Articles | Volume 5, issue 1
https://doi.org/10.5194/gchron-5-181-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-5-181-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Apr 2023
Research article |
| 20 Apr 2023
| 20 Apr 2023
DQPB: software for calculating disequilibrium U–Pb ages
Timothy Pollard
CORRESPONDING AUTHOR
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
EDYTEM UMR CNRS 5204, Université Savoie Mont Blanc, Le Bourget du Lac, CEDEX 73376, France
Jon Woodhead
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
John Hellstrom
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
John Engel
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
Roger Powell
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
Russell Drysdale
School of Geography, Earth and Atmospheric Sciences, University of Melbourne, Melbourne, Victoria 3010, Australia
EDYTEM UMR CNRS 5204, Université Savoie Mont Blanc, Le Bourget du Lac, CEDEX 73376, France
Related authors
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Timothy J. Pollard, Jon D. Woodhead, Russell N. Drysdale, R. Lawrence Edwards, Xianglei Li, Ashlea N. Wainwright, Mathieu Pythoud, Hai Cheng, John C. Hellstrom, Ilaria Isola, Eleonora Regattieri, Giovanni Zanchetta, and Dylan S. Parmenter
EGUsphere, https://doi.org/10.5194/egusphere-2024-3594, https://doi.org/10.5194/egusphere-2024-3594, 2024
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The uranium-thorium and uranium-lead radiometric dating methods are both capable of dating carbonate samples ranging in age from about 400,000 to 650,000 years. Here we test agreement between the two methods by 'double dating' speleothems (i.e. secondary cave mineral deposits) that grew within this age range. We demonstrate excellent agreement between the two dating methods and discuss their relative strengths and weaknesses.
Calla N. Gould-Whaley, Russell N. Drysdale, Pauline C. Treble, Jan-Hendrik May, Stacey C. Priestley, John C. Hellstrom, and Clare Buswell
EGUsphere, https://doi.org/10.5194/egusphere-2024-1959, https://doi.org/10.5194/egusphere-2024-1959, 2024
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Climate change is causing enhanced aridity across many regions of the globe, leading to increased reliance on groundwater resources. We need to understand how groundwater recharge behaves in arid regions over long timescales, unfortunately, arid landscapes tend to preserve very little evidence of their climatic past. We present evidence to suggest that carbonate formations that grow in groundwater can be used as archives of past groundwater recharge in Australia's arid zone.
Hubert Vonhof, Sophie Verheyden, Dominique Bonjean, Stéphane Pirson, Michael Weber, Denis Scholz, John Hellstrom, Hai Cheng, Xue Jia, Kevin Di Modica, Gregory Abrams, Marjan van Nunen, Joost Ruiter, Michèlle van der Does, Daniel Böhl, and Jeroen van der Lubbe
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-27, https://doi.org/10.5194/cp-2024-27, 2024
Revised manuscript accepted for CP
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The sedimentary sequence in Scladina Cave (Belgium) is well-known for its rich archeological assemblages and its numerous faunal remains. Of particular interest is the presence of a nearly complete jaw bone of a Neandertal child. In this study, we present new Uranium-series ages of stalagmites from the archeological sequence which allow more precise dating of the archeological finds. One key result is that the Neandertal child may be slightly older than previously thought.
Candan U. Desem, Patrice de Caritat, Jon Woodhead, Roland Maas, and Graham Carr
Earth Syst. Sci. Data, 16, 1383–1393, https://doi.org/10.5194/essd-16-1383-2024, https://doi.org/10.5194/essd-16-1383-2024, 2024
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Lead (Pb) isotopes form a potent tracer in studies of provenance, mineral exploration and environmental remediation. Previously, however, Pb isotope analysis has rarely been deployed at a continental scale. Here we present a new regolith Pb isotope dataset for Australia, which includes 1119 large catchments encompassing 5.6 × 106 km2 or close to ~75 % of the continent. Isoscape maps have been produced for use in diverse fields of study.
