Articles | Volume 7, issue 3
https://doi.org/10.5194/gchron-7-409-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-7-409-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Interlaboratory reproducibility of ID-TIMS U–Pb geochronology evaluated with a pre-spiked natural zircon solution
Dawid Szymanowski
CORRESPONDING AUTHOR
Institute of Geochemistry and Petrology, Department of Earth and Planetary Sciences, ETH Zurich, 8092 Zurich, Switzerland
Jörn-Frederik Wotzlaw
Institute of Geochemistry and Petrology, Department of Earth and Planetary Sciences, ETH Zurich, 8092 Zurich, Switzerland
Maria Ovtcharova
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Blair Schoene
Department of Geosciences, Princeton University, Princeton, New Jersey 08544, USA
Urs Schaltegger
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Mark D. Schmitz
Department of Geosciences, Boise State University, Boise, Idaho 83725, USA
Ryan B. Ickert
Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, Indiana 47907, USA
Cyril Chelle-Michou
Institute of Geochemistry and Petrology, Department of Earth and Planetary Sciences, ETH Zurich, 8092 Zurich, Switzerland
Kevin R. Chamberlain
Department of Geology and Geophysics, University of Wyoming, Laramie, Wyoming 82071, USA
James L. Crowley
Department of Geosciences, Boise State University, Boise, Idaho 83725, USA
Joshua H. F. L. Davies
Département des Sciences de la Terre et de l'Atmosphère/Geotop, Université du Québec à Montréal, Québec H2X 3Y7, Canada
Michael P. Eddy
Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, Indiana 47907, USA
Sean P. Gaynor
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Department of Geosciences, Princeton University, Princeton, New Jersey 08544, USA
Alexandra Käßner
Institut für Mineralogie, TU Bergakademie Freiberg, 09599 Freiberg, Germany
Michael T. Mohr
Department of Geosciences, Boise State University, Boise, Idaho 83725, USA
André N. Paul
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Jahandar Ramezani
Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
Simon Tapster
Geochronology and Tracers Facility, British Geological Survey, Keyworth, Nottingham, NG12 5GG, United Kingdom
Marion Tichomirowa
Institut für Mineralogie, TU Bergakademie Freiberg, 09599 Freiberg, Germany
Albrecht von Quadt
Institute of Geochemistry and Petrology, Department of Earth and Planetary Sciences, ETH Zurich, 8092 Zurich, Switzerland
Corey J. Wall
Pacific Centre for Isotopic and Geochemical Research, Department of Earth, Ocean and Atmospheric Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
Related authors
Chetan Nathwani, Dawid Szymanowski, Lorenzo Tavazzani, Sava Markovic, Adrianna L. Virmond, and Cyril Chelle-Michou
Geochronology, 7, 15–33, https://doi.org/10.5194/gchron-7-15-2025, https://doi.org/10.5194/gchron-7-15-2025, 2025
Short summary
Short summary
We performed a statistical analysis of high-precision U–Pb zircon age distributions. This reveals that volcanic and porphyry zircon age distributions are skewed to younger ages, whereas plutonic age distributions are skewed to older ages. We show that this is caused by truncation of zircon crystallisation by magma evacuation rather than differences in magmatic flux. Our contribution has key implications for modelling of magma dynamics and eruption ages using zircon age distributions.
Sava Markovic, Jörn-Frederik Wotzlaw, Dawid Szymanowski, Joakim Reuteler, Peng Zeng, and Cyril Chelle-Michou
Geochronology, 6, 621–638, https://doi.org/10.5194/gchron-6-621-2024, https://doi.org/10.5194/gchron-6-621-2024, 2024
Short summary
Short summary
We present a pioneering method for high-precision U–Pb dating of individual growth zones in zircon. These micrometer zones in single grains can record key geological processes from magma priming prior to eruptions to planetary formation, yet dating them at high precision has so far been technically challenging. Our method employs two cutting-edge microbeam techniques to microsample these growth zones for high-precision dating, allowing us to tackle a number of outstanding research questions.
