Articles | Volume 3, issue 1
https://doi.org/10.5194/gchron-3-67-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/gchron-3-67-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 Feb 2021
Research article |
| 03 Feb 2021
| 03 Feb 2021
Direct U–Pb dating of carbonates from micron-scale femtosecond laser ablation inductively coupled plasma mass spectrometry images using robust regression
Guilhem Hoareau
CORRESPONDING AUTHOR
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, TOTAL,
LFCR, UMR5150, 64000 Pau, France
Fanny Claverie
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM,
UMR5254, 64000 Pau, France
Christophe Pecheyran
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM,
UMR5254, 64000 Pau, France
Christian Paroissin
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, LMAP,
UMR5142, 64000 Pau, France
Pierre-Alexandre Grignard
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, TOTAL,
LFCR, UMR5150, 64000 Pau, France
Geoffrey Motte
Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, TOTAL,
LFCR, UMR5150, 64000 Pau, France
Olivier Chailan
TOTAL, CSTJF, 64018 Pau CEDEX, France
Jean-Pierre Girard
TOTAL, CSTJF, 64018 Pau CEDEX, France
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Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
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We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Olivier Lacombe, Nicolas E. Beaudoin, Guilhem Hoareau, Aurélie Labeur, Christophe Pecheyran, and Jean-Paul Callot
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Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
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G. Hoareau, B. Bomou, D. J. J. van Hinsbergen, N. Carry, D. Marquer, Y. Donnadieu, G. Le Hir, B. Vrielynck, and A.-V. Walter-Simonnet
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Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach: U–Th dating by bulk dissolution of samples and inductively coupled plasma mass spectrometry (ICP-MS), U–Th dating by laser ablation ICP-MS imaging, and radiocarbon dating. The samples were studied to ensure that they give reliable ages. Ages ranging from 187.9 ± 5.3 ka and 1.4 ± 0.1 ka were found. This approach should make it possible to establish more robust chronologies of archaeological caves.
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The impact of deep-sea mining will depend critically on the ability of larval dispersal of hydrothermal mollusks to connect and replenish natural populations. However, assessing connectivity is extremely challenging, especially in the deep sea. Here, we investigate the potential of using the chemical composition of larval shells to discriminate larval origins between multiple hydrothermal sites in the southwest Pacific. Our results confirm that this method can be applied with high accuracy.
Olivier Lacombe, Nicolas E. Beaudoin, Guilhem Hoareau, Aurélie Labeur, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 12, 2145–2157, https://doi.org/10.5194/se-12-2145-2021, https://doi.org/10.5194/se-12-2145-2021, 2021
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This paper aims to illustrate how the timing and duration of contractional deformation associated with folding in orogenic forelands can be constrained by the dating of brittle mesostructures observed in folded strata. The study combines new and already published absolute ages of fractures to provide, for the first time, an educated discussion about the factors controlling the duration of the sequence of deformation encompassing layer-parallel shortening, fold growth, and late fold tightening.
Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
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This paper reports a multiproxy approach to reconstruct the depth, timing, and extent of the past fluid flow during the formation of a fold-and-thrust belt in the Northern Apennines, Italy. The unique combination of paleopiezometry and absolute dating returns the absolute timing of the sequence of deformation. Combined with burial models, this leads to predict the expected temperatures for fluid, highlighting a limited hydrothermal fluid flow we relate to the large-scale subsurface geometry.
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This study presents the first step for a chemical origin certification of pirarucu fishery in the Amazon. A preliminary isotopic tool to improve the actual tracking system integrates ecological, social, and economic aspects of Amazon dynamics. The geographic origin validation of farmed and wild fishes contributes to environmental and social practices, secures food and income to communities, helps manage endangered species, reinforces aquaculture, and combats illegal fisheries.
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Absolute chronological constraints are crucial in Earth and planetary sciences. In recent years, U–Pb dating of carbonates has provided information on the timing of, for example, diagenesis, faulting, or hydrothermalism. These studies have targeted relatively young terrestrial carbonates up to 300 million years old. By dating 3.9 billion-year-old martian carbonates in situ using the U–Pb chronometer, we show that this system is robust in ancient samples that have had a relatively simple history.
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The article demonstrates a new technique that can be used to determine the age of calcite crystallisation using the decay of 176Lu to 176Hf. The technique is novel because (a) Lu–Hf radiometric dating is rarely applied to calcite and (b) this is the first instance where analysis has been conducted by ablating the sample with a laser beam rather than bulk dissolution. By using laser ablation the original context of the sample is preserved.