Miguel Bartolomé, Ana Moreno, Carlos Sancho, Isabel Cacho, Heather Stoll, Negar Haghipour, Ánchel Belmonte, Christoph Spötl, John Hellstrom, R. Lawrence Edwards, and Hai Cheng
Clim. Past, 20, 467–494, https://doi.org/10.5194/cp-20-467-2024, https://doi.org/10.5194/cp-20-467-2024, 2024
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Reconstructing past temperatures at regional scales during the Common Era is necessary to place the current warming in the context of natural climate variability. We present a climate reconstruction based on eight stalagmites from four caves in the Pyrenees, NE Spain. These stalagmites were dated precisely and analysed for their oxygen isotopes, which appear dominated by temperature changes. Solar variability and major volcanic eruptions are the two main drivers of observed climate variability.
Frédéric Parrenin, Marie Bouchet, Christo Buizert, Emilie Capron, Ellen Corrick, Russell Drysdale, Kenji Kawamura, Amaëlle Landais, Robert Mulvaney, Ikumi Oyabu, and Sune Rasmussen
EGUsphere, https://doi.org/10.5194/egusphere-2023-2911, https://doi.org/10.5194/egusphere-2023-2911, 2024
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The Paleochrono1 probablistic dating model allows to derive a common and optimized chronology for several paleoclimatic sites from various archives (ice cores, speleothems, marine cores, lake cores, etc.). It combines prior sedimentation scenarios with chronological information such as dated horizons, dated intervals, stratigraphic links and (for ice cores) Delta-depth observations. Paleochrono1 is available under the MIT open-source license.
Hege Kilhavn, Isabelle Couchoud, Russell N. Drysdale, Carlos Rossi, John Hellstrom, Fabien Arnaud, and Henri Wong
Clim. Past, 18, 2321–2344, https://doi.org/10.5194/cp-18-2321-2022, https://doi.org/10.5194/cp-18-2321-2022, 2022
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The analysis of stable carbon and oxygen isotopic ratios, trace element ratios, and growth rate from a Spanish speleothem provides quantitative information on past hydrological conditions during the early Holocene in south-western Europe. Our data show that the cave site experienced increased effective recharge during the 8.2 ka event. Additionally, the oxygen isotopes indicate a change in the isotopic composition of the moisture source, associated with the meltwater flux to the North Atlantic.
Zuorui Liu, Amy Prendergast, Russell Drysdale, and Jan-Hendrik May
E&G Quaternary Sci. J., 71, 227–241, https://doi.org/10.5194/egqsj-71-227-2022, https://doi.org/10.5194/egqsj-71-227-2022, 2022
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Past studies used two sampling strategies, the "bulk" and "sequential" drilling methods, for stable isotopic analysis of mammoth tooth enamel and paleoenvironmental reconstruction. This study applied both methods to the same enamel ridges of multiple mammoth teeth and compared their respective δ18O values. Offsets were detected between the bulk and average sequential δ18O values. The potential reasons for the offsets and their impacts on cross-method data comparison were discussed.
Cinthya Esther Nava Fernandez, Tobias Braun, Bethany Fox, Adam Hartland, Ola Kwiecien, Chelsea Pederson, Sebastian Hoepker, Stefano Bernasconi, Madalina Jaggi, John Hellstrom, Fernando Gázquez, Amanda French, Norbert Marwan, Adrian Immenhauser, and Sebastian Franz Martin Breitenbach
Clim. Past Discuss., https://doi.org/10.5194/cp-2021-172, https://doi.org/10.5194/cp-2021-172, 2022
Manuscript not accepted for further review
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We provide a ca. 1000 year long (6.4–5.4 ka BP) stalagmite-based reconstruction of mid-Holocene rainfall variability in the tropical western Pacific. The annually laminated multi-proxy (δ13C, δ18O, X/Ca, gray values) record comes from Niue island and informs on El Nino-Southern Oscillation and South Pacific Convergence Zone dynamics. Our data suggest that ENSO was active and influenced rainfall seasonality over the covered time interval. Rainfall seasonality was subdued during active ENSO phases
Inken Heidke, Adam Hartland, Denis Scholz, Andrew Pearson, John Hellstrom, Sebastian F. M. Breitenbach, and Thorsten Hoffmann
Biogeosciences, 18, 2289–2300, https://doi.org/10.5194/bg-18-2289-2021, https://doi.org/10.5194/bg-18-2289-2021, 2021
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We analyzed lignin oxidation products (LOPs) in leaf litter and different soil horizons as well as dripwater and flowstone samples from four different cave sites from different vegetation zones in New Zealand using liquid chromatography coupled to mass spectrometry. We test whether the original source-dependent LOP signal of the overlying vegetation is preserved and can be recovered from flowstone samples and investigate how the signal is altered by the transport from the soil to the cave.
