Articles | Volume 2, issue 1
https://doi.org/10.5194/gchron-2-33-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/gchron-2-33-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Apr 2020
Research article |
| 09 Apr 2020
| 09 Apr 2020
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb carbonate geochronology: strategies, progress, and limitations
Geochronology and Tracers Facility, British Geological Survey,
Environmental Science Centre, Nottingham, NG12 5GG, UK
Kerstin Drost
Department of Geology, Trinity College Dublin, Dublin, Ireland
Matthew S. A. Horstwood
Geochronology and Tracers Facility, British Geological Survey,
Environmental Science Centre, Nottingham, NG12 5GG, UK
Daniel J. Condon
Geochronology and Tracers Facility, British Geological Survey,
Environmental Science Centre, Nottingham, NG12 5GG, UK
David Chew
Department of Geology, Trinity College Dublin, Dublin, Ireland
Henrik Drake
Department of Biology and Environmental Science, Linnaeus University, 39231 Kalmar, Sweden
Antoni E. Milodowski
British Geological Survey, Environmental Science Centre, Nottingham, NG12 5GG, UK
Noah M. McLean
Department of Geology, University of Kansas, Lawrence, KS 66045, USA
Andrew J. Smye
Department of Geosciences, Pennsylvania State University, University Park, PA 16802, USA
Richard J. Walker
School of Geography, Geology, and the Environment, University of
Leicester, Leicester, LE1 7RH, UK
Richard Haslam
British Geological Survey, Environmental Science Centre, Nottingham, NG12 5GG, UK
Keith Hodson
Department of Earth and Space Sciences, University of Washington,
Seattle, WA 98195, USA
Jonathan Imber
Department of Earth Sciences, Durham University, Science Labs, Durham,
DH1 3LE, UK
Nicolas Beaudoin
Laboratoire des Fluides Complexes et leurs Réservoirs-IPRA,
E2SUPPA, Total, CNRS, Université de Pau et des Pays de l'Adour, UMR5150,
Pau, France
Jack K. Lee
Department of Earth Sciences, Durham University, Science Labs, Durham,
DH1 3LE, UK
Related authors
Henning Lorenz, Jan-Erik Rosberg, Christopher Juhlin, Iwona Klonowska, Rodolphe Lescoutre, George Westmeijer, Bjarne S. G. Almqvist, Mark Anderson, Stefan Bertilsson, Mark Dopson, Jens Kallmeyer, Jochem Kück, Oliver Lehnert, Luca Menegon, Christophe Pascal, Simon Rejkjær, and Nick N. W. Roberts
Sci. Dril., 30, 43–57, https://doi.org/10.5194/sd-30-43-2022, https://doi.org/10.5194/sd-30-43-2022, 2022
Short summary
Short summary
The Collisional Orogeny in the Scandinavian Caledonides project provides insights into the deep structure and bedrock of a ca. 400 Ma old major orogen to study deformation processes that are hidden at depth from direct access in modern mountain belts. This paper describes the successful operations at the second site. It provides an overview of the retrieved geological section that differs from the expected and summarises the scientific potential of the accomplished data sets and drill core.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
Short summary
Short summary
This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Nick M. W. Roberts, Jack K. Lee, Robert E. Holdsworth, Christopher Jeans, Andrew R. Farrant, and Richard Haslam
Solid Earth, 11, 1931–1945, https://doi.org/10.5194/se-11-1931-2020, https://doi.org/10.5194/se-11-1931-2020, 2020
Short summary
Short summary
We characterise a well-known fractured and faulted exposure of Cretaceous chalk in NE England, combining field observations with novel U–Pb calcite dating. We show that the faulting and associated fluid flow occurred during the interval of ca. 64–56 Ma, predating earlier estimates of Alpine-related tectonic inversion. We demonstrate that the main extensional fault zone acted as a conduit linking voluminous fluid flow and linking deeper sedimentary layers with the shallow subsurface.
Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 11, 1617–1641, https://doi.org/10.5194/se-11-1617-2020, https://doi.org/10.5194/se-11-1617-2020, 2020
Short summary
Short summary
This paper reports a multiproxy approach to reconstruct the depth, timing, and extent of the past fluid flow during the formation of a fold-and-thrust belt in the Northern Apennines, Italy. The unique combination of paleopiezometry and absolute dating returns the absolute timing of the sequence of deformation. Combined with burial models, this leads to predict the expected temperatures for fluid, highlighting a limited hydrothermal fluid flow we relate to the large-scale subsurface geometry.
H. Lorenz, J.-E. Rosberg, C. Juhlin, L. Bjelm, B. S. G. Almqvist, T. Berthet, R. Conze, D. G. Gee, I. Klonowska, C. Pascal, K. Pedersen, N. M. W. Roberts, and C.-F. Tsang
Sci. Dril., 19, 1–11, https://doi.org/10.5194/sd-19-1-2015, https://doi.org/10.5194/sd-19-1-2015, 2015
Short summary
Short summary
The Collisional Orogeny in the Scandinavian Caledonides (COSC) scientific drilling project successfully drilled a 2.5km fully cored borehole (COSC-1) through allochthonous subduction-related high-grade metamorphic gneisses and into the underlying thrust zone. This paper summarizes the scientific rationale of the project and presents first preliminary results.
