao Ishii, Fiz F. Pérez, and Toru Suzuki
Earth Syst. Sci. Data, 8, 297–323, https://doi.org/10.5194/essd-8-297-2016, https://doi.org/10.5194/essd-8-297-2016, 2016
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The GLODAPv2 data product collects data from more than 700 hydrographic cruises into a global and internally calibrated product. It provides access to the data from almost all ocean carbon cruises carried out since the 1970s and is a unique resource for marine science, in particular regarding the ocean carbon cycle. GLODAPv2 will form the foundation for future routine synthesis of hydrographic data of the same sort.
Siv K. Lauvset, Robert M. Key, Are Olsen, Steven van Heuven, Anton Velo, Xiaohua Lin, Carsten Schirnick, Alex Kozyr, Toste Tanhua, Mario Hoppema, Sara Jutterström, Reiner Steinfeldt, Emil Jeansson, Masao Ishii, Fiz F. Perez, Toru Suzuki, and Sylvain Watelet
Earth Syst. Sci. Data, 8, 325–340, https://doi.org/10.5194/essd-8-325-2016, https://doi.org/10.5194/essd-8-325-2016, 2016
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This paper describes the mapped climatologies that are part of the Global Ocean Data Analysis Project Version 2 (GLODAPv2). GLODAPv2 is a uniformly calibrated open ocean data product on inorganic carbon and carbon-relevant variables. Global mapped climatologies of the total dissolved inorganic carbon, total alkalinity, pH, saturation state of calcite and aragonite, anthropogenic carbon, preindustrial carbon content, inorganic macronutrients, oxygen, salinity, and temperature have been created.
Abdirahman M. Omar, Ingunn Skjelvan, Svein Rune Erga, and Are Olsen
Ocean Sci., 12, 937–951, https://doi.org/10.5194/os-12-937-2016, https://doi.org/10.5194/os-12-937-2016, 2016
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We have determined, for the first time, the seasonal changes and controlling processes of ocean acidification parameters across western Norwegian fjords, based on data obtained mainly with sensors on board a commercial ship, MS Trans Carrier, in 2005–2009. The study fills an important gap in our knowledge on ocean acidification in western Norwegian fjords, which are important ecosystems: important recreation areas, marine pathways, spawning grounds for different fish species, etc.
Maribel I. García-Ibáñez, Patricia Zunino, Friederike Fröb, Lidia I. Carracedo, Aida F. Ríos, Herlé Mercier, Are Olsen, and Fiz F. Pérez
Biogeosciences, 13, 3701–3715, https://doi.org/10.5194/bg-13-3701-2016, https://doi.org/10.5194/bg-13-3701-2016, 2016
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We assessed the progressive acidification (pH decrease) of the North Atlantic waters from direct observations between 1991 and 2015. The greatest pH decreases were observed in surface and intermediate waters. We conclude that the observed pH decreases are a consequence of the oceanic uptake of anthropogenic CO2. In addition we find that they have been partially offset by alkalinity increases.
B. A. A. Hoogakker, D. J. R. Thornalley, and S. Barker
Biogeosciences, 13, 211–221, https://doi.org/10.5194/bg-13-211-2016, https://doi.org/10.5194/bg-13-211-2016, 2016
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Models predict a decrease in future ocean O2, driven by surface water warming and freshening in the polar regions, causing a reduction in ocean circulation. Here we assess this effect in the past, focussing on the response of deep and intermediate waters from the North Atlantic during large-scale ice rafting and millennial-scale cooling events of the last glacial.
Our assessment agrees with the models but also highlights the importance of biological processes driving ocean O2 change.
C. Rödenbeck, D. C. E. Bakker, N. Gruber, Y. Iida, A. R. Jacobson, S. Jones, P. Landschützer, N. Metzl, S. Nakaoka, A. Olsen, G.-H. Park, P. Peylin, K. B. Rodgers, T. P. Sasse, U. Schuster, J. D. Shutler, V. Valsala, R. Wanninkhof, and J. Zeng
Biogeosciences, 12, 7251–7278, https://doi.org/10.5194/bg-12-7251-2015, https://doi.org/10.5194/bg-12-7251-2015, 2015
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This study investigates variations in the CO2 uptake of the ocean from year to year. These variations have been calculated from measurements of the surface-ocean carbon content by various different interpolation methods. The equatorial Pacific is estimated to be the region with the strongest year-to-year variations, tied to the El Nino phase. The global ocean CO2 uptake gradually increased from about the year 2000. The comparison of the interpolation methods identifies these findings as robust.
C. Le Quéré, R. Moriarty, R. M. Andrew, J. G. Canadell, S. Sitch, J. I. Korsbakken, P. Friedlingstein, G. P. Peters, R. J. Andres, T. A. Boden, R. A. Houghton, J. I. House, R. F. Keeling, P. Tans, A. Arneth, D. C. E. Bakker, L. Barbero, L. Bopp, J. Chang, F. Chevallier, L. P. Chini, P. Ciais, M. Fader, R. A. Feely, T. Gkritzalis, I. Harris, J. Hauck, T. Ilyina, A. K. Jain, E. Kato, V. Kitidis, K. Klein Goldewijk, C. Koven, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. Lenton, I. D. Lima, N. Metzl, F. Millero, D. R. Munro, A. Murata, J. E. M. S. Nabel, S. Nakaoka, Y. Nojiri, K. O'Brien, A. Olsen, T. Ono, F. F. Pérez, B. Pfeil, D. Pierrot, B. Poulter, G. Rehder, C. Rödenbeck, S. Saito, U. Schuster, J. Schwinger, R. Séférian, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, I. T. van der Laan-Luijkx, G. R. van der Werf, S. van Heuven, D. Vandemark, N. Viovy, A. Wiltshire, S. Zaehle, and N. Zeng
Earth Syst. Sci. Data, 7, 349–396, https://doi.org/10.5194/essd-7-349-2015, https://doi.org/10.5194/essd-7-349-2015, 2015
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Accurate assessment of anthropogenic carbon dioxide emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to understand the global carbon cycle, support the development of climate policies, and project future climate change. We describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on a range of data and models and their interpretation by a broad scientific community.
A. S. A. Ferreira, H. Hátún, F. Counillon, M. R. Payne, and A. W. Visser
Biogeosciences, 12, 3641–3653, https://doi.org/10.5194/bg-12-3641-2015, https://doi.org/10.5194/bg-12-3641-2015, 2015
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Our main objective was to assess which bottom-up processes can best predict changes in phytoplankton surface spring blooms in the North Atlantic. We applied new phenology algorithms to satellite-derived data and compared four different metrics based on physical drivers of phytoplankton. We show that there is a dominant physical mechanism - mixed layer shoaling - and that different regions are governed by different physical phenomena.