Marcel Guillong, Elias Samankassou, Inigo A. Müller, Dawid Szymanowski, Nathan Looser, Lorenzo Tavazzani, Óscar Merino-Tomé, Juan R. Bahamonde, Yannick Buret, and Maria Ovtcharova
Geochronology, 6, 465–474, https://doi.org/10.5194/gchron-6-465-2024, https://doi.org/10.5194/gchron-6-465-2024, 2024
Short summary
Short summary
RA138 is a new reference material for U–Pb dating of carbonate samples via laser ablation inductively coupled plasma mass spectrometry. RA138 exhibits variable U–Pb ratios and consistent U content, resulting in a precise isochron with low uncertainty. Isotope dilution thermal ionization mass spectrometry analyses fix a reference age of 321.99 ± 0.65 Ma. This research advances our ability to date carbonate samples accurately, providing insights into geological processes and historical timelines.
Alyssa J. McKanna, Blair Schoene, and Dawid Szymanowski
Geochronology, 6, 1–20, https://doi.org/10.5194/gchron-6-1-2024, https://doi.org/10.5194/gchron-6-1-2024, 2024
Short summary
Short summary
Acid leaching is used to remove radiation-damaged portions of zircon crystals prior to U–Pb dating to improve the accuracy of datasets. We test how the temperature and duration of acid leaching affect geochronological and geochemical outcomes. We build a framework that relates radiation damage, zircon solubility, and Pb loss.
Jesse R. Reimink, Renan Beckman, Erik Schoonover, Max Lloyd, Joshua Garber, Joshua H. F. L. Davies, Alexander Cerminaro, Morgann G. Perrot, and Andrew Smye
Geochronology, 7, 369–385, https://doi.org/10.5194/gchron-7-369-2025, https://doi.org/10.5194/gchron-7-369-2025, 2025
Short summary
Short summary
This article presents a new method to date geological events affecting sedimentary rocks. This method relies on the potential for the zircon U-Pb system to be disturbed during fluid-flow, alteration, and metamorphic events in sedimentary rocks. This article presents synthetic datasets for benchmarking the accuracy and precision of the discordance dating method, as well as data from detrital zircons found in the contact metamorphic aureole surround the Alta stock.
Trystan M. Herriott, James L. Crowley, Marwan A. Wartes, David L. LePain, and Mark D. Schmitz
EGUsphere, https://doi.org/10.5194/egusphere-2025-727, https://doi.org/10.5194/egusphere-2025-727, 2025
Short summary
Short summary
Paired low- and high-precision U–Pb geochronology data are evaluated to better understand young bias in laser ablation dates and detrital zircon maximum depositional ages (MDAs). We redefine the reference for MDA accuracy as the true age of the youngest analyzed population and reframe MDA algorithm assessments around validity. This study highlights opportunities to refine MDA research and anticipates continued community efforts to further improve accuracy of laser ablation zircon geochronology.
Chetan Nathwani, Dawid Szymanowski, Lorenzo Tavazzani, Sava Markovic, Adrianna L. Virmond, and Cyril Chelle-Michou
Geochronology, 7, 15–33, https://doi.org/10.5194/gchron-7-15-2025, https://doi.org/10.5194/gchron-7-15-2025, 2025
Short summary
Short summary
We performed a statistical analysis of high-precision U–Pb zircon age distributions. This reveals that volcanic and porphyry zircon age distributions are skewed to younger ages, whereas plutonic age distributions are skewed to older ages. We show that this is caused by truncation of zircon crystallisation by magma evacuation rather than differences in magmatic flux. Our contribution has key implications for modelling of magma dynamics and eruption ages using zircon age distributions.
Sava Markovic, Jörn-Frederik Wotzlaw, Dawid Szymanowski, Joakim Reuteler, Peng Zeng, and Cyril Chelle-Michou
Geochronology, 6, 621–638, https://doi.org/10.5194/gchron-6-621-2024, https://doi.org/10.5194/gchron-6-621-2024, 2024
Short summary
Short summary
We present a pioneering method for high-precision U–Pb dating of individual growth zones in zircon. These micrometer zones in single grains can record key geological processes from magma priming prior to eruptions to planetary formation, yet dating them at high precision has so far been technically challenging. Our method employs two cutting-edge microbeam techniques to microsample these growth zones for high-precision dating, allowing us to tackle a number of outstanding research questions.