Jesse R. Reimink, Renan Beckman, Erik Schoonover, Max Lloyd, Joshua Garber, Joshua H. F. L. Davies, Alexander Cerminaro, Morgann G. Perrot, and Andrew J. Smye
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-27, https://doi.org/10.5194/gchron-2024-27, 2024
Preprint under review for GChron
Short summary
Short summary
This manuscript presents a new method to date geological events affecting sedimentary rocks. This method relies on the potential for the zircon U-Pb system to be disturbed during fluid-flow, alteration, and metamorphic events in sedimentary rocks. This manuscript presents synthetic datasets for testing the accuracy and precision of the discordance dating method, as well as data from detrital zircons found in the contact metamorphic aureole surround the Alta Stock.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
Short summary
Short summary
We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Vincent Monchal, Remi Rateau, Kerstin Drost, Cyril Gagnaison, Bastien Mennecart, Renaud Toullec, and David Chew
EGUsphere, https://doi.org/10.5194/egusphere-2024-2325, https://doi.org/10.5194/egusphere-2024-2325, 2024
Short summary
Short summary
Sedimentary rocks are typically dated indirectly, by comparing the fossil content of basins with the geological timescale. In this study, we employed an absolute dating approach to date 19 million year old sediments in the Paris Basin, using uranium-lead dating of calcite nodules associated with soil formation. The precision of our new ages enable more accurate comparisons (independent of their fossil contents) between the Paris Basin and other basins of similar age.
Joaquín Bastías-Silva, David Chew, Fernando Poblete, Paula Castillo, William Guenthner, Anne Grunow, Ian W. D. Dalziel, Airton N. C. Dias, Cristóbal Ramírez de Arellano, and Rodrigo Fernandez
Solid Earth, 15, 555–566, https://doi.org/10.5194/se-15-555-2024, https://doi.org/10.5194/se-15-555-2024, 2024
Short summary
Short summary
The Ellsworth Mountains, situated in a remote area of Antarctica, span 350 km in length and 50 km in width, encompassing Antarctica's tallest peak. Due to their isolated location, understanding their formation has been challenging and remains incomplete. Our analysis of zircon minerals from the Ellsworth Mountains indicates that the mountain chain formed between 180 and 100 million years ago, contributing to our understanding of their formation.
Stephen P. Hesselbo, Aisha Al-Suwaidi, Sarah J. Baker, Giorgia Ballabio, Claire M. Belcher, Andrew Bond, Ian Boomer, Remco Bos, Christian J. Bjerrum, Kara Bogus, Richard Boyle, James V. Browning, Alan R. Butcher, Daniel J. Condon, Philip Copestake, Stuart Daines, Christopher Dalby, Magret Damaschke, Susana E. Damborenea, Jean-Francois Deconinck, Alexander J. Dickson, Isabel M. Fendley, Calum P. Fox, Angela Fraguas, Joost Frieling, Thomas A. Gibson, Tianchen He, Kat Hickey, Linda A. Hinnov, Teuntje P. Hollaar, Chunju Huang, Alexander J. L. Hudson, Hugh C. Jenkyns, Erdem Idiz, Mengjie Jiang, Wout Krijgsman, Christoph Korte, Melanie J. Leng, Timothy M. Lenton, Katharina Leu, Crispin T. S. Little, Conall MacNiocaill, Miguel O. Manceñido, Tamsin A. Mather, Emanuela Mattioli, Kenneth G. Miller, Robert J. Newton, Kevin N. Page, József Pálfy, Gregory Pieńkowski, Richard J. Porter, Simon W. Poulton, Alberto C. Riccardi, James B. Riding, Ailsa Roper, Micha Ruhl, Ricardo L. Silva, Marisa S. Storm, Guillaume Suan, Dominika Szűcs, Nicolas Thibault, Alfred Uchman, James N. Stanley, Clemens V. Ullmann, Bas van de Schootbrugge, Madeleine L. Vickers, Sonja Wadas, Jessica H. Whiteside, Paul B. Wignall, Thomas Wonik, Weimu Xu, Christian Zeeden, and Ke Zhao
Sci. Dril., 32, 1–25, https://doi.org/10.5194/sd-32-1-2023, https://doi.org/10.5194/sd-32-1-2023, 2023
Short summary
Short summary
We present initial results from a 650 m long core of Late Triasssic to Early Jurassic (190–202 Myr) sedimentary strata from the Cheshire Basin, UK, which is shown to be an exceptional record of Earth evolution for the time of break-up of the supercontinent Pangaea. Further work will determine periodic changes in depositional environments caused by solar system dynamics and used to reconstruct orbital history.