Johannes Rembe, Renjie Zhou, Edward R. Sobel, Jonas Kley, Jie Chen, Jian-Xin Zhao, Yuexing Feng, and Daryl L. Howard
Geochronology, 4, 227–250, https://doi.org/10.5194/gchron-4-227-2022, https://doi.org/10.5194/gchron-4-227-2022, 2022
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Calcite is frequently formed during alteration processes in the basaltic, uppermost layer of juvenile oceanic crust. Weathered oceanic basalts are hard to date with conventional radiometric methods. We show in a case study from the North Pamir, Central Asia, that calcite U–Pb age data, supported by geochemistry and petrological microscopy, have potential to date sufficiently old oceanic basalts, if the time span between basalt extrusion and latest calcite precipitation (~ 25 Myr) is considered.
Bar Elisha, Perach Nuriel, Andrew Kylander-Clark, and Ram Weinberger
Geochronology, 3, 337–349, https://doi.org/10.5194/gchron-3-337-2021, https://doi.org/10.5194/gchron-3-337-2021, 2021
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Distinguishing between different dolomitization processes is challenging yet critical for resolving some of the issues and ambiguities related to the formation of dolomitic rocks. Accurate U–Pb absolute dating of dolomite by LA-ICP-MS could contribute to a better understanding of the dolomitization process by placing syngenetic, early diagenetic, and/or epigenetic events in the proper geological context.
Louise Lenoir, Thomas Blaise, Andréa Somogyi, Benjamin Brigaud, Jocelyn Barbarand, Claire Boukari, Julius Nouet, Aurore Brézard-Oudot, and Maurice Pagel
Geochronology, 3, 199–227, https://doi.org/10.5194/gchron-3-199-2021, https://doi.org/10.5194/gchron-3-199-2021, 2021
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To explore the U–Pb geochronometer in fluorite, the spatial distribution of uranium and other substituted elements in natural crystals is investigated using induced fission-track and synchrotron radiation X-ray fluorescence mapping. LA-ICP-MS U–Pb dating on four crystals, which preserve micrometer-scale variations in U concentrations, yields identical ages within analytical uncertainty. Our results show that fluorite U–Pb geochronology has potential for dating distinct crystal growth stages.
Veronica Peverelli, Tanya Ewing, Daniela Rubatto, Martin Wille, Alfons Berger, Igor Maria Villa, Pierre Lanari, Thomas Pettke, and Marco Herwegh
Geochronology, 3, 123–147, https://doi.org/10.5194/gchron-3-123-2021, https://doi.org/10.5194/gchron-3-123-2021, 2021
Short summary
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This work presents LA-ICP-MS U–Pb geochronology of epidote in hydrothermal veins. The challenges of epidote dating are addressed, and a protocol is proposed allowing us to obtain epidote U–Pb ages with a precision as good as 5 % in addition to the initial Pb isotopic composition of the epidote-forming fluid. Epidote demonstrates its potential to be used as a U–Pb geochronometer and as a fluid tracer, allowing us to reconstruct the timing of hydrothermal activity and the origin of the fluid(s).
E. Troy Rasbury, Theodore M. Present, Paul Northrup, Ryan V. Tappero, Antonio Lanzirotti, Jennifer M. Cole, Kathleen M. Wooton, and Kevin Hatton
Geochronology, 3, 103–122, https://doi.org/10.5194/gchron-3-103-2021, https://doi.org/10.5194/gchron-3-103-2021, 2021
Short summary
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We characterize three natural carbonate samples with elevated uranium/lead (U/Pb) ratios to demonstrate techniques improving the understanding of U incorporation in carbonates for U/Pb dating. With the rapidly accelerating application of laser ablation analyses, there is a great need for well-characterized reference materials that can serve multiple functions. Strontium (Sr) isotope analyses and U XANES demonstrate that these samples could be used as reference materials.
