Articles | Volume 4, issue 2
https://doi.org/10.5194/gchron-4-617-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-4-617-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Sep 2022
Research article |
| 15 Sep 2022
| 15 Sep 2022
230Th ∕ U isochron dating of cryogenic cave carbonates
Paul Töchterle
CORRESPONDING AUTHOR
Institute of Geology, University of Innsbruck, Innsbruck, 6020,
Austria
Simon D. Steidle
Institute of Geology, University of Innsbruck, Innsbruck, 6020,
Austria
R. Lawrence Edwards
Department of Earth and Environmental Sciences, University of
Minnesota, Minneapolis, 55455, MN, USA
Yuri Dublyansky
Institute of Geology, University of Innsbruck, Innsbruck, 6020,
Austria
Christoph Spötl
Institute of Geology, University of Innsbruck, Innsbruck, 6020,
Austria
Xianglei Li
Department of Earth and Environmental Sciences, University of
Minnesota, Minneapolis, 55455, MN, USA
John Gunn
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Gina E. Moseley
Institute of Geology, University of Innsbruck, Innsbruck, 6020,
Austria
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Stalagmites are valuable climate archives, but unlike other proxies the use of stable carbon isotopes (δ13C) is still difficult. A stalagmite from the Austrian Alps was analyzed using a new laser ablation method for fast radiocarbon (14C) analysis. This allowed 14C and δ13C to be combined, showing that besides soil and bedrock a third source is contributing during periods of warm, wet climate: old organic matter.
Kathleen A. Wendt, Xianglei Li, R. Lawrence Edwards, Hai Cheng, and Christoph Spötl
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In this study, we tested the upper limits of U–Th dating precision by analyzing three stalagmites from the Austrian Alps that have high U concentrations. The composite record spans the penultimate interglacial (MIS 7) with an average 2σ age uncertainty of 400 years. This unprecedented age control allows us to constrain the timing of temperature shifts in the Alps during MIS 7 while offering new insight into millennial-scale changes in the North Atlantic leading up to Terminations III and IIIa.
Gabriella Koltai, Christoph Spötl, Alexander H. Jarosch, and Hai Cheng
Clim. Past, 17, 775–789, https://doi.org/10.5194/cp-17-775-2021, https://doi.org/10.5194/cp-17-775-2021, 2021
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Chao-Jun Chen, Dao-Xian Yuan, Jun-Yun Li, Xian-Feng Wang, Hai Cheng, You-Feng Ning, R. Lawrence Edwards, Yao Wu, Si-Ya Xiao, Yu-Zhen Xu, Yang-Yang Huang, Hai-Ying Qiu, Jian Zhang, Ming-Qiang Liang, and Ting-Yong Li
Clim. Past Discuss., https://doi.org/10.5194/cp-2021-20, https://doi.org/10.5194/cp-2021-20, 2021
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Xianglei Li, Kathleen A. Wendt, Yuri Dublyansky, Gina E. Moseley, Christoph Spötl, and R. Lawrence Edwards
Geochronology, 3, 49–58, https://doi.org/10.5194/gchron-3-49-2021, https://doi.org/10.5194/gchron-3-49-2021, 2021
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Lilian Schuster, Fabien Maussion, Lukas Langhamer, and Gina E. Moseley
Weather Clim. Dynam., 2, 1–17, https://doi.org/10.5194/wcd-2-1-2021, https://doi.org/10.5194/wcd-2-1-2021, 2021
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Precipitation and moisture sources over an arid region in northeast Greenland are investigated from 1979 to 2017 by a Lagrangian moisture source diagnostic driven by reanalysis data. Dominant winter moisture sources are the North Atlantic above 45° N. In summer local and north Eurasian continental sources dominate. In positive phases of the North Atlantic Oscillation, evaporation and moisture transport from the Norwegian Sea are stronger, resulting in more precipitation.