L. Arellano, P. Fernández, R. Fonts, N. L. Rose, U. Nickus, H. Thies, E. Stuchlík, L. Camarero, J. Catalan, and J. O. Grimalt
Atmos. Chem. Phys., 15, 6069–6085, https://doi.org/10.5194/acp-15-6069-2015, https://doi.org/10.5194/acp-15-6069-2015, 2015
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Despite the regulations in the use of polychlorobiphenyls (PCBs), an increase in atmospheric deposition fluxes of these pollutants in high-altitude mountain areas of Europe is observed for the period between 1996 and 2006. In contrast, atmospheric deposition of organochlorine pesticides showed a strong decrease. Volatilization from soils or melting glaciers related to climate change and the differences in physical–chemical properties between compounds may explain the observed temporal trend.
C. Le Quéré, R. Moriarty, R. M. Andrew, G. P. Peters, P. Ciais, P. Friedlingstein, S. D. Jones, S. Sitch, P. Tans, A. Arneth, T. A. Boden, L. Bopp, Y. Bozec, J. G. Canadell, L. P. Chini, F. Chevallier, C. E. Cosca, I. Harris, M. Hoppema, R. A. Houghton, J. I. House, A. K. Jain, T. Johannessen, E. Kato, R. F. Keeling, V. Kitidis, K. Klein Goldewijk, C. Koven, C. S. Landa, P. Landschützer, A. Lenton, I. D. Lima, G. Marland, J. T. Mathis, N. Metzl, Y. Nojiri, A. Olsen, T. Ono, S. Peng, W. Peters, B. Pfeil, B. Poulter, M. R. Raupach, P. Regnier, C. Rödenbeck, S. Saito, J. E. Salisbury, U. Schuster, J. Schwinger, R. Séférian, J. Segschneider, T. Steinhoff, B. D. Stocker, A. J. Sutton, T. Takahashi, B. Tilbrook, G. R. van der Werf, N. Viovy, Y.-P. Wang, R. Wanninkhof, A. Wiltshire, and N. Zeng
Earth Syst. Sci. Data, 7, 47–85, https://doi.org/10.5194/essd-7-47-2015, https://doi.org/10.5194/essd-7-47-2015, 2015
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Carbon dioxide (CO2) emissions from human activities (burning fossil fuels and cement production, deforestation and other land-use change) are set to rise again in 2014.
This study (updated yearly) makes an accurate assessment of anthropogenic CO2 emissions and their redistribution between the atmosphere, ocean, and terrestrial biosphere in order to better understand the global carbon cycle, support the development of climate policies, and project future climate change.
S. K. Lauvset, N. Gruber, P. Landschützer, A. Olsen, and J. Tjiputra
Biogeosciences, 12, 1285–1298, https://doi.org/10.5194/bg-12-1285-2015, https://doi.org/10.5194/bg-12-1285-2015, 2015
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This paper utilizes the SOCATv2 data product to calculate surface ocean pH. The pH data are divided into 17 biomes, and a linear regression is used to derive the long-term trend of pH in each biome. The results are consistent with the trends observed at time series stations. The uncertainties are too large for a mechanistic understanding of the driving forces behind the trend, but there are indications that concurrent changes in chemistry create spatial variability.
C. Rödenbeck, D. C. E. Bakker, N. Metzl, A. Olsen, C. Sabine, N. Cassar, F. Reum, R. F. Keeling, and M. Heimann
Biogeosciences, 11, 4599–4613, https://doi.org/10.5194/bg-11-4599-2014, https://doi.org/10.5194/bg-11-4599-2014, 2014
L. Arellano, P. Fernández, J. F. López, N. L. Rose, U. Nickus, H. Thies, E. Stuchlik, L. Camarero, J. Catalan, and J. O. Grimalt
Atmos. Chem. Phys., 14, 4441–4457, https://doi.org/10.5194/acp-14-4441-2014, https://doi.org/10.5194/acp-14-4441-2014, 2014
D. C. E. Bakker, B. Pfeil, K. Smith, S. Hankin, A. Olsen, S. R. Alin, C. Cosca, S. Harasawa, A. Kozyr, Y. Nojiri, K. M. O'Brien, U. Schuster, M. Telszewski, B. Tilbrook, C. Wada, J. Akl, L. Barbero, N. R. Bates, J. Boutin, Y. Bozec, W.-J. Cai, R. D. Castle, F. P. Chavez, L. Chen, M. Chierici, K. Currie, H. J. W. de Baar, W. Evans, R. A. Feely, A. Fransson, Z. Gao, B. Hales, N. J. Hardman-Mountford, M. Hoppema, W.-J. Huang, C. W. Hunt, B. Huss, T. Ichikawa, T. Johannessen, E. M. Jones, S. D. Jones, S. Jutterström, V. Kitidis, A. Körtzinger, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. B. Manke, J. T. Mathis, L. Merlivat, N. Metzl, A. Murata, T. Newberger, A. M. Omar, T. Ono, G.-H. Park, K. Paterson, D. Pierrot, A. F. Ríos, C. L. Sabine, S. Saito, J. Salisbury, V. V. S. S. Sarma, R. Schlitzer, R. Sieger, I. Skjelvan, T. Steinhoff, K. F. Sullivan, H. Sun, A. J. Sutton, T. Suzuki, C. Sweeney, T. Takahashi, J. Tjiputra, N. Tsurushima, S. M. A. C. van Heuven, D. Vandemark, P. Vlahos, D. W. R. Wallace, R. Wanninkhof, and A. J. Watson
Earth Syst. Sci. Data, 6, 69–90, https://doi.org/10.5194/essd-6-69-2014, https://doi.org/10.5194/essd-6-69-2014, 2014
C. L. Sabine, S. Hankin, H. Koyuk, D. C. E. Bakker, B. Pfeil, A. Olsen, N. Metzl, A. Kozyr, A. Fassbender, A. Manke, J. Malczyk, J. Akl, S. R. Alin, R. G. J. Bellerby, A. Borges, J. Boutin, P. J. Brown, W.-J. Cai, F. P. Chavez, A. Chen, C. Cosca, R. A. Feely, M. González-Dávila, C. Goyet, N. Hardman-Mountford, C. Heinze, M. Hoppema, C. W. Hunt, D. Hydes, M. Ishii, T. Johannessen, R. M. Key, A. Körtzinger, P. Landschützer, S. K. Lauvset, N. Lefèvre, A. Lenton, A. Lourantou, L. Merlivat, T. Midorikawa, L. Mintrop, C. Miyazaki, A. Murata, A. Nakadate, Y. Nakano, S. Nakaoka, Y. Nojiri, A. M. Omar, X. A. Padin, G.-H. Park, K. Paterson, F. F. Perez, D. Pierrot, A. Poisson, A. F. Ríos, J. Salisbury, J. M. Santana-Casiano, V. V. S. S. Sarma, R. Schlitzer, B. Schneider, U. Schuster, R. Sieger, I. Skjelvan, T. Steinhoff, T. Suzuki, T. Takahashi, K. Tedesco, M. Telszewski, H. Thomas, B. Tilbrook, D. Vandemark, T. Veness, A. J. Watson, R. Weiss, C. S. Wong, and H. Yoshikawa-Inoue