Marcel Guillong, Elias Samankassou, Inigo A. Müller, Dawid Szymanowski, Nathan Looser, Lorenzo Tavazzani, Óscar Merino-Tomé, Juan R. Bahamonde, Yannick Buret, and Maria Ovtcharova
Geochronology, 6, 465–474, https://doi.org/10.5194/gchron-6-465-2024, https://doi.org/10.5194/gchron-6-465-2024, 2024
Short summary
Short summary
RA138 is a new reference material for U–Pb dating of carbonate samples via laser ablation inductively coupled plasma mass spectrometry. RA138 exhibits variable U–Pb ratios and consistent U content, resulting in a precise isochron with low uncertainty. Isotope dilution thermal ionization mass spectrometry analyses fix a reference age of 321.99 ± 0.65 Ma. This research advances our ability to date carbonate samples accurately, providing insights into geological processes and historical timelines.
André Navin Paul, Anders Lindskog, and Urs Schaltegger
Geochronology, 6, 325–335, https://doi.org/10.5194/gchron-6-325-2024, https://doi.org/10.5194/gchron-6-325-2024, 2024
Short summary
Short summary
The “Likhall” bed helps to constrain the timing of increased meteorite bombardment of the Earth during the Ordovician period. It is important to understand the timing of this meteorite bombardment when attempting to correlate it with biodiversity changes during the Ordovician period. Calibrating a good age for the “Likhall” bed is, however, challenging and benefited in this study from advances in sample preparation.
Erin E. Donaghy, Michael P. Eddy, Federico Moreno, and Mauricio Ibañez-Mejia
Geochronology, 6, 89–106, https://doi.org/10.5194/gchron-6-89-2024, https://doi.org/10.5194/gchron-6-89-2024, 2024
Short summary
Short summary
Chemical abrasion (CA) is a technique that reduces or eliminates the effects of Pb loss in zircon U–Pb geochronology. However, CA has yet to be applied to large-n detrital zircon (DZ) analyses. We show that CA does not negatively impact or systematically bias U–Pb dates, improves the resolution of age populations defined by 206Pb/238U dates, and increases the percentage of concordant analyses in age populations defined by 207Pb/206Pb dates.
Robin B. Trayler, Stephen R. Meyers, Bradley B. Sageman, and Mark D. Schmitz
Geochronology, 6, 107–123, https://doi.org/10.5194/gchron-6-107-2024, https://doi.org/10.5194/gchron-6-107-2024, 2024
Short summary
Short summary
Developing models that relate stratigraphic position to time are important because they allow the rock record to be understood in terms of absolute time, allowing global comparisons. We developed a novel method for developing these models (called age–depth models) that uses two different types of chronologic information, dated rocks, and records of variations in the Earth's orbit (astrochronology). The resulting models are very precise, which can improve understanding of past climates.
Alyssa J. McKanna, Blair Schoene, and Dawid Szymanowski
Geochronology, 6, 1–20, https://doi.org/10.5194/gchron-6-1-2024, https://doi.org/10.5194/gchron-6-1-2024, 2024
Short summary
Short summary
Acid leaching is used to remove radiation-damaged portions of zircon crystals prior to U–Pb dating to improve the accuracy of datasets. We test how the temperature and duration of acid leaching affect geochronological and geochemical outcomes. We build a framework that relates radiation damage, zircon solubility, and Pb loss.
Alyssa J. McKanna, Isabel Koran, Blair Schoene, and Richard A. Ketcham
Geochronology, 5, 127–151, https://doi.org/10.5194/gchron-5-127-2023, https://doi.org/10.5194/gchron-5-127-2023, 2023
Short summary
Short summary
Acid leaching is commonly used to remove damaged portions of zircon crystals prior to U–Pb dating. However, a basic understanding of the microstructural processes that occur during leaching is lacking. We present the first 3D view of zircon dissolution based on X-ray computed tomography data acquired before and after acid leaching. These data are paired with images of etched grain surfaces and Raman spectral data. We also reveal exciting opportunities for imaging radiation damage zoning in 3D.
Charles W. Magee Jr., Simon Bodorkos, Christopher J. Lewis, James L. Crowley, Corey J. Wall, and Richard M. Friedman
Geochronology, 5, 1–19, https://doi.org/10.5194/gchron-5-1-2023, https://doi.org/10.5194/gchron-5-1-2023, 2023
Short summary
Short summary
SHRIMP (Sensitive High Resolution Ion MicroProbe) is an instrument that for decades has used the radioactive decay of uranium into lead to measure geologic time. The accuracy and precision of this instrument has not been seriously reviewed in almost 20 years. This paper compares several dozen SHRIMP ages in our database with more accurate and precise methods to assess SHRIMP accuracy and precision. Analytical and geological complications are addressed to try to improve the method.