Matej Lipar, Andrea Martín-Pérez, Jure Tičar, Miha Pavšek, Matej Gabrovec, Mauro Hrvatin, Blaž Komac, Matija Zorn, Nadja Zupan Hajna, Jian-Xin Zhao, Russell N. Drysdale, and Mateja Ferk
The Cryosphere, 15, 17–30, https://doi.org/10.5194/tc-15-17-2021, https://doi.org/10.5194/tc-15-17-2021, 2021
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The U–Th ages of subglacial carbonate deposits from a recently exposed surface previously occupied by the disappearing glacier in the SE European Alps suggest the glacier’s presence throughout the entire Holocene. These thin deposits, formed by regelation, would have been easily eroded if exposed during previous Holocene climatic optima. The age data indicate the glacier’s present unprecedented level of retreat and the potential of subglacial carbonates to act as palaeoclimate proxies.
Roger Powell, Eleanor C. R. Green, Estephany Marillo Sialer, and Jon Woodhead
Geochronology, 2, 325–342, https://doi.org/10.5194/gchron-2-325-2020, https://doi.org/10.5194/gchron-2-325-2020, 2020
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The standard approach to isochron calculation assumes that the distribution of uncertainties on the data arising from isotopic analysis is strictly Gaussian. This excludes datasets that have more scatter, even though many appear to have age significance. Our new approach requires only that the central part of the uncertainty distribution of the data defines a "spine" in the trend of the data. A robust statistics approach is used to locate the spine, and an implementation in Python is given.
Cinthya Nava-Fernandez, Adam Hartland, Fernando Gázquez, Ola Kwiecien, Norbert Marwan, Bethany Fox, John Hellstrom, Andrew Pearson, Brittany Ward, Amanda French, David A. Hodell, Adrian Immenhauser, and Sebastian F. M. Breitenbach
Hydrol. Earth Syst. Sci., 24, 3361–3380, https://doi.org/10.5194/hess-24-3361-2020, https://doi.org/10.5194/hess-24-3361-2020, 2020
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Speleothems are powerful archives of past climate for understanding modern local hydrology and its relation to regional circulation patterns. We use a 3-year monitoring dataset to test the sensitivity of Waipuna Cave to seasonal changes and El Niño–Southern Oscillation (ENSO) dynamics. Drip water data suggest a fast response to rainfall events; its elemental composition reflects a seasonal cycle and ENSO variability. Waipuna Cave speleothems have a high potential for past ENSO reconstructions.
Jon Woodhead and Joseph Petrus
Geochronology, 1, 69–84, https://doi.org/10.5194/gchron-1-69-2019, https://doi.org/10.5194/gchron-1-69-2019, 2019
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Recently developed methods for in situ U–Pb age determination in carbonates have found widespread application, but the benefits and limitations of the method over bulk analysis approaches have yet to be fully explored. Here we use speleothems – cave carbonates such as stalagmites and flowstones – to investigate the utility of these in situ dating methodologies for challenging matrices with low U and Pb contents and predominantly late Cenozoic ages.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell N. Drysdale, Philip L. Gibbard, Lauren Gregoire, Feng He, Ruza F. Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis C. Tzedakis, Eric Wolff, and Xu Zhang
Geosci. Model Dev., 12, 3649–3685, https://doi.org/10.5194/gmd-12-3649-2019, https://doi.org/10.5194/gmd-12-3649-2019, 2019
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As part of the Past Global Changes (PAGES) working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation for the Paleoclimate Modelling Intercomparison Project (PMIP4). This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. Key paleo-records for model-data comparison are also included.
Monica Bini, Giovanni Zanchetta, Aurel Perşoiu, Rosine Cartier, Albert Català, Isabel Cacho, Jonathan R. Dean, Federico Di Rita, Russell N. Drysdale, Martin Finnè, Ilaria Isola, Bassem Jalali, Fabrizio Lirer, Donatella Magri, Alessia Masi, Leszek Marks, Anna Maria Mercuri, Odile Peyron, Laura Sadori, Marie-Alexandrine Sicre, Fabian Welc, Christoph Zielhofer, and Elodie Brisset
Clim. Past, 15, 555–577, https://doi.org/10.5194/cp-15-555-2019, https://doi.org/10.5194/cp-15-555-2019, 2019
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The Mediterranean region has returned some of the clearest evidence of a climatically dry period occurring approximately 4200 years ago. We reviewed selected proxies to infer regional climate patterns between 4.3 and 3.8 ka. Temperature data suggest a cooling anomaly, even if this is not uniform, whereas winter was drier, along with dry summers. However, some exceptions to this prevail, where wetter condition seems to have persisted, suggesting regional heterogeneity.