Earth Syst. Sci. Data, 5, 145–153, https://doi.org/10.5194/essd-5-145-2013, https://doi.org/10.5194/essd-5-145-2013, 2013
C. Rödenbeck, R. F. Keeling, D. C. E. Bakker, N. Metzl, A. Olsen, C. Sabine, and M. Heimann
Ocean Sci., 9, 193–216, https://doi.org/10.5194/os-9-193-2013, https://doi.org/10.5194/os-9-193-2013, 2013
U. Schuster, G. A. McKinley, N. Bates, F. Chevallier, S. C. Doney, A. R. Fay, M. González-Dávila, N. Gruber, S. Jones, J. Krijnen, P. Landschützer, N. Lefèvre, M. Manizza, J. Mathis, N. Metzl, A. Olsen, A. F. Rios, C. Rödenbeck, J. M. Santana-Casiano, T. Takahashi, R. Wanninkhof, and A. J. Watson
Biogeosciences, 10, 607–627, https://doi.org/10.5194/bg-10-607-2013, https://doi.org/10.5194/bg-10-607-2013, 2013
Related subject area
Geochronological data analysis/statistics/modelling
The quantification of down-hole fractionation for laser ablation mass spectrometry
Global analysis of in situ cosmogenic 26Al and 10Be and inferred erosion rate ratios in modern fluvial sediments indicates widespread sediment storage and burial during transport
New controls on sedimentation and climate in the central equatorial Pacific Ocean
Measuring varve thickness using micro-computed tomography (µCT): a comparison with thin section
Technical Note: Incorporating topographic deflection effects into thermal history modelling
Controls on zircon age distributions in volcanic, porphyry and plutonic rocks
Broken 206Pb/238U carbonate chronometers and 207Pb/235U fixes
Interpreting cooling dates and histories from laser ablation in situ (U–Th–Sm) ∕ He thermochronometry: a modelling perspective
Short communication: Nanoscale heterogeneity of U and Pb in baddeleyite from atom probe tomography – 238U series alpha recoil effects and U atom clustering
In situ rubidium–strontium geochronology of white mica in young metamafic and metasomatic rocks from Syros: testing the limits of laser-ablation triple-quadrupole inductively coupled plasma mass spectrometer mica dating using different anchoring approaches
Discordance Dating: A New Approach for Dating Sedimentary Alteration Events
An optimization tool for identifying multiple-diffusion domain model parameters
Nonparametric estimation of age-depth models from sedimentological and stratigraphic information
The virtual spot approach: a simple method for image U-Pb carbonate geochronology by high-repetition rate LA-ICP-MS
Technical note: RA138 calcite U–Pb LA-ICP-MS primary reference material
Short Communication: A database of the global distribution of (U-Th)/He ages and U, Th contents of goethites
The daughter–parent plot: a tool for analyzing thermochronological data
Errorchrons and anchored isochrons in IsoplotR
Short communication: Resolving the discrepancy between U–Pb age estimates for the “Likhall” bed, a key level in the Ordovician timescale
Navigating the complexity of detrital rutile provenance: methodological insights from the Neotethys Orogen in Anatolia
Solving crustal heat transfer for thermochronology using physics-informed neural networks
Minimizing the effects of Pb loss in detrital and igneous U–Pb zircon geochronology by CA-LA-ICP-MS
Modeling apparent Pb loss in zircon U–Pb geochronology
Calibration methods for laser ablation Rb–Sr geochronology: comparisons and recommendation based on NIST glass and natural reference materials
Short communication: The Wasserstein distance as a dissimilarity metric for comparing detrital age spectra and other geological distributions
ChronoLorica: introduction of a soil–landscape evolution model combined with geochronometers
Technical note: colab_zirc_dims: a Google Colab-compatible toolset for automated and semi-automated measurement of mineral grains in laser ablation–inductively coupled plasma–mass spectrometry images using deep learning models
Calculation of uncertainty in the (U–Th) ∕ He system
Bayesian age–depth modelling applied to varve and radiometric dating to optimize the transfer of an existing high-resolution chronology to a new composite sediment profile from Holzmaar (West Eifel Volcanic Field, Germany)
Short communication: age2exhume – a MATLAB/Python script to calculate steady-state vertical exhumation rates from thermochronometric ages and application to the Himalaya
U and Th content in magnetite and Al spinel obtained by wet chemistry and laser ablation methods: implication for (U–Th) ∕ He thermochronometer
In situ LA-ICPMS U–Pb dating of sulfates: applicability of carbonate reference materials as matrix-matched standards
An algorithm for U–Pb geochronology by secondary ion mass spectrometry
Technical note: Rapid phase identification of apatite and zircon grains for geochronology using X-ray micro-computed tomography
Simulating sedimentary burial cycles – Part 2: Elemental-based multikinetic apatite fission-track interpretation and modelling techniques illustrated using examples from northern Yukon
sandbox – creating and analysing synthetic sediment sections with R
Improving age–depth relationships by using the LANDO (“Linked age and depth modeling”) model ensemble
How many grains are needed for quantifying catchment erosion from tracer thermochronology?