Blair Schoene, Michael P. Eddy, C. Brenhin Keller, and Kyle M. Samperton
Geochronology, 3, 181–198, https://doi.org/10.5194/gchron-3-181-2021, https://doi.org/10.5194/gchron-3-181-2021, 2021
Short summary
Short summary
We compare two published U–Pb and 40Ar / 39Ar geochronologic datasets to produce eruption rate models for the Deccan Traps large igneous province. Applying the same approach to each dataset, the resulting models agree well, but the higher-precision U–Pb dataset results in a more detailed eruption model than the lower-precision 40Ar / 39Ar data. We explore sources of geologic uncertainty and reiterate the importance of systematic uncertainties in comparing U–Pb and 40Ar / 39Ar datasets.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
Short summary
Short summary
This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Simon Tapster and Joshua W. G. Bright
Geochronology, 2, 425–441, https://doi.org/10.5194/gchron-2-425-2020, https://doi.org/10.5194/gchron-2-425-2020, 2020
Short summary
Short summary
Cassiterite is the primary tin ore mineral and is associated with other elements needed for green technology. The mineral is deposited from hydrothermal fluids released from magmas. Because it is extremely acid resistant, there has been difficulty dissolving the mineral for isotopic analysis. To improve the understanding of the timing and models of formation processes, we use a novel method to dissolve and extract radiogenic isotopes of the uranium-to-lead decay scheme from cassiterite.
Jack Carter, Ryan B. Ickert, Darren F. Mark, Marissa M. Tremblay, Alan J. Cresswell, and David C. W. Sanderson
Geochronology, 2, 355–365, https://doi.org/10.5194/gchron-2-355-2020, https://doi.org/10.5194/gchron-2-355-2020, 2020
Short summary
Short summary
40K is an isotope of potassium that undergoes several different modes of radioactive decay. We use the decay of 40K to determine the ages of geologic materials that contain potassium but doing this requires us to know the rate at which 40K decays by its different decay modes. Here, we investigate one decay mode of 40K that has previously been overlooked. We demonstrate that this decay mode exists, estimate its rate, and evaluate its significance for geochronology.
Cited articles
Baresel, B., Bucher, H., Brosse, M., Cordey, F., Guodun, K., and Schaltegger, U.: Precise age for the Permian–Triassic boundary in South China from high-precision U-Pb geochronology and Bayesian age–depth modeling, Solid Earth, 8, 361–378, https://doi.org/10.5194/se-8-361-2017, 2017.
Bowring, J. F., McLean, N. M., and Bowring, S. A.: Engineering cyber infrastructure for U-Pb geochronology: Tripoli and U-Pb_Redux, Geochem. Geophy. Geosy., 12, Q0AA19, https://doi.org/10.1029/2010GC003479, 2011.
Bowring, S. A., Erwin, D., Parrish, R., and Renne, P.: EARTHTIME: A community-based effort towards high-precision calibration of Earth history, Geochim. Cosmochim. Ac., 69, A316, https://doi.org/10.1016/j.gca.2005.03.028, 2005.
Bruck, B. T., Singer, B. S., Schmitz, M. D., Carroll, A. R., Meyers, S., Walters, A. P., and Jicha, B. R.: Astronomical and tectonic influences on climate and deposition revealed through radioisotopic geochronology and Bayesian age-depth modeling of the early Eocene Green River Formation, Wyoming, USA, Geol. Soc. Am. Bull., 135, 3173–3182, https://doi.org/10.1130/B36584.1, 2023.
Condon, D., Schoene, B., Schmitz, M., Schaltegger, U., Ickert, R. B., Amelin, Y., Augland, L. E., Chamberlain, K. R., Coleman, D. S., Connelly, J. N., Corfu, F., Crowley, J. L., Davies, J. H. F. L., Denyszyn, S. W., Eddy, M. P., Gaynor, S. P., Heaman, L. M., Huyskens, M. H., Kamo, S., Kasbohm, J., Keller, C. B., MacLennan, S. A., McLean, N. M., Noble, S., Ovtcharova, M., Paul, A., Ramezani, J., Rioux, M., Sahy, D., Scoates, J. S., Szymanowski, D., Tapster, S., Tichomirowa, M., Wall, C. J., Wotzlaw, J.-F., Yang, C., and Yin, Q.-Z.: Recommendations for the reporting and interpretation of isotope dilution U-Pb geochronological information, Geol. Soc. Am. Bull., 136, 4233–4251, https://doi.org/10.1130/B37321.1, 2024.