Ilaria Isola, Giovanni Zanchetta, Russell N. Drysdale, Eleonora Regattieri, Monica Bini, Petra Bajo, John C. Hellstrom, Ilaria Baneschi, Piero Lionello, Jon Woodhead, and Alan Greig
Clim. Past, 15, 135–151, https://doi.org/10.5194/cp-15-135-2019, https://doi.org/10.5194/cp-15-135-2019, 2019
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To understand the natural variability in the climate system, the hydrological aspect (dry and wet conditions) is particularly important for its impact on our societies. The reconstruction of past precipitation regimes can provide a useful tool for forecasting future climate changes. We use multi-proxy time series (oxygen and carbon isotopes, trace elements) from a speleothem to investigate circulation pattern variations and seasonality effects during the dry 4.2 ka event in central Italy.
Laurie Menviel, Emilie Capron, Aline Govin, Andrea Dutton, Lev Tarasov, Ayako Abe-Ouchi, Russell Drysdale, Philip Gibbard, Lauren Gregoire, Feng He, Ruza Ivanovic, Masa Kageyama, Kenji Kawamura, Amaelle Landais, Bette L. Otto-Bliesner, Ikumi Oyabu, Polychronis Tzedakis, Eric Wolff, and Xu Zhang
Clim. Past Discuss., https://doi.org/10.5194/cp-2018-106, https://doi.org/10.5194/cp-2018-106, 2018
Preprint withdrawn
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The penultimate deglaciation (~ 138–128 ka), which represents the transition into the Last Interglacial period, provides a framework to investigate the climate and environmental response to large changes in boundary conditions. Here, as part of the PAGES-PMIP working group on Quaternary Interglacials, we propose a protocol to perform transient simulations of the penultimate deglaciation as well as a selection of paleo records for upcoming model-data comparisons.
Bronwyn C. Dixon, Jonathan J. Tyler, Andrew M. Lorrey, Ian D. Goodwin, Joëlle Gergis, and Russell N. Drysdale
Clim. Past, 13, 1403–1433, https://doi.org/10.5194/cp-13-1403-2017, https://doi.org/10.5194/cp-13-1403-2017, 2017
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Existing sedimentary palaeoclimate records in Australasia were assessed for suitability for examining the last 2 millennia. A small number of high-quality records were identified, and new Bayesian age models were constructed for each record. Findings suggest that Australasian record chronologies and confidence in proxy–climate relationships are the main factors limiting appropriate data for examining Common Era climate variability. Recommendations for improving data accessibility are provided.
Pauline C. Treble, Andy Baker, Linda K. Ayliffe, Timothy J. Cohen, John C. Hellstrom, Michael K. Gagan, Silvia Frisia, Russell N. Drysdale, Alan D. Griffiths, and Andrea Borsato
Clim. Past, 13, 667–687, https://doi.org/10.5194/cp-13-667-2017, https://doi.org/10.5194/cp-13-667-2017, 2017
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Little is known about the climate of southern Australia during the Last Glacial Maximum and deglaciation owing to sparse records for this region. We present the first high-resolution data, derived from speleothems that grew 23–5 ka. It appears that recharge to the Flinders Ranges was higher than today, particularly during 18.9–15.8 ka, argued to be due to the enhanced availability of tropical moisture. An abrupt shift to aridity is recorded at 15.8 ka, associated with restored westerly airflow.