Henning Lorenz, Jan-Erik Rosberg, Christopher Juhlin, Iwona Klonowska, Rodolphe Lescoutre, George Westmeijer, Bjarne S. G. Almqvist, Mark Anderson, Stefan Bertilsson, Mark Dopson, Jens Kallmeyer, Jochem Kück, Oliver Lehnert, Luca Menegon, Christophe Pascal, Simon Rejkjær, and Nick N. W. Roberts
Sci. Dril., 30, 43–57, https://doi.org/10.5194/sd-30-43-2022, https://doi.org/10.5194/sd-30-43-2022, 2022
Short summary
Short summary
The Collisional Orogeny in the Scandinavian Caledonides project provides insights into the deep structure and bedrock of a ca. 400 Ma old major orogen to study deformation processes that are hidden at depth from direct access in modern mountain belts. This paper describes the successful operations at the second site. It provides an overview of the retrieved geological section that differs from the expected and summarises the scientific potential of the accomplished data sets and drill core.
Olivier Lacombe, Nicolas E. Beaudoin, Guilhem Hoareau, Aurélie Labeur, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 12, 2145–2157, https://doi.org/10.5194/se-12-2145-2021, https://doi.org/10.5194/se-12-2145-2021, 2021
Short summary
Short summary
This paper aims to illustrate how the timing and duration of contractional deformation associated with folding in orogenic forelands can be constrained by the dating of brittle mesostructures observed in folded strata. The study combines new and already published absolute ages of fractures to provide, for the first time, an educated discussion about the factors controlling the duration of the sequence of deformation encompassing layer-parallel shortening, fold growth, and late fold tightening.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
Short summary
Short summary
This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Nick M. W. Roberts, Jack K. Lee, Robert E. Holdsworth, Christopher Jeans, Andrew R. Farrant, and Richard Haslam
Solid Earth, 11, 1931–1945, https://doi.org/10.5194/se-11-1931-2020, https://doi.org/10.5194/se-11-1931-2020, 2020
Short summary
Short summary
We characterise a well-known fractured and faulted exposure of Cretaceous chalk in NE England, combining field observations with novel U–Pb calcite dating. We show that the faulting and associated fluid flow occurred during the interval of ca. 64–56 Ma, predating earlier estimates of Alpine-related tectonic inversion. We demonstrate that the main extensional fault zone acted as a conduit linking voluminous fluid flow and linking deeper sedimentary layers with the shallow subsurface.
Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 11, 1617–1641, https://doi.org/10.5194/se-11-1617-2020, https://doi.org/10.5194/se-11-1617-2020, 2020
Short summary
Short summary
This paper reports a multiproxy approach to reconstruct the depth, timing, and extent of the past fluid flow during the formation of a fold-and-thrust belt in the Northern Apennines, Italy. The unique combination of paleopiezometry and absolute dating returns the absolute timing of the sequence of deformation. Combined with burial models, this leads to predict the expected temperatures for fluid, highlighting a limited hydrothermal fluid flow we relate to the large-scale subsurface geometry.
Jack H. Lacey, Melanie J. Leng, Alexander Francke, Hilary J. Sloane, Antoni Milodowski, Hendrik Vogel, Henrike Baumgarten, Giovanni Zanchetta, and Bernd Wagner
Biogeosciences, 13, 1801–1820, https://doi.org/10.5194/bg-13-1801-2016, https://doi.org/10.5194/bg-13-1801-2016, 2016
Short summary
Short summary
We use stable isotope data from carbonates to provide a palaeoenvironmental reconstruction covering the last 637 kyr at Lake Ohrid (FYROM/Albania). Our results indicate a relatively stable climate until 450 ka, wetter climate conditions at 400–250 ka, and a transition to a drier climate after 250 ka. This work emphasises the importance of Lake Ohrid as a valuable archive of climate change in the northern Mediterranean region.
D. J. Condon, P. Boggiani, D. Fike, G. P. Halverson, S. Kasemann, A. H. Knoll, F. A. Macdonald, A. R. Prave, and M. Zhu
Sci. Dril., 19, 17–25, https://doi.org/10.5194/sd-19-17-2015, https://doi.org/10.5194/sd-19-17-2015, 2015
Short summary
Short summary
This workshop report outlines the background, topics discussed and major conclusions/future directions arising form an ICDP- and ECORD-sponsored workshop convened to discuss the utility of scientific drilling for accelerating Neoproterozoic research.
H. Lorenz, J.-E. Rosberg, C. Juhlin, L. Bjelm, B. S. G. Almqvist, T. Berthet, R. Conze, D. G. Gee, I. Klonowska, C. Pascal, K. Pedersen, N. M. W. Roberts, and C.-F. Tsang
Sci. Dril., 19, 1–11, https://doi.org/10.5194/sd-19-1-2015, https://doi.org/10.5194/sd-19-1-2015, 2015
Short summary
Short summary
The Collisional Orogeny in the Scandinavian Caledonides (COSC) scientific drilling project successfully drilled a 2.5km fully cored borehole (COSC-1) through allochthonous subduction-related high-grade metamorphic gneisses and into the underlying thrust zone. This paper summarizes the scientific rationale of the project and presents first preliminary results.