Condon, D. J. and EARTHTIME U–Pb Working Group: Progress report on the U–Pb interlaboratory experiment, Geochim. Cosmochim. Ac., 69, A319, https://doi.org/10.1016/j.gca.2005.03.028, 2005.
Condon, D. J., McLean, N., Schoene, B., Bowring, S., Parrish, R., and Noble, S.: Synthetic U-Pb “standard” solutions for ID-TIMS geochronology, Geochim. Cosmochim. Ac., 72, A175, https://doi.org/10.1016/j.gca.2008.05.006, 2008.
Condon, D. J., Schoene, B., McLean, N. M., Bowring, S. A., and Parrish, R. R.: Metrology and traceability of U–Pb isotope dilution geochronology (EARTHTIME Tracer Calibration Part I), Geochim. Cosmochim. Ac., 164, 464–480, https://doi.org/10.1016/j.gca.2015.05.026, 2015.
Connelly, J. N. and Condon, D. J.: Interlaboratory calibration of mass spectrometric methods used for Pb–Pb dating of meteorites under the auspices of the EarlyTime initiative, Goldschmidt Abstracts, 448, 2014.
Davis, D. W.: A simple method for rapid calibration of faraday and ion-counting detectors on movable multicollector mass spectrometers, J. Mass Spectrom., 55, e4511, https://doi.org/10.1002/jms.4511, 2020.
Di, Y., Li, Z., and Amelin, Y.: Monitoring and quantitative evaluation of Faraday cup deterioration in a thermal ionization mass spectrometer using multidynamic analyses of laboratory standards, J. Anal. Atom. Spectrom., 36, 1489–1502, https://doi.org/10.1039/d1ja00028d, 2021.
Eddy, M. P., Ibañez-Mejia, M., Burgess, S. D., Coble, M. A., Cordani, U. G., DesOrmeau, J., Gehrels, G. E., Li, X., MacLennan, S., and Pecha, M.: GHR1 zircon – A new Eocene natural reference material for microbeam U-Pb geochronology and Hf isotopic analysis of zircon, Geostand. Geoanal. Res., 43, 113–132, https://doi.org/10.1111/ggr.12246, 2019.
Gerstenberger, H. and Haase, G.: A highly effective emitter substance for mass spectrometric Pb isotope ratio determinations, Chem. Geol., 136, 309–312, https://doi.org/10.1016/S0009-2541(96)00033-2, 1997.
Hiess, J., Condon, D. J., McLean, N., and Noble, S. R.: systematics in terrestrial uranium-bearing minerals, Science, 335, 1610–1614, https://doi.org/10.1126/science.1215507, 2012.
Huyskens, M. H., Iizuka, T., and Amelin, Y.: Evaluation of colloidal silicagels for lead isotopic measurements using thermal ionisation mass spectrometry, J. Anal. Atom. Spectrom., 27, 1439–1446, https://doi.org/10.1039/c2ja30083d, 2012.
Jaffey, A. H., Flynn, K. F., Glendenin, L. E., Bentley, W. C., and Essling, A. M.: Precision measurement of half-lives and specific activities of 235U and 238U, Phys. Rev. C, 4, 1889–1906, https://doi.org/10.1103/PhysRevC.4.1889, 1971.
Kennedy, A. K., Wotzlaw, J.-F., Schaltegger, U., Crowley, J. L., and Schmitz, M.: Eocene zircon reference material for microanalysis of U-Th-Pb isotopes and trace elements, Can. Mineral., 52, 409–421, https://doi.org/10.3749/canmin.52.3.409, 2014.
Krogh, T. E.: A low-contamination method for hydrothermal decomposition of zircon and extraction of U and Pb for isotopic age determinations, Geochim. Cosmochim. Ac., 37, 485–494, https://doi.org/10.1016/0016-7037(73)90213-5, 1973.
Ludwig, K.: Errors of isotope ratios acquired by double interpolation, Chem. Geol., 268, 24–26, https://doi.org/10.1016/j.chemgeo.2009.07.004, 2009.
Ludwig, K. R.: Calculation of uncertainties of U-Pb isotope data, Earth Planet. Sc. Lett., 46, 212–220, https://doi.org/10.1016/0012-821X(80)90007-2, 1980.