S. Frisia, A. Borsato, R. N. Drysdale, B. Paul, A. Greig, and M. Cotte
Clim. Past, 8, 2039–2051, https://doi.org/10.5194/cp-8-2039-2012, https://doi.org/10.5194/cp-8-2039-2012, 2012
Related subject area
U-series
Technical note: „U-Th Analysis” – an open-source software dedicated to MCICPMS U-series-data treatment and evaluation
A new multimethod approach for dating cave calcite: application to the cave of Trou du Renard (Soyons, France)
230Th ∕ U isochron dating of cryogenic cave carbonates
A simplified isotope dilution approach for the U–Pb dating of speleogenic and other low-232Th carbonates by multi-collector ICP-MS
Novel method for determining 234U–238U ages of Devils Hole 2 cave calcite (Nevada)
Inga Kristina Kerber, Fabian Kontor, Sophie Warken, and Norbert Frank
EGUsphere, https://doi.org/10.5194/egusphere-2024-1788, https://doi.org/10.5194/egusphere-2024-1788, 2024
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A standalone data analysis application for Th/U dating on multi-collector inductively coupled plasma mass spectrometers features a Python-based algorithm with a graphical user interface. It handles data treatment, corrections, age calculus, and error estimation and supports various detector layouts including Faraday and electron multiplier detectors. Key features include reproducibility, user-friendly reanalysis, and automated data storage. A case study demonstrated the software’s performance.
Loïc Martin, Julius Nouet, Arnaud Dapoigny, Gaëlle Barbotin, Fanny Claverie, Edwige Pons-Branchu, Jocelyn Barbarand, Christophe Pécheyran, Norbert Mercier, Fanny Derym, Bernard Gély, and Hélène Valladas
Geochronology, 6, 247–263, https://doi.org/10.5194/gchron-6-247-2024, https://doi.org/10.5194/gchron-6-247-2024, 2024
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Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach: U–Th dating by bulk dissolution of samples and inductively coupled plasma mass spectrometry (ICP-MS), U–Th dating by laser ablation ICP-MS imaging, and radiocarbon dating. The samples were studied to ensure that they give reliable ages. Ages ranging from 187.9 ± 5.3 ka and 1.4 ± 0.1 ka were found. This approach should make it possible to establish more robust chronologies of archaeological caves.
Paul Töchterle, Simon D. Steidle, R. Lawrence Edwards, Yuri Dublyansky, Christoph Spötl, Xianglei Li, John Gunn, and Gina E. Moseley
Geochronology, 4, 617–627, https://doi.org/10.5194/gchron-4-617-2022, https://doi.org/10.5194/gchron-4-617-2022, 2022
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Cryogenic cave carbonates (CCCs) provide a marker for past permafrost conditions. Their formation age is determined by Th / U dating. However, samples can be contaminated with small amounts of Th at formation, which can cause inaccurate ages and require correction. We analysed multiple CCCs and found that varying degrees of contamination can cause an apparent spread of ages, when samples actually formed within distinguishable freezing events. A correction method using isochrons is presented.
Andrew J. Mason, Anton Vaks, Sebastian F. M. Breitenbach, John N. Hooker, and Gideon M. Henderson
Geochronology, 4, 33–54, https://doi.org/10.5194/gchron-4-33-2022, https://doi.org/10.5194/gchron-4-33-2022, 2022
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A novel technique for the uranium–lead dating of geologically young carbonates is described and tested. The technique expands our ability to date geological events such as fault movements and past climate records.
Xianglei Li, Kathleen A. Wendt, Yuri Dublyansky, Gina E. Moseley, Christoph Spötl, and R. Lawrence Edwards
Geochronology, 3, 49–58, https://doi.org/10.5194/gchron-3-49-2021, https://doi.org/10.5194/gchron-3-49-2021, 2021
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In this study, we built a statistical model to determine the initial δ234U in submerged calcite crusts that coat the walls of Devils Hole 2 (DH2) cave (Nevada, USA) and, using a 234U–238U dating method, extended the chronology of the calcite deposition beyond previous well-established 230Th ages and determined the oldest calcite deposited in this cave, a time marker for cave genesis. The novel method presented here may be used in future speleothem studies in similar hydrogeological settings.
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Short summary
When using the uranium–lead (U–Pb) radiometric dating method on very young materials (e.g. Quaternary age zircon and carbonate minerals), it is important to accurately account for the production and decay of intermediate
daughterisotopes in the uranium-series decay chain. DQPB is open-source software that allows users to easily perform such calculations for a variety of sample types and produce publication-ready graphical outputs of the resulting age information.
When using the uranium–lead (U–Pb) radiometric dating method on very young materials (e.g....
