Articles | Volume 6, issue 2
https://doi.org/10.5194/gchron-6-247-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-6-247-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A new multimethod approach for dating cave calcite: application to the cave of Trou du Renard (Soyons, France)
LSCE/IPSL, UMR 8212, CEA-CNRS-UVSQ, Université Paris-Saclay, Chemin de Saint Aubin – RD 128, 91191 Gif-sur-Yvette CEDEX, France
Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM, Avenue de l'Université, BP 576, 64012 Pau CEDEX, France
Julius Nouet
Géosciences Paris Saclay, Université Paris-Saclay, CNRS, bâtiment 504, 91405 Orsay, France
Arnaud Dapoigny
LSCE/IPSL, UMR 8212, CEA-CNRS-UVSQ, Université Paris-Saclay, Chemin de Saint Aubin – RD 128, 91191 Gif-sur-Yvette CEDEX, France
Gaëlle Barbotin
Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM, Avenue de l'Université, BP 576, 64012 Pau CEDEX, France
Fanny Claverie
Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM, Avenue de l'Université, BP 576, 64012 Pau CEDEX, France
Edwige Pons-Branchu
LSCE/IPSL, UMR 8212, CEA-CNRS-UVSQ, Université Paris-Saclay, Chemin de Saint Aubin – RD 128, 91191 Gif-sur-Yvette CEDEX, France
Jocelyn Barbarand
Géosciences Paris Saclay, Université Paris-Saclay, CNRS, bâtiment 504, 91405 Orsay, France
Christophe Pécheyran
Université de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM, Avenue de l'Université, BP 576, 64012 Pau CEDEX, France
Norbert Mercier
Archéosciences Bordeaux, UMR 6034 CNRS – Université Bordeaux Montaigne, Maison de l'archéologie, Esplanade des Antilles, 33607 Pessac CEDEX, France
Fanny Derym
Site archéologique de Soyons, 28 rue de l'église, 07130 Soyons, France
Bernard Gély
Service Régional de l'Archéologie de la région Rhône-Alpes, 6 quai Saint Vincent, 69283 Lyon CEDEX, France
Hélène Valladas
LSCE/IPSL, UMR 8212, CEA-CNRS-UVSQ, Université Paris-Saclay, Chemin de Saint Aubin – RD 128, 91191 Gif-sur-Yvette CEDEX, France
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Sebastian Kreutzer, Loïc Martin, Didier Miallier, and Norbert Mercier
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-31, https://doi.org/10.5194/gchron-2024-31, 2024
Preprint under review for GChron
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Accurate readings on the environmental gamma dose rate are important. Portable gamma-ray detectors, such as NaI or LaBr3-based, are easy to handle and affordable. Limited information on alternatives, like CZT (Cadmium Zinc Telluride) detectors is available. We tested CZT detectors and found them suitable for in-field deployment. We used simulations and field tests to evaluate the optimal energy threshold for direct dose rate readings, making the CZT system a reliable alternative.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
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We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Clémence Paul, Clément Piel, Joana Sauze, Olivier Jossoud, Arnaud Dapoigny, Daniele Romanini, Frédérique Prié, Sébastien Devidal, Roxanne Jacob, Alexandru Milcu, and Amaëlle Landais
EGUsphere, https://doi.org/10.5194/egusphere-2024-1755, https://doi.org/10.5194/egusphere-2024-1755, 2024
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Our study investigated the influence of plant processes on oxygen dynamics, crucial for paleoclimatology. By examining maize respiration and photosynthesis using advanced techniques, we enhanced our understanding of past climates through ice core analysis.