Ole Valk, Michiel M. Rutgers van der Loeff, Walter Geibert, Sandra Gdaniec, S. Bradley Moran, Kate Lepore, Robert Lawrence Edwards, Yanbin Lu, Viena Puigcorbé, Nuria Casacuberta, Ronja Paffrath, William Smethie, and Matthieu Roy-Barman
Ocean Sci., 16, 221–234, https://doi.org/10.5194/os-16-221-2020, https://doi.org/10.5194/os-16-221-2020, 2020
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After 2007 230Th decreased significantly in the central Amundsen Basin. This decrease is accompanied by a circulation change, indicated by changes in salinity. Ventilation of waters is most likely not the reason for the observed depletion in 230Th as atmospherically derived tracers do not reveal an increase in ventilation rate. It is suggested that these interior waters have undergone enhanced scavenging of Th during transit from Fram Strait and the Barents Sea to the central Amundsen Basin.
Haiwei Zhang, Hai Cheng, Yanjun Cai, Christoph Spötl, Ashish Sinha, Gayatri Kathayat, and Hanying Li
Clim. Past, 16, 211–225, https://doi.org/10.5194/cp-16-211-2020, https://doi.org/10.5194/cp-16-211-2020, 2020
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Few studies have paid attention to the important effect of nonsummer monsoon (NSM) precipitation on the speleothem δ18O in SE China. We find the summer monsoon precipitation is equivalent to NSM precipitation amount in the area of spring persistent rain in SE China, and we discuss the relationships between seasonal precipitation amount, moisture source, δ18O, and ENSO. Characterizing the spatial differences in seasonal precipitation is key to interpreting the speleothem δ18O record.
Gina E. Moseley, Christoph Spötl, Susanne Brandstätter, Tobias Erhardt, Marc Luetscher, and R. Lawrence Edwards
Clim. Past, 16, 29–50, https://doi.org/10.5194/cp-16-29-2020, https://doi.org/10.5194/cp-16-29-2020, 2020
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Abrupt climate change during the last ice age can be used to provide important insights into the timescales on which the climate is capable of changing and the mechanisms that drive those changes. In this study, we construct climate records for the period 60 to 120 ka using stalagmites that formed in caves along the northern rim of the European Alps and find good agreement with the timing of climate changes in Greenland and the Asian monsoon.
Mike Rogerson, Yuri Dublyansky, Dirk L. Hoffmann, Marc Luetscher, Paul Töchterle, and Christoph Spötl
Clim. Past, 15, 1757–1769, https://doi.org/10.5194/cp-15-1757-2019, https://doi.org/10.5194/cp-15-1757-2019, 2019
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Rainfall in North Africa is known to vary through time and is likely to change as global climate warms. Here, we provide a new level of understanding about past rainfall in North Africa by looking at a stalagmite which formed within northeastern Libya between 67 and 30 thousand years ago. We find that at times more rain falls, and the associated moisture is mostly derived from the western Mediterranean during winter storms. Sometimes, water comes from the eastern Mediterranean.
Hanying Li, Hai Cheng, Ashish Sinha, Gayatri Kathayat, Christoph Spötl, Aurèle Anquetil André, Arnaud Meunier, Jayant Biswas, Pengzhen Duan, Youfeng Ning, and Richard Lawrence Edwards
Clim. Past, 14, 1881–1891, https://doi.org/10.5194/cp-14-1881-2018, https://doi.org/10.5194/cp-14-1881-2018, 2018
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Gayatri Kathayat, Hai Cheng, Ashish Sinha, Max Berkelhammer, Haiwei Zhang, Pengzhen Duan, Hanying Li, Xianglei Li, Youfeng Ning, and R. Lawrence Edwards
Clim. Past, 14, 1869–1879, https://doi.org/10.5194/cp-14-1869-2018, https://doi.org/10.5194/cp-14-1869-2018, 2018
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The 4.2 ka event is generally characterized as an approximately 300-year period of major global climate anomaly. However, the climatic manifestation of this event remains unclear in the Indian monsoon domain. Our high-resolution and precisely dated speleothem record from Meghalaya, India, characterizes the event as consisting of a series of multi-decadal droughts between 3.9 and 4.0 ka rather than a singular pulse of multi-centennial drought as previously thought.