Related subject area
SIMS, LA-ICP-MS
Effect of chemical abrasion of zircon on SIMS U–Pb, δ18O, trace element, and LA-ICPMS trace element and Lu–Hf isotopic analyses
On the viability of detrital biotite Rb–Sr geochronology
Late Neogene terrestrial climate reconstruction of the central Namib Desert derived by the combination of U–Pb silcrete and terrestrial cosmogenic nuclide exposure dating
Examination of the accuracy of SHRIMP U–Pb geochronology based on samples dated by both SHRIMP and CA-TIMS
In situ U–Pb dating of 4 billion-year-old carbonates in the martian meteorite Allan Hills 84001
Constraining the geothermal parameters of in situ Rb–Sr dating on Proterozoic shales and their subsequent applications
Short communication: On the potential use of materials with heterogeneously distributed parent and daughter isotopes as primary standards for non-U–Pb geochronological applications of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS)
In situ Lu–Hf geochronology of calcite
Calcite U–Pb dating of altered ancient oceanic crust in the North Pamir, Central Asia
Towards in situ U–Pb dating of dolomite
Uranium incorporation in fluorite and exploration of U–Pb dating
U − Pb geochronology of epidote by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a tool for dating hydrothermal-vein formation
Tools for uranium characterization in carbonate samples: case studies of natural U–Pb geochronology reference materials
Direct U–Pb dating of carbonates from micron-scale femtosecond laser ablation inductively coupled plasma mass spectrometry images using robust regression
Technical note: LA–ICP-MS U–Pb dating of unetched and etched apatites
The use of ASH-15 flowstone as a matrix-matched reference material for laser-ablation U − Pb geochronology of calcite
Expanding the limits of laser-ablation U–Pb calcite geochronology
Resolving multiple geological events using in situ Rb–Sr geochronology: implications for metallogenesis at Tropicana, Western Australia
LA-ICPMS U–Pb geochronology of detrital zircon grains from the Coconino, Moenkopi, and Chinle formations in the Petrified Forest National Park (Arizona)
Evaluating the reliability of U–Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) carbonate geochronology: matrix issues and a potential calcite validation reference material
Cate Kooymans, Charles W. Magee Jr., Kathryn Waltenberg, Noreen J. Evans, Simon Bodorkos, Yuri Amelin, Sandra L. Kamo, and Trevor Ireland
Geochronology, 6, 337–363, https://doi.org/10.5194/gchron-6-337-2024, https://doi.org/10.5194/gchron-6-337-2024, 2024
Short summary
Short summary
Zircon is a mineral where uranium decays to lead. Some radiation damage lets lead escape. A method called chemical abrasion (CA) dissolves out the damaged portions of zircon so that remaining zircon retains lead. We compare ion beam analyses of untreated and chemically abraded zircons. The ion beam ages for untreated zircons match the reference values for untreated zircon. The ion beam ages for CA zircon match CA reference ages. Other elements are unaffected by the chemical abrasion process.
Kyle P. Larson, Brendan Dyck, Sudip Shrestha, Mark Button, and Yani Najman
Geochronology, 6, 303–312, https://doi.org/10.5194/gchron-6-303-2024, https://doi.org/10.5194/gchron-6-303-2024, 2024
Short summary
Short summary
This study demonstrates the utility of laser-ablation-based detrital biotite Rb–Sr geochronology to investigate the rates of exhumation and burial in active mountain-building systems. It is further demonstrated that additional chemical data collected during spot analyses can be used to determine temperatures recorded in biotite. The method used has advantages over traditional methods in speed, ease of acquisition, and the ability to collect additional chemical information.
Benedikt Ritter, Richard Albert, Aleksandr Rakipov, Frederik M. Van der Wateren, Tibor J. Dunai, and Axel Gerdes
Geochronology, 5, 433–450, https://doi.org/10.5194/gchron-5-433-2023, https://doi.org/10.5194/gchron-5-433-2023, 2023
Short summary
Short summary
Chronological information on the evolution of the Namib Desert is scarce. We used U–Pb dating of silcretes formed by pressure solution during calcrete formation to track paleoclimate variability since the Late Miocene. Calcrete formation took place during the Pliocene with an abrupt cessation at 2.9 Ma. The end took place due to deep canyon incision which we dated using TCN exposure dating. With our data we correct and contribute to the Neogene history of the Namib Desert and its evolution.