Short communication: Inverse isochron regression for Re–Os, K–Ca and other chronometers
Technical note: Analytical protocols and performance for apatite and zircon (U–Th) ∕ He analysis on quadrupole and magnetic sector mass spectrometer systems between 2007 and 2020
Simulating sedimentary burial cycles – Part 1: Investigating the role of apatite fission track annealing kinetics using synthetic data
The closure temperature(s) of zircon Raman dating
On the treatment of discordant detrital zircon U–Pb data
An evaluation of Deccan Traps eruption rates using geochronologic data
geoChronR – an R package to model, analyze, and visualize age-uncertain data
Development of a multi-method chronology spanning the Last Glacial Interval from Orakei maar lake, Auckland, New Zealand
Robust isochron calculation
Resolving the timescales of magmatic and hydrothermal processes associated with porphyry deposit formation using zircon U–Pb petrochronology
Seasonal deposition processes and chronology of a varved Holocene lake sediment record from Chatyr Kol lake (Kyrgyz Republic)
Unifying the U–Pb and Th–Pb methods: joint isochron regression and common Pb correction
Jarred C. Lloyd, Carl Spandler, Sarah E. Gilbert, and Derrick Hasterok
Geochronology, 7, 265–287, https://doi.org/10.5194/gchron-7-265-2025, https://doi.org/10.5194/gchron-7-265-2025, 2025
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Laser-based dating of rocks and minerals is invaluable in geoscience. This study significantly advances our ability to model and correct for a process called down-hole fractionation (DHF) that impacts the accuracy and uncertainty of dates. We develop an algorithm that quantitatively models DHF patterns but can be used on other geoscientific data. The implications are far-reaching: improved accuracy, reduced uncertainty, and easier comparisons between different samples and laboratories.
Christopher T. Halsted, Paul R. Bierman, Alexandru T. Codilean, Lee B. Corbett, and Marc W. Caffee
Geochronology, 7, 213–228, https://doi.org/10.5194/gchron-7-213-2025, https://doi.org/10.5194/gchron-7-213-2025, 2025
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Sediment generation on hillslopes and transport through river networks are complex processes that influence landscape evolution. In this study, we compiled sand from 766 river basins and measured its subtle radioactivity to unravel timelines of sediment routing around the world. With these data, we empirically confirm that sediment from large lowland basins in tectonically stable regions typically experiences long periods of burial, while sediment moves rapidly through small upland basins.
Allison W. Jacobel, Kassandra M. Costa, Lily M. Applebaum, and Serena Conde
Geochronology, 7, 123–138, https://doi.org/10.5194/gchron-7-123-2025, https://doi.org/10.5194/gchron-7-123-2025, 2025
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The equatorial Pacific is an important region that helps determine Earth's climate. This work presents new age models for two sediment core sites located in that region, spanning the last 280 kyr. Our age models are based on new radiocarbon dates and oxygen isotope measurements. We also use the oxygen isotope data to infer changes in sea surface salinity patterns, finding evidence for a change in the position of the Intertropical Convergence Zone (ITCZ) on glacial and interglacial timescales.
Marie-Eugénie Meusseunan Pascale Jamba, Pierre Francus, Antoine Gagnon-Poiré, and Guillaume St-Onge
Geochronology, 7, 83–111, https://doi.org/10.5194/gchron-7-83-2025, https://doi.org/10.5194/gchron-7-83-2025, 2025
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This article presents a non-destructive method for studying laminated sediments with X-ray micro-computed tomography (μCT). It aims to study the possibility of using μCT as an analytical tool to analyse varved sediments in the context of paleoclimatic studies. As a result, µCT offers the possibility of doing fast analysis and constitutes a powerful tool to improve the quality of results through the access of a 3D view, allowing for choosing the most representative part of a varved record.
Richard A. Ketcham
EGUsphere, https://doi.org/10.5194/egusphere-2025-901, https://doi.org/10.5194/egusphere-2025-901, 2025
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This technical note develops and demonstrates an improvement in how to calculate the temperatures experienced by rocks as they come to the Earth surface due to erosion in mountainous regions. The solution is fast and flexible, and works even in areas where erosion rates have varied through time. The new method has been added to software used to interpret geochronologic data to help discern the history of mountain ranges.
Chetan Nathwani, Dawid Szymanowski, Lorenzo Tavazzani, Sava Markovic, Adrianna L. Virmond, and Cyril Chelle-Michou
Geochronology, 7, 15–33, https://doi.org/10.5194/gchron-7-15-2025, https://doi.org/10.5194/gchron-7-15-2025, 2025
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We performed a statistical analysis of high-precision U–Pb zircon age distributions. This reveals that volcanic and porphyry zircon age distributions are skewed to younger ages, whereas plutonic age distributions are skewed to older ages. We show that this is caused by truncation of zircon crystallisation by magma evacuation rather than differences in magmatic flux. Our contribution has key implications for modelling of magma dynamics and eruption ages using zircon age distributions.
Pieter Vermeesch, Noah McLean, Anton Vaks, Tzahi Golan, Sebastian F. M. Breitenbach, and Randall Parris
EGUsphere, https://doi.org/10.5194/egusphere-2025-432, https://doi.org/10.5194/egusphere-2025-432, 2025
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U-Pb dating of cave sediments has provided important new time constraints on the evolution of cave-dwelling organisms (including early humans), and of Earth's climate during the past 5 million years. This paper shows that the most common type of U-Pb dating, which uses 238U and 206Pb, can be inaccurate beyond 2 million years ago. It proposes an alternative type of U-Pb dating, using 235U and 207Pb, as a more accurate alternative.
Christoph Glotzbach and Todd A. Ehlers
Geochronology, 6, 697–717, https://doi.org/10.5194/gchron-6-697-2024, https://doi.org/10.5194/gchron-6-697-2024, 2024
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The (U–Th–Sm) / He dating method helps understand the cooling history of rocks. Synthetic modelling experiments were conducted to explore factors affecting in situ vs. whole-grain (U–Th) / He dates. In situ dates are often 30 % older than whole-grain dates, whereas very rapid cooling makes helium loss negligible, resulting in similar whole-grain and in situ dates. In addition, in situ data can reveal cooling histories even from a single grain by measuring helium distributions.
Steven Denyszyn, Donald W. Davis, and Denis Fougerouse
Geochronology, 6, 607–619, https://doi.org/10.5194/gchron-6-607-2024, https://doi.org/10.5194/gchron-6-607-2024, 2024
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Decay of U to Pb in baddeleyite is used for dating mafic rocks, but some daughter Pb atoms can be ejected out of the crystal, resulting in ages that seem too young. Atom probe tomography was used to map U and Pb atoms in 3D within baddeleyite crystals and estimate the average distance that Pb atoms are displaced by recoil. This allows us to test the relationship between crystal size and apparent age. There is also evidence for clustering of U atoms, inviting more work on how this may occur.