Ludwig, K. R.: PBDAT for MS-DOS; a computer program for IBM-PC compatibles for processing raw Pb-U-Th isotope data, version 1.00a, United States Geological Survey, Open-File Report 88-542, https://doi.org/10.3133/ofr88542, 1988.
Makishima, A. and Nakamura, E.: Calibration of Faraday cup efficiency in a multicollector mass spectrometer, Chem. Geol., 94, 105–110, https://doi.org/10.1016/0168-9622(91)90003-F, 1991.
Mattinson, J. M.: Zircon U–Pb chemical abrasion (“CA-TIMS”) method: Combined annealing and multi-step partial dissolution analysis for improved precision and accuracy of zircon ages, Chem. Geol., 220, 47–66, https://doi.org/10.1016/j.chemgeo.2005.03.011, 2005.
McLean, N. M., Bowring, J. F., and Bowring, S. A.: An algorithm for U-Pb isotope dilution data reduction and uncertainty propagation, Geochem. Geophy. Geosy., 12, Q0AA18, https://doi.org/10.1029/2010GC003478, 2011.
McLean, N. M., Condon, D. J., Schoene, B., and Bowring, S. A.: Evaluating uncertainties in the calibration of isotopic reference materials and multi-element isotopic tracers (EARTHTIME Tracer Calibration Part II), Geochim. Cosmochim. Ac., 164, 481–501, https://doi.org/10.1016/j.gca.2015.02.040, 2015.
Metcalfe, I., Crowley, J. L., Nicoll, R. S., and Schmitz, M.: High-precision U-Pb CA-TIMS calibration of Middle Permian to Lower Triassic sequences, mass extinction and extreme climate-change in eastern Australian Gondwana, Gondwana Res., 28, 61–81, https://doi.org/10.1016/j.gr.2014.09.002, 2015.
Miyazaki, T., Vaglarov, B. S., and Kimura, J.-I.: Determination of relative Faraday cup efficiency factor using exponential law mass fractionation model for multiple collector thermal ionization mass spectrometry, Geochem. J., 50, 445–447, https://doi.org/10.2343/geochemj.2.0439, 2016.
Nasdala, L., Hofmeister, W., Norberg, N., Martinson, J. M., Corfu, F., Dörr, W., Kamo, S. L., Kennedy, A. K., Kronz, A., and Reiners, P. W.: Zircon M257 – a homogeneous natural reference material for the ion microprobe U-Pb analysis of zircon, Geostand. Geoanal. Res., 32, 247–265, https://doi.org/10.1111/j.1751-908X.2008.00914.x, 2008.
Nasdala, L., Corfu, F., Schoene, B., Tapster, S. R., Wall, C. J., Schmitz, M. D., Ovtcharova, M., Schaltegger, U., Kennedy, A. K., Kronz, A., Reiners, P. W., Yang, Y.-H., Wu, F.-Y., Gain, S. E. M., Griffin, W. L., Szymanowski, D., Chanmuang N., C., Ende, M., Valley, J. W., Spicuzza, M. J., Wanthanachaisaeng, B., and Giester, G.: GZ7 and GZ8-Two Zircon Reference Materials for SIMS U-Pb Geochronology, Geostand. Geoanal. Res., 42, 431–457, https://doi.org/10.1111/ggr.12239, 2018.
Richter, S., Goldberg, S., Mason, P., Traina, A., and Schwieters, J.: Linearity tests for secondary electron multipliers used in isotope ratio mass spectrometry, Int. J. Mass Spectrom., 206, 105–127, https://doi.org/10.1016/S1387-3806(00)00395-X, 2001.
Sahy, D., Condon, D. J., Terry, D. O., Fischer, A. U., and Kuiper, K. F.: Synchronizing terrestrial and marine records of environmental change across the Eocene–Oligocene transition, Earth Planet. Sc. Lett., 427, 171–182, https://doi.org/10.1016/j.epsl.2015.06.057, 2015.
Schaltegger, U., Ovtcharova, M., Gaynor, S. P., Schoene, B., Wotzlaw, J.-F., Davies, J. F. H. L., Farina, F., Greber, N. D., Szymanowski, D., and Chelle-Michou, C.: Long-term repeatability and interlaboratory reproducibility of high-precision ID-TIMS U–Pb geochronology, J. Anal. Atom. Spectrom., 36, 1466–1477, https://doi.org/10.1039/d1ja00116g, 2021.