Charles W. Magee Jr., Simon Bodorkos, Christopher J. Lewis, James L. Crowley, Corey J. Wall, and Richard M. Friedman
Geochronology, 5, 1–19, https://doi.org/10.5194/gchron-5-1-2023, https://doi.org/10.5194/gchron-5-1-2023, 2023
Short summary
Short summary
SHRIMP (Sensitive High Resolution Ion MicroProbe) is an instrument that for decades has used the radioactive decay of uranium into lead to measure geologic time. The accuracy and precision of this instrument has not been seriously reviewed in almost 20 years. This paper compares several dozen SHRIMP ages in our database with more accurate and precise methods to assess SHRIMP accuracy and precision. Analytical and geological complications are addressed to try to improve the method.
Romain Tartèse and Ian C. Lyon
Geochronology, 4, 683–690, https://doi.org/10.5194/gchron-4-683-2022, https://doi.org/10.5194/gchron-4-683-2022, 2022
Short summary
Short summary
Absolute chronological constraints are crucial in Earth and planetary sciences. In recent years, U–Pb dating of carbonates has provided information on the timing of, for example, diagenesis, faulting, or hydrothermalism. These studies have targeted relatively young terrestrial carbonates up to 300 million years old. By dating 3.9 billion-year-old martian carbonates in situ using the U–Pb chronometer, we show that this system is robust in ancient samples that have had a relatively simple history.
Darwinaji Subarkah, Angus L. Nixon, Monica Jimenez, Alan S. Collins, Morgan L. Blades, Juraj Farkaš, Sarah E. Gilbert, Simon Holford, and Amber Jarrett
Geochronology, 4, 577–600, https://doi.org/10.5194/gchron-4-577-2022, https://doi.org/10.5194/gchron-4-577-2022, 2022
Short summary
Short summary
Advancements in technology have introduced new techniques to more quickly and cheaply date rocks with little sample preparation. A unique use of this method is to date shales and constrain when these rocks were first deposited. This approach can also time when such sequences were subsequently affected by heat or fluids after they were deposited. This is useful, as the formation of precious-metal-bearing systems or petroleum source rocks is commonly associated with such processes.
Daniil V. Popov
Geochronology, 4, 399–407, https://doi.org/10.5194/gchron-4-399-2022, https://doi.org/10.5194/gchron-4-399-2022, 2022
Short summary
Short summary
This work provides equations allowing the use of minerals with variable concentrations of parent and daughter isotopes as primary standards to correct for elemental fractionation during the analysis by laser ablation inductively coupled plasma mass spectrometry.
Alexander Simpson, Stijn Glorie, Martin Hand, Carl Spandler, Sarah Gilbert, and Brad Cave
Geochronology, 4, 353–372, https://doi.org/10.5194/gchron-4-353-2022, https://doi.org/10.5194/gchron-4-353-2022, 2022
Short summary
Short summary
The article demonstrates a new technique that can be used to determine the age of calcite crystallisation using the decay of 176Lu to 176Hf. The technique is novel because (a) Lu–Hf radiometric dating is rarely applied to calcite and (b) this is the first instance where analysis has been conducted by ablating the sample with a laser beam rather than bulk dissolution. By using laser ablation the original context of the sample is preserved.
Johannes Rembe, Renjie Zhou, Edward R. Sobel, Jonas Kley, Jie Chen, Jian-Xin Zhao, Yuexing Feng, and Daryl L. Howard
Geochronology, 4, 227–250, https://doi.org/10.5194/gchron-4-227-2022, https://doi.org/10.5194/gchron-4-227-2022, 2022
Short summary
Short summary
Calcite is frequently formed during alteration processes in the basaltic, uppermost layer of juvenile oceanic crust. Weathered oceanic basalts are hard to date with conventional radiometric methods. We show in a case study from the North Pamir, Central Asia, that calcite U–Pb age data, supported by geochemistry and petrological microscopy, have potential to date sufficiently old oceanic basalts, if the time span between basalt extrusion and latest calcite precipitation (~ 25 Myr) is considered.
Bar Elisha, Perach Nuriel, Andrew Kylander-Clark, and Ram Weinberger
Geochronology, 3, 337–349, https://doi.org/10.5194/gchron-3-337-2021, https://doi.org/10.5194/gchron-3-337-2021, 2021
Short summary
Short summary
Distinguishing between different dolomitization processes is challenging yet critical for resolving some of the issues and ambiguities related to the formation of dolomitic rocks. Accurate U–Pb absolute dating of dolomite by LA-ICP-MS could contribute to a better understanding of the dolomitization process by placing syngenetic, early diagenetic, and/or epigenetic events in the proper geological context.
Louise Lenoir, Thomas Blaise, Andréa Somogyi, Benjamin Brigaud, Jocelyn Barbarand, Claire Boukari, Julius Nouet, Aurore Brézard-Oudot, and Maurice Pagel
Geochronology, 3, 199–227, https://doi.org/10.5194/gchron-3-199-2021, https://doi.org/10.5194/gchron-3-199-2021, 2021
Short summary
Short summary
To explore the U–Pb geochronometer in fluorite, the spatial distribution of uranium and other substituted elements in natural crystals is investigated using induced fission-track and synchrotron radiation X-ray fluorescence mapping. LA-ICP-MS U–Pb dating on four crystals, which preserve micrometer-scale variations in U concentrations, yields identical ages within analytical uncertainty. Our results show that fluorite U–Pb geochronology has potential for dating distinct crystal growth stages.