Jesús Muñoz-Montecinos, Andrea Giuliani, Senan Oesch, Silvia Volante, Bradley Peters, and Whitney Behr
Geochronology, 6, 585–605, https://doi.org/10.5194/gchron-6-585-2024, https://doi.org/10.5194/gchron-6-585-2024, 2024
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Dating the roots of plate boundaries is essential for understanding geologic processes, but geochemical limitations, particularly in young mafic rocks, make this challenging. Advancements in mass spectrometry now enable high-resolution analysis of micro-domains. We assess these limitations by dating rocks from Syros. Multi-phase mineral analysis improves age uncertainty 6-fold. We emphasize the importance of the local geologic context and propose strategies to mitigate uncertainties.
Jesse R. Reimink, Renan Beckman, Erik Schoonover, Max Lloyd, Joshua Garber, Joshua H. F. L. Davies, Alexander Cerminaro, Morgann G. Perrot, and Andrew J. Smye
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-27, https://doi.org/10.5194/gchron-2024-27, 2024
Revised manuscript accepted for GChron
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This manuscript presents a new method to date geological events affecting sedimentary rocks. This method relies on the potential for the zircon U-Pb system to be disturbed during fluid-flow, alteration, and metamorphic events in sedimentary rocks. This manuscript presents synthetic datasets for testing the accuracy and precision of the discordance dating method, as well as data from detrital zircons found in the contact metamorphic aureole surround the Alta Stock.
Andrew L. Gorin, Joshua M. Gorin, Marie Bergelin, and David L. Shuster
Geochronology, 6, 521–540, https://doi.org/10.5194/gchron-6-521-2024, https://doi.org/10.5194/gchron-6-521-2024, 2024
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The multiple-diffusion domain (MDD) model quantifies the temperature dependence of noble gas diffusivity in minerals. However, current methods for tuning MDD parameters can yield biased results, leading to underestimates of sample temperatures through geologic time. Our "MDD Tool Kit" software optimizes all MDD parameters simultaneously, overcoming these biases. We then apply this software to a previously published 40Ar/39Ar dataset (Wong, 2023) to showcase its efficacy.
Niklas Hohmann, David De Vleeschouwer, Sietske Batenburg, and Emilia Jarochowska
EGUsphere, https://doi.org/10.5194/egusphere-2024-2857, https://doi.org/10.5194/egusphere-2024-2857, 2024
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Age-depth models assign ages to sampling locations (e.g., in drill cores), making them crucial to determined timing and pace of past changes. We present two methods to estimate age-depth models from sedimentological and stratigraphic information, resulting in richer and more empirically realistic age-depth models. As a use case, we determine (1) the timing of the Frasnian-Famennian extinction and (2) examine the duration of PETM, an potential deep time analogue for anthropogenic climate change.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
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We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Marcel Guillong, Elias Samankassou, Inigo A. Müller, Dawid Szymanowski, Nathan Looser, Lorenzo Tavazzani, Óscar Merino-Tomé, Juan R. Bahamonde, Yannick Buret, and Maria Ovtcharova
Geochronology, 6, 465–474, https://doi.org/10.5194/gchron-6-465-2024, https://doi.org/10.5194/gchron-6-465-2024, 2024
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RA138 is a new reference material for U–Pb dating of carbonate samples via laser ablation inductively coupled plasma mass spectrometry. RA138 exhibits variable U–Pb ratios and consistent U content, resulting in a precise isochron with low uncertainty. Isotope dilution thermal ionization mass spectrometry analyses fix a reference age of 321.99 ± 0.65 Ma. This research advances our ability to date carbonate samples accurately, providing insights into geological processes and historical timelines.
Hevelyn S. Monteiro, Kenneth A. Farley, and Paulo M. Vasconcelos
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-13, https://doi.org/10.5194/gchron-2024-13, 2024
Revised manuscript accepted for GChron
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We have built a database of (U-Th)/He ages and U and Th contents of goethites from various weathering environments. The database contains 2597 (U-Th)/He ages of goethites from 10 countries. The findings presented in this manuscript contribute insights onto the distribution of dated goethites from different environments globally and into the Earth's Cenozoic weathering history.
Birk Härtel and Eva Enkelmann
Geochronology, 6, 429–448, https://doi.org/10.5194/gchron-6-429-2024, https://doi.org/10.5194/gchron-6-429-2024, 2024
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We present a new data analysis workflow for thermochronological data based on plots of radiogenic daughter vs. radioactive parent concentration. The daughter–parent relationship helps to identify the sources of age variation. Our workflow classifies the daughter–parent relationship and provides further suggestions, e.g., if a dataset can be described by a sample age and which type of sample age to report. We also introduce Incaplot, which is software for creating daughter–parent plots.
Pieter Vermeesch
Geochronology, 6, 397–407, https://doi.org/10.5194/gchron-6-397-2024, https://doi.org/10.5194/gchron-6-397-2024, 2024
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The age of some geological materials can be estimated from the ratio of certain radiogenic "daughter" isotopes to their radioactive "parent". However, in many cases, the age estimation process is complicated by the presence of an inherited component of non-radiogenic daughter isotopes. This paper presents an improved algorithm to estimate the radiogenic and non-radiogenic components, either separately or jointly.
André Navin Paul, Anders Lindskog, and Urs Schaltegger
Geochronology, 6, 325–335, https://doi.org/10.5194/gchron-6-325-2024, https://doi.org/10.5194/gchron-6-325-2024, 2024
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The “Likhall” bed helps to constrain the timing of increased meteorite bombardment of the Earth during the Ordovician period. It is important to understand the timing of this meteorite bombardment when attempting to correlate it with biodiversity changes during the Ordovician period. Calibrating a good age for the “Likhall” bed is, however, challenging and benefited in this study from advances in sample preparation.
Megan A. Mueller, Alexis Licht, Andreas Möller, Cailey B. Condit, Julie C. Fosdick, Faruk Ocakoğlu, and Clay Campbell
Geochronology, 6, 265–290, https://doi.org/10.5194/gchron-6-265-2024, https://doi.org/10.5194/gchron-6-265-2024, 2024
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Sedimentary provenance refers to the study of the origin of sedimentary rocks, tracing where sediment particles originated. Common sedimentary provenance techniques struggle to track mafic igneous and metamorphic rock sources and rutile forms in these rock types. We use rutile form ancient sedimentary rocks in Türkiye to present new recommendations and workflows for integrating rutile U–Pb ages and chemical composition into an accurate sedimentary provenance reconstruction.
Ruohong Jiao, Shengze Cai, and Jean Braun
Geochronology, 6, 227–245, https://doi.org/10.5194/gchron-6-227-2024, https://doi.org/10.5194/gchron-6-227-2024, 2024
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We demonstrate a machine learning method to estimate the temperature changes in the Earth's crust over time. The method respects physical laws and conditions imposed by users. By using observed rock cooling ages as constraints, the method can be used to estimate the tectonic and landscape evolution of the Earth. We show the applications of the method using a synthetic rock uplift model in 1D and an evolution model of a real mountain range in 3D.