Vincent Mouchi, Christophe Pecheyran, Fanny Claverie, Cécile Cathalot, Marjolaine Matabos, Yoan Germain, Olivier Rouxel, Didier Jollivet, Thomas Broquet, and Thierry Comtet
Biogeosciences, 21, 145–160, https://doi.org/10.5194/bg-21-145-2024, https://doi.org/10.5194/bg-21-145-2024, 2024
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The impact of deep-sea mining will depend critically on the ability of larval dispersal of hydrothermal mollusks to connect and replenish natural populations. However, assessing connectivity is extremely challenging, especially in the deep sea. Here, we investigate the potential of using the chemical composition of larval shells to discriminate larval origins between multiple hydrothermal sites in the southwest Pacific. Our results confirm that this method can be applied with high accuracy.
Clémence Paul, Clément Piel, Joana Sauze, Nicolas Pasquier, Frédéric Prié, Sébastien Devidal, Roxanne Jacob, Arnaud Dapoigny, Olivier Jossoud, Alexandru Milcu, and Amaëlle Landais
Biogeosciences, 20, 1047–1062, https://doi.org/10.5194/bg-20-1047-2023, https://doi.org/10.5194/bg-20-1047-2023, 2023
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To improve the interpretation of the δ18Oatm and Δ17O of O2 in air bubbles in ice cores, we need to better quantify the oxygen fractionation coefficients associated with biological processes. We performed a simplified analogue of the terrestrial biosphere in a closed chamber. We found a respiration fractionation in agreement with the previous estimates at the microorganism scale, and a terrestrial photosynthetic fractionation was found. This has an impact on the estimation of the Dole effect.
Norbert Mercier, Jean-Michel Galharret, Chantal Tribolo, Sebastian Kreutzer, and Anne Philippe
Geochronology, 4, 297–310, https://doi.org/10.5194/gchron-4-297-2022, https://doi.org/10.5194/gchron-4-297-2022, 2022
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Dosimetric dating methods based on the analysis of luminescence signals emitted by granular minerals extracted from sedimentary deposits now play an important role in the study of the Quaternary. Here we propose a new approach in which the age of the deposit is calculated by combining the equivalent dose and dose-rate distributions. The underlying Bayesian mathematical model and its implementation via an R code are provided, together with the results obtained for a finite set of configurations.
Olivier Lacombe, Nicolas E. Beaudoin, Guilhem Hoareau, Aurélie Labeur, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 12, 2145–2157, https://doi.org/10.5194/se-12-2145-2021, https://doi.org/10.5194/se-12-2145-2021, 2021
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This paper aims to illustrate how the timing and duration of contractional deformation associated with folding in orogenic forelands can be constrained by the dating of brittle mesostructures observed in folded strata. The study combines new and already published absolute ages of fractures to provide, for the first time, an educated discussion about the factors controlling the duration of the sequence of deformation encompassing layer-parallel shortening, fold growth, and late fold tightening.
Barbara Mauz, Loïc Martin, Michael Discher, Chantal Tribolo, Sebastian Kreutzer, Chiara Bahl, Andreas Lang, and Nobert Mercier
Geochronology, 3, 371–381, https://doi.org/10.5194/gchron-3-371-2021, https://doi.org/10.5194/gchron-3-371-2021, 2021
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Luminescence dating requires irradiating the sample in the laboratory. Here, we address some concerns about the reliability of the calibration procedure that have been published recently. We found that the interplay between geometrical parameters such as grain size and aliquot size impacts the calibration value more than previously thought. The results of our study are robust and allow us to recommend an improved calibration procedure in order to enhance the reliability of the calibration value.