Veronica Peverelli, Tanya Ewing, Daniela Rubatto, Martin Wille, Alfons Berger, Igor Maria Villa, Pierre Lanari, Thomas Pettke, and Marco Herwegh
Geochronology, 3, 123–147, https://doi.org/10.5194/gchron-3-123-2021, https://doi.org/10.5194/gchron-3-123-2021, 2021
Short summary
Short summary
This work presents LA-ICP-MS U–Pb geochronology of epidote in hydrothermal veins. The challenges of epidote dating are addressed, and a protocol is proposed allowing us to obtain epidote U–Pb ages with a precision as good as 5 % in addition to the initial Pb isotopic composition of the epidote-forming fluid. Epidote demonstrates its potential to be used as a U–Pb geochronometer and as a fluid tracer, allowing us to reconstruct the timing of hydrothermal activity and the origin of the fluid(s).
E. Troy Rasbury, Theodore M. Present, Paul Northrup, Ryan V. Tappero, Antonio Lanzirotti, Jennifer M. Cole, Kathleen M. Wooton, and Kevin Hatton
Geochronology, 3, 103–122, https://doi.org/10.5194/gchron-3-103-2021, https://doi.org/10.5194/gchron-3-103-2021, 2021
Short summary
Short summary
We characterize three natural carbonate samples with elevated uranium/lead (U/Pb) ratios to demonstrate techniques improving the understanding of U incorporation in carbonates for U/Pb dating. With the rapidly accelerating application of laser ablation analyses, there is a great need for well-characterized reference materials that can serve multiple functions. Strontium (Sr) isotope analyses and U XANES demonstrate that these samples could be used as reference materials.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Christian Paroissin, Pierre-Alexandre Grignard, Geoffrey Motte, Olivier Chailan, and Jean-Pierre Girard
Geochronology, 3, 67–87, https://doi.org/10.5194/gchron-3-67-2021, https://doi.org/10.5194/gchron-3-67-2021, 2021
Short summary
Short summary
A new methodology for the micron-scale uranium–lead dating of carbonate minerals is proposed. It is based on the extraction of ages directly from pixel images (< 1 mm2) obtained by laser ablation coupled to a mass spectrometer. The ages are calculated with a robust linear regression through the pixel values. This methodology is compared to existing approaches.
Fanis Abdullin, Luigi A. Solari, Jesús Solé, and Carlos Ortega-Obregón
Geochronology, 3, 59–65, https://doi.org/10.5194/gchron-3-59-2021, https://doi.org/10.5194/gchron-3-59-2021, 2021
Short summary
Short summary
Unetched and etched apatite grains from five samples were dated by U–Pb method using laser ablation inductively coupled plasma mass spectrometry. Our experiment indicates that etching needed for apatite fission track dating has insignificant effects on obtaining accurate U–Pb ages; thus, the laser ablation-based technique may be used for apatite fission track and U–Pb double dating.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
Short summary
Short summary
This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Andrew R. C. Kylander-Clark
Geochronology, 2, 343–354, https://doi.org/10.5194/gchron-2-343-2020, https://doi.org/10.5194/gchron-2-343-2020, 2020
Short summary
Short summary
This paper serves as a guide to those interested in dating calcite by laser ablation. Within it are theoretical and practical limits of U and Pb concentrations (and U / Pb ratios), which would allow viable extraction of ages from calcite (and other minerals with moderate U / Pb ratios), and which type of instrumentation would be appropriate for any given sample. The method described uses a new detector array, allowing for lower detection limits and thereby expanding the range of viable samples.
Hugo K. H. Olierook, Kai Rankenburg, Stanislav Ulrich, Christopher L. Kirkland, Noreen J. Evans, Stephen Brown, Brent I. A. McInnes, Alexander Prent, Jack Gillespie, Bradley McDonald, and Miles Darragh
Geochronology, 2, 283–303, https://doi.org/10.5194/gchron-2-283-2020, https://doi.org/10.5194/gchron-2-283-2020, 2020
Short summary
Short summary
Using a relatively new dating technique, in situ Rb–Sr geochronology, we constrain the ages of two generations of mineral assemblages from the Tropicana Zone, Western Australia. The first, dated at ca. 2535 Ma, is associated with exhumation of an Archean craton margin and gold mineralization. The second, dated at ca. 1210 Ma, has not been previously documented in the Tropicana Zone. It is probably associated with Stage II of the Albany–Fraser Orogeny and additional gold mineralization.