Fanis Abdullin, Luigi A. Solari, Jesús Solé, and Carlos Ortega-Obregón
Geochronology, 3, 59–65, https://doi.org/10.5194/gchron-3-59-2021, https://doi.org/10.5194/gchron-3-59-2021, 2021
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Unetched and etched apatite grains from five samples were dated by U–Pb method using laser ablation inductively coupled plasma mass spectrometry. Our experiment indicates that etching needed for apatite fission track dating has insignificant effects on obtaining accurate U–Pb ages; thus, the laser ablation-based technique may be used for apatite fission track and U–Pb double dating.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
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This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Andrew R. C. Kylander-Clark
Geochronology, 2, 343–354, https://doi.org/10.5194/gchron-2-343-2020, https://doi.org/10.5194/gchron-2-343-2020, 2020
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This paper serves as a guide to those interested in dating calcite by laser ablation. Within it are theoretical and practical limits of U and Pb concentrations (and U / Pb ratios), which would allow viable extraction of ages from calcite (and other minerals with moderate U / Pb ratios), and which type of instrumentation would be appropriate for any given sample. The method described uses a new detector array, allowing for lower detection limits and thereby expanding the range of viable samples.
Hugo K. H. Olierook, Kai Rankenburg, Stanislav Ulrich, Christopher L. Kirkland, Noreen J. Evans, Stephen Brown, Brent I. A. McInnes, Alexander Prent, Jack Gillespie, Bradley McDonald, and Miles Darragh
Geochronology, 2, 283–303, https://doi.org/10.5194/gchron-2-283-2020, https://doi.org/10.5194/gchron-2-283-2020, 2020
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Using a relatively new dating technique, in situ Rb–Sr geochronology, we constrain the ages of two generations of mineral assemblages from the Tropicana Zone, Western Australia. The first, dated at ca. 2535 Ma, is associated with exhumation of an Archean craton margin and gold mineralization. The second, dated at ca. 1210 Ma, has not been previously documented in the Tropicana Zone. It is probably associated with Stage II of the Albany–Fraser Orogeny and additional gold mineralization.
George Gehrels, Dominique Giesler, Paul Olsen, Dennis Kent, Adam Marsh, William Parker, Cornelia Rasmussen, Roland Mundil, Randall Irmis, John Geissman, and Christopher Lepre
Geochronology, 2, 257–282, https://doi.org/10.5194/gchron-2-257-2020, https://doi.org/10.5194/gchron-2-257-2020, 2020
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U–Pb ages of zircon crystals are used to determine the provenance and depositional age of strata of the Triassic Chinle and Moenkopi formations and the Permian Coconino Sandstone of northern Arizona. Primary source regions include the Ouachita orogen, local Precambrian basement rocks, and Permian–Triassic magmatic arcs to the south and west. Ages from fine-grained strata provide reliable depositional ages, whereas ages from sandstones are compromised by zircon grains recycled from older strata.
Marcel Guillong, Jörn-Frederik Wotzlaw, Nathan Looser, and Oscar Laurent
Geochronology, 2, 155–167, https://doi.org/10.5194/gchron-2-155-2020, https://doi.org/10.5194/gchron-2-155-2020, 2020
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The dating of carbonates by laser ablation inductively coupled plasma mass spectrometry is improved by an additional, newly characterised reference material and adapted data evaluation protocols: the shape (diameter to depth) of the ablation crater has to be as similar as possible in the reference material used and the unknown samples to avoid an offset. Different carbonates have different ablation rates per laser pulse. With robust uncertainty propagation, precision can be as good as 2–3 %.
Nick M. W. Roberts, Kerstin Drost, Matthew S. A. Horstwood, Daniel J. Condon, David Chew, Henrik Drake, Antoni E. Milodowski, Noah M. McLean, Andrew J. Smye, Richard J. Walker, Richard Haslam, Keith Hodson, Jonathan Imber, Nicolas Beaudoin, and Jack K. Lee
Geochronology, 2, 33–61, https://doi.org/10.5194/gchron-2-33-2020, https://doi.org/10.5194/gchron-2-33-2020, 2020
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Here we review current progress in LA-ICP-MS U–Pb carbonate geochronology and present strategies for acquisition and interpretation of carbonate U–Pb dates. We cover topics from imaging techniques and U and Pb incorporation into calcite to potential limitations of the method – disequilibrium and isotope mobility. We demonstrate the incorporation of imaging and compositional data to help refine and interpret U–Pb dates. We expect this paper to become a
go-toreference paper for years to come.
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Short summary
A new methodology for the micron-scale uranium–lead dating of carbonate minerals is proposed. It is based on the extraction of ages directly from pixel images (< 1 mm2) obtained by laser ablation coupled to a mass spectrometer. The ages are calculated with a robust linear regression through the pixel values. This methodology is compared to existing approaches.
A new methodology for the micron-scale uranium–lead dating of carbonate minerals is proposed. It...
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