Louise Lenoir, Thomas Blaise, Andréa Somogyi, Benjamin Brigaud, Jocelyn Barbarand, Claire Boukari, Julius Nouet, Aurore Brézard-Oudot, and Maurice Pagel
Geochronology, 3, 199–227, https://doi.org/10.5194/gchron-3-199-2021, https://doi.org/10.5194/gchron-3-199-2021, 2021
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To explore the U–Pb geochronometer in fluorite, the spatial distribution of uranium and other substituted elements in natural crystals is investigated using induced fission-track and synchrotron radiation X-ray fluorescence mapping. LA-ICP-MS U–Pb dating on four crystals, which preserve micrometer-scale variations in U concentrations, yields identical ages within analytical uncertainty. Our results show that fluorite U–Pb geochronology has potential for dating distinct crystal growth stages.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Christian Paroissin, Pierre-Alexandre Grignard, Geoffrey Motte, Olivier Chailan, and Jean-Pierre Girard
Geochronology, 3, 67–87, https://doi.org/10.5194/gchron-3-67-2021, https://doi.org/10.5194/gchron-3-67-2021, 2021
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A new methodology for the micron-scale uranium–lead dating of carbonate minerals is proposed. It is based on the extraction of ages directly from pixel images (< 1 mm2) obtained by laser ablation coupled to a mass spectrometer. The ages are calculated with a robust linear regression through the pixel values. This methodology is compared to existing approaches.
Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 11, 1617–1641, https://doi.org/10.5194/se-11-1617-2020, https://doi.org/10.5194/se-11-1617-2020, 2020
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This paper reports a multiproxy approach to reconstruct the depth, timing, and extent of the past fluid flow during the formation of a fold-and-thrust belt in the Northern Apennines, Italy. The unique combination of paleopiezometry and absolute dating returns the absolute timing of the sequence of deformation. Combined with burial models, this leads to predict the expected temperatures for fluid, highlighting a limited hydrothermal fluid flow we relate to the large-scale subsurface geometry.
Luciana A. Pereira, Roberto V. Santos, Marília Hauser, Fabrice Duponchelle, Fernando Carvajal, Christophe Pecheyran, Sylvain Bérail, and Marc Pouilly
Biogeosciences, 16, 1781–1797, https://doi.org/10.5194/bg-16-1781-2019, https://doi.org/10.5194/bg-16-1781-2019, 2019
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This study presents the first step for a chemical origin certification of pirarucu fishery in the Amazon. A preliminary isotopic tool to improve the actual tracking system integrates ecological, social, and economic aspects of Amazon dynamics. The geographic origin validation of farmed and wild fishes contributes to environmental and social practices, secures food and income to communities, helps manage endangered species, reinforces aquaculture, and combats illegal fisheries.
Claire Waelbroeck, Sylvain Pichat, Evelyn Böhm, Bryan C. Lougheed, Davide Faranda, Mathieu Vrac, Lise Missiaen, Natalia Vazquez Riveiros, Pierre Burckel, Jörg Lippold, Helge W. Arz, Trond Dokken, François Thil, and Arnaud Dapoigny
Clim. Past, 14, 1315–1330, https://doi.org/10.5194/cp-14-1315-2018, https://doi.org/10.5194/cp-14-1315-2018, 2018
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Recording the precise timing and sequence of events is essential for understanding rapid climate changes and improving climate model predictive skills. Here, we precisely assess the relative timing between ocean and atmospheric changes, both recorded in the same deep-sea core over the last 45 kyr. We show that decreased mid-depth water mass transport in the western equatorial Atlantic preceded increased rainfall over the adjacent continent by 120 to 980 yr, depending on the type of climate event.