George Gehrels, Dominique Giesler, Paul Olsen, Dennis Kent, Adam Marsh, William Parker, Cornelia Rasmussen, Roland Mundil, Randall Irmis, John Geissman, and Christopher Lepre
Geochronology, 2, 257–282, https://doi.org/10.5194/gchron-2-257-2020, https://doi.org/10.5194/gchron-2-257-2020, 2020
Short summary
Short summary
U–Pb ages of zircon crystals are used to determine the provenance and depositional age of strata of the Triassic Chinle and Moenkopi formations and the Permian Coconino Sandstone of northern Arizona. Primary source regions include the Ouachita orogen, local Precambrian basement rocks, and Permian–Triassic magmatic arcs to the south and west. Ages from fine-grained strata provide reliable depositional ages, whereas ages from sandstones are compromised by zircon grains recycled from older strata.
Marcel Guillong, Jörn-Frederik Wotzlaw, Nathan Looser, and Oscar Laurent
Geochronology, 2, 155–167, https://doi.org/10.5194/gchron-2-155-2020, https://doi.org/10.5194/gchron-2-155-2020, 2020
Short summary
Short summary
The dating of carbonates by laser ablation inductively coupled plasma mass spectrometry is improved by an additional, newly characterised reference material and adapted data evaluation protocols: the shape (diameter to depth) of the ablation crater has to be as similar as possible in the reference material used and the unknown samples to avoid an offset. Different carbonates have different ablation rates per laser pulse. With robust uncertainty propagation, precision can be as good as 2–3 %.
Cited articles
Albut, G., Kamber, B. S., Brüske, A., Beukes, N. J., Smith, A. J., and
Schoenberg, R.: Modern weathering in outcrop samples versus ancient
paleoredox information in drill core samples from a Mesoarchaean marine
oxygen oasis in Pongola Supergroup, South Africa, Geochim. Cosmochim. Ac., 265, 330-353, 2019.
Babinski, M., Van Schmus, W. R., and Chemale Jr., F.: Pb–Pb dating and Pb
isotope geochemistry of Neoproterozoic carbonate rocks from the São
Francisco basin, Brazil: implications for the mobility of Pb isotopes during
tectonism and metamorphism, Chem. Geol., 160, 175–199, 1999.
Babinski, M., Vieira, L. C., and Trindade, R. I.: Direct dating of the Sete
Lagoas cap carbonate (Bambuí Group, Brazil) and implications for the
Neoproterozoic glacial events, Terra Nova, 19, 401–406, 2007.
Baker, A., Smart, P. L., Barnes, W. L., Edwards, R. L., and Farrant, A.: The
Hekla 3 volcanic eruption recorded in a Scottish speleothem, Holocene, 5, 336–342,
1995.
Baker, A., Smith, C. L., Jex, C., Fairchild, I. J., Genty, D., and Fuller, L.:
Annually laminated speleothems: a review, Int. J. Speleol., 37, 193–206, 2008.
Barnaby, R. J. and Rimstidt, J. D.: Redox conditions of calcite cementation
interpreted from Mn and Fe contents of authigenic calcites, GSA Bulletin, 101, 795–804,
1989.
Beaudoin, N., Lacombe, O., Roberts, N. M., and Koehn, D.: U-Pb dating of
calcite veins reveals complex stress evolution and thrust sequence in the
Bighorn Basin, Wyoming, USA, Geology, 46, 1015–1018, 2018.
Bertok, C., Barale, L., d'Atri, A., Martire, L., Piana, F., Rossetti, P., and
Gerdes, A.: Unusual marbles in a non-metamorphic succession of the SW
Alps (Valdieri, Italy) due to early Oligocene hydrothermal
flow, Int. J. Earth Sci., 108, 693–712, 2019.
Bons, P. D., Elburg, M. A., and Gomez-Rivas, E.: A review of the formation of
tectonic veins and their microstructures, J. Struct. Geol., 43, 33–62, 2012.
Brannon, J. C., Cole, S. C., Podosek, F. A., Ragan, V. M., Coveney, R. M.,
Wallace, M. W., and Bradley, A. J.: Th-Pb and U-Pb dating of ore-stage calcite
and Paleozoic fluid flow, Science, 271, 491–493, 1996.
Buckman, J. O., Corbett, P. W., and Mitchell, L.: Charge contrast imaging
(CCI): revealing enhanced diagenetic features of a coquina
limestone, J. Sediment. Res., 86, 734–748, 2016.
Burisch, M., Gerdes, A., Walter, B. F., Neumann, U., Fettel, M., and Markl,
G.: Methane and the origin of five-element veins: mineralogy, age, fluid
inclusion chemistry and ore forming processes in the Odenwald, SW
Germany, Ore Geol. Rev., 81, 42–61, 2017.
Burisch, M., Walter, B. F., Gerdes, A., Lanz, M., and Markl, G.: Late-stage
anhydrite-gypsum-siderite-dolomite-calcite assemblages record the transition
from a deep to a shallow hydrothermal system in the Schwarzwald mining
district, SW Germany, Geochim. Cosmochim. Ac., 223, 259–278, 2018.