Haiwei Zhang, Hai Cheng, Yanjun Cai, Christoph Spötl, Gayatri Kathayat, Ashish Sinha, R. Lawrence Edwards, and Liangcheng Tan
Clim. Past, 14, 1805–1817, https://doi.org/10.5194/cp-14-1805-2018, https://doi.org/10.5194/cp-14-1805-2018, 2018
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The collapses of several Neolithic cultures in China are considered to have been associated with abrupt climate change during the 4.2 ka BP event; however, the hydroclimate of this event in China is still poorly known. Based on stalagmite records from monsoonal China, we found that north China was dry but south China was wet during this event. We propose that the rain belt remained longer at its southern position, giving rise to a pronounced humidity gradient between north and south China.
Florian Adolphi, Christopher Bronk Ramsey, Tobias Erhardt, R. Lawrence Edwards, Hai Cheng, Chris S. M. Turney, Alan Cooper, Anders Svensson, Sune O. Rasmussen, Hubertus Fischer, and Raimund Muscheler
Clim. Past, 14, 1755–1781, https://doi.org/10.5194/cp-14-1755-2018, https://doi.org/10.5194/cp-14-1755-2018, 2018
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The last glacial period was characterized by a number of rapid climate changes seen, for example, as abrupt warmings in Greenland and changes in monsoon rainfall intensity. However, due to chronological uncertainties it is challenging to know how tightly coupled these changes were. Here we exploit cosmogenic signals caused by changes in the Sun and Earth magnetic fields to link different climate archives and improve our understanding of the dynamics of abrupt climate change.
Gabriella Koltai, Hai Cheng, and Christoph Spötl
Clim. Past, 14, 369–381, https://doi.org/10.5194/cp-14-369-2018, https://doi.org/10.5194/cp-14-369-2018, 2018
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Here we present a multi-proxy study of flowstones in fractures of crystalline rocks with the aim of assessing the palaeoclimate significance of this new type of speleothem archive. Our results indicate a high degree of spatial heterogeneity, whereby changes in speleothem mineralogy and carbon isotope composition are likely governed by aquifer-internal processes. In contrast, the oxygen isotope composition reflects first-order climate variability.
Ny Riavo Gilbertinie Voarintsoa, Loren Bruce Railsback, George Albert Brook, Lixin Wang, Gayatri Kathayat, Hai Cheng, Xianglei Li, Richard Lawrence Edwards, Amos Fety Michel Rakotondrazafy, and Marie Olga Madison Razanatseheno
Clim. Past, 13, 1771–1790, https://doi.org/10.5194/cp-13-1771-2017, https://doi.org/10.5194/cp-13-1771-2017, 2017
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This research has been an investigation of two stalagmites from two caves in NW Madagascar to reconstruct the region's paleoenvironmental changes, and to understand the linkage of such changes to the dynamics of the ITCZ. Stable isotopes, mineralogy, and petrography suggest wetter climate conditions than today during the early and late Holocene, when the mean ITCZ was south, and drier during the mid-Holocene when the ITCZ was north.
Stef Vansteenberge, Sophie Verheyden, Hai Cheng, R. Lawrence Edwards, Eddy Keppens, and Philippe Claeys
Clim. Past, 12, 1445–1458, https://doi.org/10.5194/cp-12-1445-2016, https://doi.org/10.5194/cp-12-1445-2016, 2016
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The use of stalagmites for last interglacial continental climate reconstructions in Europe has been successful in the past; however to expand the geographical coverage, additional data from Belgium is presented. It has been shown that stalagmite growth, morphology and stable isotope content reflect regional and local climate conditions, with Eemian optimum climate occurring between 125.3 and 117.3 ka. The start the Weichselian is expressed by a stop of growth caused by a drying climate.