Quentin Dubois-Dauphin, Paolo Montagna, Giuseppe Siani, Eric Douville, Claudia Wienberg, Dierk Hebbeln, Zhifei Liu, Nejib Kallel, Arnaud Dapoigny, Marie Revel, Edwige Pons-Branchu, Marco Taviani, and Christophe Colin
Clim. Past, 13, 17–37, https://doi.org/10.5194/cp-13-17-2017, https://doi.org/10.5194/cp-13-17-2017, 2017
Related subject area
U-series
Technical note: „U-Th Analysis” – an open-source software dedicated to MCICPMS U-series-data treatment and evaluation
DQPB: software for calculating disequilibrium U–Pb ages
230Th ∕ U isochron dating of cryogenic cave carbonates
A simplified isotope dilution approach for the U–Pb dating of speleogenic and other low-232Th carbonates by multi-collector ICP-MS
Novel method for determining 234U–238U ages of Devils Hole 2 cave calcite (Nevada)
Inga Kristina Kerber, Fabian Kontor, Sophie Warken, and Norbert Frank
EGUsphere, https://doi.org/10.5194/egusphere-2024-1788, https://doi.org/10.5194/egusphere-2024-1788, 2024
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A standalone data analysis application for Th/U dating on multi-collector inductively coupled plasma mass spectrometers features a Python-based algorithm with a graphical user interface. It handles data treatment, corrections, age calculus, and error estimation and supports various detector layouts including Faraday and electron multiplier detectors. Key features include reproducibility, user-friendly reanalysis, and automated data storage. A case study demonstrated the software’s performance.
Timothy Pollard, Jon Woodhead, John Hellstrom, John Engel, Roger Powell, and Russell Drysdale
Geochronology, 5, 181–196, https://doi.org/10.5194/gchron-5-181-2023, https://doi.org/10.5194/gchron-5-181-2023, 2023
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When using the uranium–lead (U–Pb) radiometric dating method on very young materials (e.g. Quaternary age zircon and carbonate minerals), it is important to accurately account for the production and decay of intermediate
daughterisotopes in the uranium-series decay chain. DQPB is open-source software that allows users to easily perform such calculations for a variety of sample types and produce publication-ready graphical outputs of the resulting age information.
Paul Töchterle, Simon D. Steidle, R. Lawrence Edwards, Yuri Dublyansky, Christoph Spötl, Xianglei Li, John Gunn, and Gina E. Moseley
Geochronology, 4, 617–627, https://doi.org/10.5194/gchron-4-617-2022, https://doi.org/10.5194/gchron-4-617-2022, 2022
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Cryogenic cave carbonates (CCCs) provide a marker for past permafrost conditions. Their formation age is determined by Th / U dating. However, samples can be contaminated with small amounts of Th at formation, which can cause inaccurate ages and require correction. We analysed multiple CCCs and found that varying degrees of contamination can cause an apparent spread of ages, when samples actually formed within distinguishable freezing events. A correction method using isochrons is presented.
Andrew J. Mason, Anton Vaks, Sebastian F. M. Breitenbach, John N. Hooker, and Gideon M. Henderson
Geochronology, 4, 33–54, https://doi.org/10.5194/gchron-4-33-2022, https://doi.org/10.5194/gchron-4-33-2022, 2022
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A novel technique for the uranium–lead dating of geologically young carbonates is described and tested. The technique expands our ability to date geological events such as fault movements and past climate records.
Xianglei Li, Kathleen A. Wendt, Yuri Dublyansky, Gina E. Moseley, Christoph Spötl, and R. Lawrence Edwards
Geochronology, 3, 49–58, https://doi.org/10.5194/gchron-3-49-2021, https://doi.org/10.5194/gchron-3-49-2021, 2021
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In this study, we built a statistical model to determine the initial δ234U in submerged calcite crusts that coat the walls of Devils Hole 2 (DH2) cave (Nevada, USA) and, using a 234U–238U dating method, extended the chronology of the calcite deposition beyond previous well-established 230Th ages and determined the oldest calcite deposited in this cave, a time marker for cave genesis. The novel method presented here may be used in future speleothem studies in similar hydrogeological settings.
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Short summary
Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach: U–Th dating by bulk dissolution of samples and inductively coupled plasma mass spectrometry (ICP-MS), U–Th dating by laser ablation ICP-MS imaging, and radiocarbon dating. The samples were studied to ensure that they give reliable ages. Ages ranging from 187.9 ± 5.3 ka and 1.4 ± 0.1 ka were found. This approach should make it possible to establish more robust chronologies of archaeological caves.
Carbonate wall deposits of Trou du Renard cave (France) were dated using a multimethod approach:...