Erin E. Donaghy, Michael P. Eddy, Federico Moreno, and Mauricio Ibañez-Mejia
Geochronology, 6, 89–106, https://doi.org/10.5194/gchron-6-89-2024, https://doi.org/10.5194/gchron-6-89-2024, 2024
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Chemical abrasion (CA) is a technique that reduces or eliminates the effects of Pb loss in zircon U–Pb geochronology. However, CA has yet to be applied to large-n detrital zircon (DZ) analyses. We show that CA does not negatively impact or systematically bias U–Pb dates, improves the resolution of age populations defined by 206Pb/238U dates, and increases the percentage of concordant analyses in age populations defined by 207Pb/206Pb dates.
Glenn R. Sharman and Matthew A. Malkowski
Geochronology, 6, 37–51, https://doi.org/10.5194/gchron-6-37-2024, https://doi.org/10.5194/gchron-6-37-2024, 2024
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The mineral zircon is widely used to determine the age of rocks based on the radioactive decay of U to Pb, but the measured U–Pb date can be too young if the zircon loses Pb. We present a method for estimating the distribution of apparent Pb loss by mathematical convolution. Applying this approach to 10 samples illustrates contrasting patterns of apparent Pb loss. This study highlights the importance of quantifying Pb loss to better understand its potential effects on zircon U–Pb dates.
Stijn Glorie, Sarah E. Gilbert, Martin Hand, and Jarred C. Lloyd
Geochronology, 6, 21–36, https://doi.org/10.5194/gchron-6-21-2024, https://doi.org/10.5194/gchron-6-21-2024, 2024
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Radiometric dating methods, involving laser ablation as the sample introduction, require robust calibrations to reference materials with similar ablation properties to the analysed samples. In the case of the rubidium–strontium dating method, calibrations are often conducted to nano powder with different ablation characteristics than the crystalline minerals. We describe the limitations of this approach and recommend an alternative calibration method involving natural minerals.
Alex Lipp and Pieter Vermeesch
Geochronology, 5, 263–270, https://doi.org/10.5194/gchron-5-263-2023, https://doi.org/10.5194/gchron-5-263-2023, 2023
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We propose using the Wasserstein-2 distance (W2) as an alternative to the widely used Kolmogorov–Smirnov (KS) statistic for analysing distributional data in geochronology. W2 measures the horizontal distance between observations, while KS measures vertical differences in cumulative distributions. Using case studies, we find that W2 is preferable in scenarios where the absolute age differences in observations provide important geological information. W2 has been added to the R package IsoplotR.
W. Marijn van der Meij, Arnaud J. A. M. Temme, Steven A. Binnie, and Tony Reimann
Geochronology, 5, 241–261, https://doi.org/10.5194/gchron-5-241-2023, https://doi.org/10.5194/gchron-5-241-2023, 2023
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We present our model ChronoLorica. We coupled the original Lorica model, which simulates soil and landscape evolution, with a geochronological module that traces cosmogenic nuclide inventories and particle ages through simulations. These properties are often measured in the field to determine rates of landscape change. The coupling enables calibration of the model and the study of how soil, landscapes and geochronometers change under complex boundary conditions such as intensive land management.
Michael C. Sitar and Ryan J. Leary
Geochronology, 5, 109–126, https://doi.org/10.5194/gchron-5-109-2023, https://doi.org/10.5194/gchron-5-109-2023, 2023
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We developed code to automatically and semi-automatically measure dimensions of detrital mineral grains in reflected-light images saved at laser ablation–inductively coupled plasma–mass spectrometry facilities that use Chromium targeting software. Our code uses trained deep learning models to segment grain images with greater accuracy than is achievable using other segmentation techniques. We implement our code in Jupyter notebooks which can also be run online via Google Colab.
Peter E. Martin, James R. Metcalf, and Rebecca M. Flowers
Geochronology, 5, 91–107, https://doi.org/10.5194/gchron-5-91-2023, https://doi.org/10.5194/gchron-5-91-2023, 2023
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There is currently no standardized method of performing uncertainty propagation in the (U–Th) / He system, causing data interpretation difficulties. We present two methods of uncertainty propagation and describe free, open-source software (HeCalc) to apply them. Compilation of real data using only analytical uncertainty as well as 2 % and 5 % uncertainties in FT yields respective median relative date uncertainties of 2.9 %, 3.3 %, and 5.0 % for apatites and 1.7 %, 3.3 %, and 5.0 % for zircons.
Stella Birlo, Wojciech Tylmann, and Bernd Zolitschka
Geochronology, 5, 65–90, https://doi.org/10.5194/gchron-5-65-2023, https://doi.org/10.5194/gchron-5-65-2023, 2023
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Sediment cores from the volcanic lake Holzmaar provide a very precise chronology based on tree-ring-like annual laminations or varves. We statistically combine this varve chronology with radiometric dating and tested three different methods to upgrade the age–depth model. However, only one of the three methods tested improved the dating accuracy considerably. With this work, an overview of different age integration methods is discussed and made available for increased future demands.
Peter van der Beek and Taylor F. Schildgen
Geochronology, 5, 35–49, https://doi.org/10.5194/gchron-5-35-2023, https://doi.org/10.5194/gchron-5-35-2023, 2023
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Thermochronometric data can provide unique insights into the patterns of rock exhumation and the driving mechanisms of landscape evolution. Several well-established thermal models allow for a detailed exploration of how cooling rates evolved in a limited area or along a transect, but more regional analyses have been challenging. We present age2exhume, a thermal model that can be used to rapidly provide a synoptic overview of exhumation rates from large regional thermochronologic datasets.
Marianna Corre, Arnaud Agranier, Martine Lanson, Cécile Gautheron, Fabrice Brunet, and Stéphane Schwartz
Geochronology, 4, 665–681, https://doi.org/10.5194/gchron-4-665-2022, https://doi.org/10.5194/gchron-4-665-2022, 2022
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This study is focused on the accurate measurement of U and Th by wet chemistry and laser ablation methods to improve (U–Th)/He dating of magnetite and spinel. The low U–Th content and the lack of specific U–Th standards significantly limit the accuracy of (U–Th)/He dating. Obtained U–Th results on natural and synthetic magnetite and aluminous spinel samples analyzed by wet chemistry methods and LA-ICP-MS sampling have important implications for the (U–Th)/He method and dates interpretation.