C. Spötl and H. Cheng
Clim. Past, 10, 1349–1362, https://doi.org/10.5194/cp-10-1349-2014, https://doi.org/10.5194/cp-10-1349-2014, 2014
M. Luetscher, M. Borreguero, G. E. Moseley, C. Spötl, and R. L. Edwards
The Cryosphere, 7, 1073–1081, https://doi.org/10.5194/tc-7-1073-2013, https://doi.org/10.5194/tc-7-1073-2013, 2013
V. E. Johnston, A. Borsato, C. Spötl, S. Frisia, and R. Miorandi
Clim. Past, 9, 99–118, https://doi.org/10.5194/cp-9-99-2013, https://doi.org/10.5194/cp-9-99-2013, 2013
Related subject area
U-series
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Inga Kristina Kerber, Fabian Kontor, Sophie Warken, and Norbert Frank
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A standalone data analysis application for Th/U dating on multi-collector inductively coupled plasma mass spectrometers features a Python-based algorithm with a graphical user interface. It handles data treatment, corrections, age calculus, and error estimation and supports various detector layouts including Faraday and electron multiplier detectors. Key features include reproducibility, user-friendly reanalysis, and automated data storage. A case study demonstrated the software’s performance.
Loïc Martin, Julius Nouet, Arnaud Dapoigny, Gaëlle Barbotin, Fanny Claverie, Edwige Pons-Branchu, Jocelyn Barbarand, Christophe Pécheyran, Norbert Mercier, Fanny Derym, Bernard Gély, and Hélène Valladas
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Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach: U–Th dating by bulk dissolution of samples and inductively coupled plasma mass spectrometry (ICP-MS), U–Th dating by laser ablation ICP-MS imaging, and radiocarbon dating. The samples were studied to ensure that they give reliable ages. Ages ranging from 187.9 ± 5.3 ka and 1.4 ± 0.1 ka were found. This approach should make it possible to establish more robust chronologies of archaeological caves.
Timothy Pollard, Jon Woodhead, John Hellstrom, John Engel, Roger Powell, and Russell Drysdale
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When using the uranium–lead (U–Pb) radiometric dating method on very young materials (e.g. Quaternary age zircon and carbonate minerals), it is important to accurately account for the production and decay of intermediate
daughterisotopes in the uranium-series decay chain. DQPB is open-source software that allows users to easily perform such calculations for a variety of sample types and produce publication-ready graphical outputs of the resulting age information.
Andrew J. Mason, Anton Vaks, Sebastian F. M. Breitenbach, John N. Hooker, and Gideon M. Henderson
Geochronology, 4, 33–54, https://doi.org/10.5194/gchron-4-33-2022, https://doi.org/10.5194/gchron-4-33-2022, 2022
Short summary
Short summary
A novel technique for the uranium–lead dating of geologically young carbonates is described and tested. The technique expands our ability to date geological events such as fault movements and past climate records.
Xianglei Li, Kathleen A. Wendt, Yuri Dublyansky, Gina E. Moseley, Christoph Spötl, and R. Lawrence Edwards
Geochronology, 3, 49–58, https://doi.org/10.5194/gchron-3-49-2021, https://doi.org/10.5194/gchron-3-49-2021, 2021
Short summary
Short summary
In this study, we built a statistical model to determine the initial δ234U in submerged calcite crusts that coat the walls of Devils Hole 2 (DH2) cave (Nevada, USA) and, using a 234U–238U dating method, extended the chronology of the calcite deposition beyond previous well-established 230Th ages and determined the oldest calcite deposited in this cave, a time marker for cave genesis. The novel method presented here may be used in future speleothem studies in similar hydrogeological settings.
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Short summary
Cryogenic cave carbonates (CCCs) provide a marker for past permafrost conditions. Their formation age is determined by Th / U dating. However, samples can be contaminated with small amounts of Th at formation, which can cause inaccurate ages and require correction. We analysed multiple CCCs and found that varying degrees of contamination can cause an apparent spread of ages, when samples actually formed within distinguishable freezing events. A correction method using isochrons is presented.
Cryogenic cave carbonates (CCCs) provide a marker for past permafrost conditions. Their...
