Articles | Volume 8, issue 3
https://doi.org/10.5194/gchron-8-495-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-8-495-2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
U-Pb dating of sub-ng g−1 U garnet by LA-MC-ICP-MS
Aratz Beranoaguirre
CORRESPONDING AUTHOR
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-University Frankfurt, 60438 Frankfurt am Main, Germany
Goethe-University Frankfurt, Department of Geosciences, 60438 Frankfurt am Main, Germany
Leo J. Millonig
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-University Frankfurt, 60438 Frankfurt am Main, Germany
Goethe-University Frankfurt, Department of Geosciences, 60438 Frankfurt am Main, Germany
Richard Albert
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-University Frankfurt, 60438 Frankfurt am Main, Germany
Goethe-University Frankfurt, Department of Geosciences, 60438 Frankfurt am Main, Germany
Horst R. Marschall
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-University Frankfurt, 60438 Frankfurt am Main, Germany
Goethe-University Frankfurt, Department of Geosciences, 60438 Frankfurt am Main, Germany
Axel Gerdes
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-University Frankfurt, 60438 Frankfurt am Main, Germany
Goethe-University Frankfurt, Department of Geosciences, 60438 Frankfurt am Main, Germany
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Garnet U–Pb dating is useful for dating geologic events. However, contamination by U-rich minerals included in garnet is a risk. Inclusions are often spotted by high-U spikes or large errors in the age. We dated garnets in metamorphic rocks and calculated ages 10–15 Myr older than expected, reflecting contamination by the mineral zircon. We provide recommendations for identifying contamination and suggest that the bulk dating of zircon inclusions in garnet may also provide valuable information.
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U–Pb dating by the in situ laser ablation mass spectrometry (LA-ICPMS) technique requires reference materials of the same nature as the samples to be analysed. Here, we have explored the suitability of using carbonate materials as a reference for sulfates, since there is no sulfate reference material. The results we obtained are satisfactory, and thus, from now on, the sulfates can also be analysed.
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Garnet U–Pb dating is useful for dating geologic events. However, contamination by U-rich minerals included in garnet is a risk. Inclusions are often spotted by high-U spikes or large errors in the age. We dated garnets in metamorphic rocks and calculated ages 10–15 Myr older than expected, reflecting contamination by the mineral zircon. We provide recommendations for identifying contamination and suggest that the bulk dating of zircon inclusions in garnet may also provide valuable information.
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U–Pb dating by the in situ laser ablation mass spectrometry (LA-ICPMS) technique requires reference materials of the same nature as the samples to be analysed. Here, we have explored the suitability of using carbonate materials as a reference for sulfates, since there is no sulfate reference material. The results we obtained are satisfactory, and thus, from now on, the sulfates can also be analysed.
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Short summary
We present a high-sensitivity laser ablation multi-collector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS) method for in-situ U–Pb dating of garnet with under 1 ng g⁻¹ U. Using ion counters, geologically meaningful ages are obtained from garnets with up to three orders of magnitude less uranium than standard in-situ U–Pb dating. This expands garnet petrochronology to low-U metamorphic rocks.
We present a high-sensitivity laser ablation multi-collector inductively coupled plasma mass...