Aratz Beranoaguirre, Iuliana Vasiliev, and Axel Gerdes
Geochronology, 4, 601–616, https://doi.org/10.5194/gchron-4-601-2022, https://doi.org/10.5194/gchron-4-601-2022, 2022
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U–Pb dating by the in situ laser ablation mass spectrometry (LA-ICPMS) technique requires reference materials of the same nature as the samples to be analysed. Here, we have explored the suitability of using carbonate materials as a reference for sulfates, since there is no sulfate reference material. The results we obtained are satisfactory, and thus, from now on, the sulfates can also be analysed.
Pieter Vermeesch
Geochronology, 4, 561–576, https://doi.org/10.5194/gchron-4-561-2022, https://doi.org/10.5194/gchron-4-561-2022, 2022
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Secondary ion mass spectrometry (SIMS) is the oldest and most sensitive analytical technique for in situ U–Pb geochronology. This paper introduces a new algorithm for SIMS data reduction that treats data as
compositional data, which means that the relative abundances of 204Pb, 206Pb, 207Pb, and 238Pb are processed within a tetrahedral data space or
simplex. The new method is implemented in an eponymous computer programme that is compatible with the two dominant types of SIMS instruments.
Emily H. G. Cooperdock, Florian Hofmann, Ryley M. C. Tibbetts, Anahi Carrera, Aya Takase, and Aaron J. Celestian
Geochronology, 4, 501–515, https://doi.org/10.5194/gchron-4-501-2022, https://doi.org/10.5194/gchron-4-501-2022, 2022
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Apatite and zircon are the most widely used minerals for dating rocks, but they can be difficult to identify in some crushed rock samples. Incorrect mineral identification results in wasted analytical resources and inaccurate data. We show how X-ray computed tomography can be used to efficiently and accurately distinguish apatite from zircon based on density variations, and provide non-destructive 3D grain-specific size, shape, and inclusion information for improved data quality.
Dale R. Issler, Kalin T. McDannell, Paul B. O'Sullivan, and Larry S. Lane
Geochronology, 4, 373–397, https://doi.org/10.5194/gchron-4-373-2022, https://doi.org/10.5194/gchron-4-373-2022, 2022
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Phanerozoic sedimentary rocks of northern Canada have compositionally heterogeneous detrital apatite with high age dispersion caused by differential thermal annealing. Discrete apatite fission track kinetic populations with variable annealing temperatures are defined using elemental data but are poorly resolved using conventional parameters. Inverse thermal modelling of samples from northern Yukon reveals a record of multiple heating–cooling cycles consistent with geological constraints.
Michael Dietze, Sebastian Kreutzer, Margret C. Fuchs, and Sascha Meszner
Geochronology, 4, 323–338, https://doi.org/10.5194/gchron-4-323-2022, https://doi.org/10.5194/gchron-4-323-2022, 2022
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The R package sandbox is a collection of functions that allow the creation, sampling and analysis of fully virtual sediment sections, like having a virtual twin of real-world deposits. This article introduces the concept, features, and workflows required to use sandbox. It shows how a real-world sediment section can be mapped into the model and subsequently addresses a series of theoretical and practical questions, exploiting the flexibility of the model framework.
Gregor Pfalz, Bernhard Diekmann, Johann-Christoph Freytag, Liudmila Syrykh, Dmitry A. Subetto, and Boris K. Biskaborn
Geochronology, 4, 269–295, https://doi.org/10.5194/gchron-4-269-2022, https://doi.org/10.5194/gchron-4-269-2022, 2022
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We use age–depth modeling systems to understand the relationship between age and depth in lake sediment cores. However, depending on which modeling system we use, the model results may vary. We provide a tool to link different modeling systems in an interactive computational environment and make their results comparable. We demonstrate the power of our tool by highlighting three case studies in which we test our application for single-sediment cores and a collection of multiple sediment cores.
Andrea Madella, Christoph Glotzbach, and Todd A. Ehlers
Geochronology, 4, 177–190, https://doi.org/10.5194/gchron-4-177-2022, https://doi.org/10.5194/gchron-4-177-2022, 2022
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Cooling ages date the time at which minerals cross a certain isotherm on the way up to Earth's surface. Such ages can be measured from bedrock material and river sand. If spatial variations in bedrock ages are known in a river catchment, the spatial distribution of erosion can be inferred from the distribution of the ages measured from the river sand grains. Here we develop a new tool to help such analyses, with particular emphasis on quantifying uncertainties due to sample size.
Yang Li and Pieter Vermeesch
Geochronology, 3, 415–420, https://doi.org/10.5194/gchron-3-415-2021, https://doi.org/10.5194/gchron-3-415-2021, 2021
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A conventional isochron is a straight-line fit to two sets of isotopic ratios, D/d and P/d, where P is the radioactive parent, D is the radiogenic daughter, and d is a second isotope of the daughter element. The slope of this line is proportional to the age of the system. An inverse isochron is a linear fit through d/D and P/D. The horizontal intercept of this line is inversely proportional to the age. The latter approach is preferred when d<D, which is the case in Re–Os and K–Ca geochronology.
Cécile Gautheron, Rosella Pinna-Jamme, Alexis Derycke, Floriane Ahadi, Caroline Sanchez, Frédéric Haurine, Gael Monvoisin, Damien Barbosa, Guillaume Delpech, Joseph Maltese, Philippe Sarda, and Laurent Tassan-Got
Geochronology, 3, 351–370, https://doi.org/10.5194/gchron-3-351-2021, https://doi.org/10.5194/gchron-3-351-2021, 2021
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Apatite and zircon (U–Th) / He thermochronology is now a mainstream tool to reconstruct Earth's evolution through the history of cooling and exhumation over the first dozen kilometers. The geological implications of these data rely on the precision of measurements of He, U, Th, and Sm contents in crystals. This technical note documents the methods for He thermochronology developed at the GEOPS laboratory, Paris-Saclay University, that allow (U–Th) / He data to be obtained with precision.
Kalin T. McDannell and Dale R. Issler
Geochronology, 3, 321–335, https://doi.org/10.5194/gchron-3-321-2021, https://doi.org/10.5194/gchron-3-321-2021, 2021
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We generated a synthetic dataset applying published kinetic models and distinct annealing kinetics for the apatite fission track and (U–Th)/He methods using a predetermined thermal history. We then tested how well the true thermal history could be recovered under different data interpretation schemes and geologic constraint assumptions using the Bayesian QTQt software. Our results demonstrate that multikinetic data increase time–temperature resolution and can constrain complex thermal histories.
