Articles | Volume 7, issue 4
https://doi.org/10.5194/gchron-7-513-2025
© Author(s) 2025. This work is distributed under the Creative Commons Attribution 4.0 License.
Accuracy and validity of maximum depositional ages in light of tandem (laser ablation and isotope dilution) U–Pb detrital zircon geochronology, including results from northern Alaska
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- Final revised paper (published on 24 Oct 2025)
- Preprint (discussion started on 27 Feb 2025)
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
| : Report abuse
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RC1: 'Comment on egusphere-2025-727', B. Schoene, 17 Apr 2025
- AC1: 'Reply on RC1', Trystan Herriott, 10 May 2025
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CC1: 'Comment on egusphere-2025-727', Mike Eddy, 29 Apr 2025
- AC2: 'Reply on CC1', Trystan Herriott, 10 May 2025
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RC2: 'Comment on egusphere-2025-727', Anonymous Referee #2, 30 Apr 2025
- AC3: 'Reply on RC2', Trystan Herriott, 10 May 2025
Peer review completion
AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
ED: Publish subject to revisions (further review by editor and referees) (21 May 2025) by Brenhin Keller
AR by Trystan Herriott on behalf of the Authors (06 Aug 2025)
Author's response
Author's tracked changes
Manuscript
ED: Publish subject to technical corrections (14 Aug 2025) by Brenhin Keller
ED: Publish subject to technical corrections (15 Aug 2025) by Klaus Mezger (Editor)
AR by Trystan Herriott on behalf of the Authors (16 Aug 2025)
Author's response
Manuscript
Herriott et al. presents an analysis of detrital zircon (DZ) U-Pb geochronologic data as a means of determining maximum depositional ages (MDAs) for strata by comparing the youngest zircons measured from a bed by LA-ICPMS with the same grains measured by ID-TIMS. It is a thorough analysis that focuses on one dataset, and it also compiles data from a few other recent studies that have both ICPMS and TIMS paired analyses. They show there is a semi-systematic offset between the ICPMS and TIMS data where the ICPMS data is younger – often beyond analytical uncertainty – than the TIMS date from the same zircon. They discuss the possible causes and implications of this in detail.
I was a bit surprised to find out that all the data in this paper are already published in an Alaskan Survey publication that is easily obtainable and contains some of the same figures and tables (in addition to all the raw data tables). I speculate that perhaps the great state of Alaska requires this form of publication first, as that first publication reads like more of a data dump. The current manuscript is perhaps seen as an opportunity to analyze the data in more detail and in a way that would appeal to a broader readership, but I can't help wonder if they both need to exist.
I must admit that I’m not entrenched in the DZ literature and therefore am somewhat ignorant to published discussions of the precision and accuracy of DZ MDAs. To be honest, I have just always assumed MDAs in general should be taken with a grain of salt, and those determined by ICPMS are likely inaccurate by some unknown amount, and that playing statistical games doesn’t get you much closer to assessing their accuracy. I have also noticed numerous examples in my own lab where ID-TIMS dates on the same zircons dated by LA-ICPMS are older, sometimes by tens of Myr or more in the Paleozoic or Ediacaran, so I bring this observation to every MDA DZ dataset I see (i.e., big grain of salt). Given that predisposition, I find the results and conclusions of Herriott et al. not too surprising and found parts of the paper to be overly verbose in coming to their conclusions. So, I guess assessing the value of this contribution would be best done within the context of someone who uses DZ MDAs, or wants to, but is less aware of the challenges of doing so. Herriott et al. cites numerous papers that appear to provide reviews of or new approaches to analyzing MDAs, so I would hope one of those folks could also chime in on this paper to assess its novelty. Regardless, I see an obvious contribution from this paper is the reiteration that without paired LA-ICPMS and CA-ID-TIMS dates, you can’t have much confidence that n=1 zircon MDAs determined without chemical abrasion to remove Pb-loss are likely accurate. Whether or not that matters of course depends on the question being asked in a given study.
For revisions, perhaps the authors could add some statements in the abstract and intro that delineate the novelty of this analysis. I also suggest shortening parts of the manuscript. For example, I bet sections 2.4.3., 3.1.1., 3.1.2. could be considerably condensed (by 50%?). I would also include some text near the beginning that clearly states what data from this paper are already published and why those data need to be revisited here, in order to alleviate potential concerns about, or impressions that you are, double-dipping.
Here's some line-by-line comments:
27: I find the sentence beginning on this line fairly confusing. Try rewriting or breaking into two sentences.
34: I’ve never heard the word “stratal” used in this way before. But I guess you mean “same age as the bed the zircons are found in”?
54: the previous two paragraphs assume people already know this, so move it up or perhaps it’s ok to delete.
176: “…to the work by LePain…” could be interpreted to mean that LePain did the correlation, though I think you mean you did the correlation between your samples and those in LePain.
199: I’m not sure what you mean by “in quadrature” here. Maybe just cite the papers with the algorithms used.
212: If your intended audience includes geochronologists, you might report the MSWD statistic when discussing equivalence of MSWDs.
229-232: I have personally used the term accuracy to also include data interpretation, i.e., how well does a date measure the process you’re interested in. But I like the suggestion here to use validity in that it separates the two, perhaps in useful ways.
240: out of curiosity, why did the ID-TIMS dates fail for these?
260: could you actually state what the kernel bandwidth is?
Fig 4: I’d put the dates for individual zircons on the figure beneath the sample name, and include you’re preferred depositional interpretation of the tephra samples as well.
Fig. 5 and associated: I must say that after reading the abstract I was expecting the LA data to be resolvably and consistently younger than the TIMS data. However, when I look at Fig. 5 it seems 6/10 single analysis pairs agree within 2sigma. Some LA people may call that a win, whereas it’s being pitched here (at least how I read it) as a loss. I’d recommend revising some of the language with a focus on accurately describing the data comparison given analytical uncertainties. One could raise a similar question for Fig. 9, which may or may or may not look so bleak if analytical uncertainties were included. But don’t get me wrong, I agree the dates are shifted young and I appreciate the cause is likely to be Pb-loss but for most readers, esp. of DZ data, they want to know if the mean overlaps with the true or not, not if the mean is shifted slightly younger but overlapping with the true given the uncertainty.
Fig. 6: these aerial photos are amazing.
Fig. 7: I don’t think you should be plotting a KDE with the intent of comparing precision and accuracy of two datasets that measure the same thing with different instruments. The KDE ignores actual measured uncertainties and therefore is not going to serve your purpose. I’d plot a PDF in (b) instead.
337: I’d delete “suggest and” and replace with “and are”
374: “very good goodness” sounds funny
514-529: I don’t feel like I have enough information about what Copeland 2020 is proposing for me to get much out of this paragraph.
593-595: I think this sentence is important, and what I was thinking while reading the previous few pages…
670: it would be useful to describe what the MLA algorithm does. For me, I’ve never used it, so the following discussion about it is rather black box.
720, Fig. 9: I could have used a better description of what the nth Youngest Tandem LA-ICPMS date means. I got lost here.
724: typo