Schaltegger, U., Ovtcharova, M., and Schoene, B.: Chapter 2 – High-precision CA-ID-TIMS U-Pb geochronology of zircon: Materials, methods, and interpretations, in: Methods and Applications of Geochronology, edited by: Shellnutt, J. G., Denyszyn, S. W., and Suga, K., Elsevier, 19–52, https://doi.org/10.1016/B978-0-443-18803-9.00012-2, 2024.
Schmitz, M. D. and Schoene, B.: Derivation of isotope ratios, errors, and error correlations for U-Pb geochronology using 205Pb-235U-(233U)-spiked isotope dilution thermal ionization mass spectrometric data, Geochem. Geophy., Geosy., 8, Q08006, https://doi.org/10.1029/2006gc001492, 2007.
Schoene, B.: U–Th–Pb Geochronology, in: Treatise on Geochemistry, edited by: Holland, H. D., and Turekian, K. K., 2nd Edn., Elsevier, Oxford, 341–378, https://doi.org/10.1016/B978-0-08-095975-7.00310-7, 2014.
Sláma, J., Košler, J., Condon, D. J., Crowley, J. L., Gerdes, A., Hanchar, J. M., Horstwood, M. S. A., Morris, G. A., Nasdala, L., Norberg, N., Schaltegger, U., Schoene, B., Tubrett, M. N., and Whitehouse, M. J.: Plešovice zircon – A new natural reference material for U-Pb and Hf isotopic microanalysis, Chem. Geol., 249, 1–35, https://doi.org/10.1016/j.chemgeo.2007.11.005, 2008.
Szymanowski, D. and Schoene, B.: U-Pb ID-TIMS geochronology using ATONA amplifiers, J. Anal. Atom. Spectrom., 35, 1207–1216, https://doi.org/10.1039/d0ja00135j, 2020.
Taylor, R. N., Ishizuka, O., Michalik, A., Milton, J. A., and Croudace, I. W.: Evaluating the precision of Pb isotope measurement by mass spectrometry, J. Anal. Atom. Spectrom., 30, 198–213, https://doi.org/10.1039/c4ja00279b, 2015.
Vermeesch, P.: IsoplotR: A free and open toolbox for geochronology, Geosci. Front., 9, 1479–1493, https://doi.org/10.1016/j.gsf.2018.04.001, 2018.
von Quadt, A., Wotzlaw, J. F., Buret, Y., Large, S. J. E., Peytcheva, I., and Trinquier, A.: High-precision zircon U/Pb geochronology by ID-TIMS using new 1013 ohm resistors, J. Anal. Atom. Spectrom., 31, 658–665, https://doi.org/10.1039/c5ja00457h, 2016.
Widmann, P., Davies, J. H. F. L., and Schaltegger, U.: Calibrating chemical abrasion: Its effects on zircon crystal structure, chemical composition and U–Pb age, Chem. Geol., 511, 1–10, https://doi.org/10.1016/j.chemgeo.2019.02.026, 2019.
Wiedenbeck, M., Allé, P., Corfu, F., Griffin, W., Meier, M., Oberli, F., von Quadt, A., Roddick, J., and Spiegel, W.: Three natural zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analyses, Geostandards Newsl., 19, 1–23, https://doi.org/10.1111/j.1751-908X.1995.tb00147.x, 1995.
Wotzlaw, J. F., Buret, Y., Large, S. J. E., Szymanowski, D., and von Quadt, A.: ID-TIMS U-Pb geochronology at the 0.1 ‰ level using 1013 Ω resistors and simultaneous U and 18O/16O isotope ratio determination for accurate UO2 interference correction, J. Anal. Atom. Spectrom., 32, 579–586, https://doi.org/10.1039/c6ja00278a, 2017.
Short summary
We present the first community-wide evaluation of the reproducibility of U–Pb zircon geochronology by isotope dilution thermal ionisation mass spectrometry (ID-TIMS). Eleven labs analysed aliquots of the same, homogenised, pre-spiked solution of natural zircon, which removed geological bias inherent to using heterogeneous natural zircon grain populations. We discuss remaining sources of inter-lab bias and propose areas of improvement to analytical procedures.
We present the first community-wide evaluation of the reproducibility of U–Pb zircon...