Birk Härtel, Raymond Jonckheere, Bastian Wauschkuhn, and Lothar Ratschbacher
Geochronology, 3, 259–272, https://doi.org/10.5194/gchron-3-259-2021, https://doi.org/10.5194/gchron-3-259-2021, 2021
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We carried out thermal annealing experiments between 500 and 1000 °C to determine the closure temperature of radiation-damage annealing in zircon (ZrSiO4). Our results show that the different Raman bands of zircon respond differently to annealing. The repair is highest for the external rotation Raman band near 356.6 cm−1. The closure temperature estimates range from 250 to 370 °C for different bands. The differences in closure temperatures offer the prospect of multi-T zircon Raman dating.
Pieter Vermeesch
Geochronology, 3, 247–257, https://doi.org/10.5194/gchron-3-247-2021, https://doi.org/10.5194/gchron-3-247-2021, 2021
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This paper shows that the current practice of filtering discordant U–Pb data based on the relative difference between the 206Pb/238U and 207Pb/206Pb ages is just one of several possible approaches to the problem and demonstrably not the best one. An alternative approach is to define discordance in terms of isotopic composition, as a log ratio distance between the measurement and the concordia line. Application to real data indicates that this reduces the positive bias of filtered age spectra.
Blair Schoene, Michael P. Eddy, C. Brenhin Keller, and Kyle M. Samperton
Geochronology, 3, 181–198, https://doi.org/10.5194/gchron-3-181-2021, https://doi.org/10.5194/gchron-3-181-2021, 2021
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We compare two published U–Pb and 40Ar / 39Ar geochronologic datasets to produce eruption rate models for the Deccan Traps large igneous province. Applying the same approach to each dataset, the resulting models agree well, but the higher-precision U–Pb dataset results in a more detailed eruption model than the lower-precision 40Ar / 39Ar data. We explore sources of geologic uncertainty and reiterate the importance of systematic uncertainties in comparing U–Pb and 40Ar / 39Ar datasets.
Nicholas P. McKay, Julien Emile-Geay, and Deborah Khider
Geochronology, 3, 149–169, https://doi.org/10.5194/gchron-3-149-2021, https://doi.org/10.5194/gchron-3-149-2021, 2021
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This paper describes geoChronR, an R package that streamlines the process of quantifying age uncertainties, propagating uncertainties through several common analyses, and visualizing the results. In addition to describing the structure and underlying theory of the package, we present five real-world use cases that illustrate common workflows in geoChronR. geoChronR is built on the Linked PaleoData framework, is open and extensible, and we welcome feedback and contributions from the community.
Leonie Peti, Kathryn E. Fitzsimmons, Jenni L. Hopkins, Andreas Nilsson, Toshiyuki Fujioka, David Fink, Charles Mifsud, Marcus Christl, Raimund Muscheler, and Paul C. Augustinus
Geochronology, 2, 367–410, https://doi.org/10.5194/gchron-2-367-2020, https://doi.org/10.5194/gchron-2-367-2020, 2020
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Orakei Basin – a former maar lake in Auckland, New Zealand – provides an outstanding sediment record over the last ca. 130 000 years, but an age model is required to allow the reconstruction of climate change and volcanic eruptions contained in the sequence. To construct a relationship between depth in the sediment core and age of deposition, we combined tephrochronology, radiocarbon dating, luminescence dating, and the relative intensity of the paleomagnetic field in a Bayesian age–depth model.
Roger Powell, Eleanor C. R. Green, Estephany Marillo Sialer, and Jon Woodhead
Geochronology, 2, 325–342, https://doi.org/10.5194/gchron-2-325-2020, https://doi.org/10.5194/gchron-2-325-2020, 2020
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The standard approach to isochron calculation assumes that the distribution of uncertainties on the data arising from isotopic analysis is strictly Gaussian. This excludes datasets that have more scatter, even though many appear to have age significance. Our new approach requires only that the central part of the uncertainty distribution of the data defines a "spine" in the trend of the data. A robust statistics approach is used to locate the spine, and an implementation in Python is given.
Simon J. E. Large, Jörn-Frederik Wotzlaw, Marcel Guillong, Albrecht von Quadt, and Christoph A. Heinrich
Geochronology, 2, 209–230, https://doi.org/10.5194/gchron-2-209-2020, https://doi.org/10.5194/gchron-2-209-2020, 2020
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The integration of zircon geochemistry and U–Pb geochronology (petrochronology) allows us to improve our understanding of magmatic processes. Here we could reconstruct the ~300 kyr evolution of the magma reservoir that sourced the magmas, fluids and metals to form the Batu Hijau porphyry Cu–Au deposit. The application of in situ LA-ICP-MS and high-precision CA–ID–TIMS geochronology to the same zircons further allowed an assessment of the strengths and limitations of the different techniques.
Julia Kalanke, Jens Mingram, Stefan Lauterbach, Ryskul Usubaliev, Rik Tjallingii, and Achim Brauer
Geochronology, 2, 133–154, https://doi.org/10.5194/gchron-2-133-2020, https://doi.org/10.5194/gchron-2-133-2020, 2020
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Our study presents the first seasonally laminated (varved) sediment record covering almost the entire Holocene in high mountainous arid Central Asia. The established floating varve chronology is confirmed by two terrestrial radiocarbon dates, whereby aquatic radiocarbon dates reveal decreasing reservoir ages up core. Changes in seasonal deposition characteristics are attributed to changes in runoff and precipitation and/or to evaporative summer conditions.
Pieter Vermeesch
Geochronology, 2, 119–131, https://doi.org/10.5194/gchron-2-119-2020, https://doi.org/10.5194/gchron-2-119-2020, 2020
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The U–Pb method is one of the most powerful and versatile methods in the geochronological toolbox. With two isotopes of uranium decaying to two different isotopes of lead, the U–Pb method offers an internal quality control that is absent from most other geochronological techniques. U-bearing minerals often contain significant amounts of Th, which decays to a third Pb isotope. This paper presents an algorithm to jointly process all three chronometers at once.
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Short summary
Marine sediments are excellent archives for reconstructing past changes in climate and ocean circulation. Yet, dating uncertainties, particularly during the 20th century, pose major challenges. Here we propose a novel chronostratigraphic approach that uses anthropogenic signals, such as the oceanic 13C Suess effect and spheroidal carbonaceous fly-ash particles, to reduce age model uncertainties in high-resolution marine archives over the 20th century.
Marine sediments are excellent archives for reconstructing past changes in climate and ocean...