Burn, M., Lanari, P., Pettke, T., and Engi, M.: Non-matrix-matched
standardisation in LA-ICP-MS analysis: general approach, and application to
allanite Th–U–Pb dating, J. Anal. Atom. Spectrom., 32, 1359–1377, 2017.
Cherniak, D. J.: An experimental study of strontium and lead diffusion in
calcite, and implications for carbonate diagenesis and
metamorphism, Geochim. Cosmochim. Ac., 61, 4173–4179, 1997.
Cole, J. M., Nienstedt, J., Spataro, G., Rasbury, E. T., Lanzirotti, A.,
Celestian, A. J., Nilsson, M., and Hanson, G. N.: Phosphor imaging as a tool
for in situ mapping of ppm levels of uranium and thorium in rocks and
minerals, Chem. Geol., 193, 127–136, 2003.
Cole, J. M., Rasbury, E. T., Hanson, G. N., Montañez, I. P., and Pedone,
V. A.: Using U-Pb ages of Miocene tufa for correlation in a terrestrial
succession, Barstow Formation, California, Geol. Soc. Am. Bull., 117, 276–287, 2005.
Coogan, L. A., Parrish, R. R., and Roberts, N. M.: Early hydrothermal carbon
uptake by the upper oceanic crust: Insight from in situ U-Pb
dating, Geology, 44, 147–150, 2016.
Cuthbert, S. J. and Buckman, J. O.: Charge contrast imaging of fine-scale
microstructure and compositional variation in garnet using the environmental
scanning electron microscope, Am. Mineral., 90, 701–707, 2005.
De Paola, N., Holdsworth, R. E., McCaffrey, K. J., and Barchi, M. R.:
Partitioned transtension: an alternative to basin inversion models, J. Struct. Geol., 27,
607–625, 2005.
DeWolf, C. P. and Halliday, A. N.: U-Pb dating of a remagnetized Paleozoic
limestone, Geophys. Res. Lett., 18, 1445–1448, 1991.
Drake, H., Tullborg, E. L., Hogmalm, K. J., and Åström, M. E.: Trace
metal distribution and isotope variations in low-temperature calcite and
groundwater in granitoid fractures down to 1 km depth, Geochim. Cosmochim. Ac., 84, 217–238, 2012.
Drake, H., Heim, C., Hogmalm, K. J., and Hansen, B. T.: Fracture zone-scale
variation of trace elements and stable isotopes in calcite in a crystalline
rock setting, Appl. Geochem., 40, 11–24, 2014.
Drake, H., Heim, C., Roberts, N. M. W., Zack, T., Tillberg, M., Broman, C.,
Ivarsson, M., Whitehouse, M. J., and Åström, M. E.: Isotopic evidence
for microbial production and consumption of methane in the upper continental
crust throughout the Phanerozoic eon, Earth Planet. Sc.
Lett., 470, 108–118, 2017.
Drake, H., Mathurin, F. A., Zack, T., Schäfer, T.,
Roberts, N. M. W., Whitehouse, M., Karlsson, A., Broman, C., and
Åström, M. E.: Incorporation of metals into calcite in
a deep anoxic granite aquifer, Environ. Sci. Technol., 52, 493–502, 2018.
Drake, H., Roberts, N. M. W., Heim, C., Whitehouse, M. J., Siljeström, S.,
Kooijman, E., Broman, C., Ivarsson, M., and Åström, M. E.:
Timing and origin of natural gas accumulation in the Siljan impact
structure, Sweden, Nat. Commun., 10, 1–14, 2019.
Drake, H., Roberts, N. M., and Whitehouse, M. J.: Geochronology and Stable Isotope Analysis of Fracture-fill and Karst Mineralization Reveal Sub-Surface Paleo-Fluid Flow and Microbial Activity of the COSC-1 Borehole, Scandinavian Caledonides, Geosciences, 10, 56, https://doi.org/10.3390/geosciences10020056, 2020.
Drost, K., Chew, D., Petrus, J. A., Scholze, F., Woodhead, J. D., Schneider,
J. W., and Harper, D. A.: An Image Mapping Approach to U-Pb LA-ICP-MS Carbonate
Dating, and Applications to Direct Dating of Carbonate
Sedimentation, Geochem. Geophy. Geosy., 19, 4631–4648,
https://doi.org/10.1029/2018GC007850, 2018.
Eichhubl, P., Davatz, N. C., and Becker, S. P.: Structural and diagenetic
control of fluid migration and cementation along the Moab fault
, Utah, AAPG Bulletin, 93,
653–681, 2009.
Eiler, J. M.: “Clumped-isotope” geochemistry – The study of
naturally-occurring, multiply-substituted isotopologues, Earth Planet. Sc. Lett., 262, 309–327, 2007.
Engel, J., Woodhead, J., Hellstrom, J., Maas, R., Drysdale, R., and Ford, D.:
Corrections for initial isotopic disequilibrium in the speleothem U-Pb
dating method, Quat. Geochronol., 54, 101009, https://doi.org/10.1016/j.quageo.2019.101009, 2019.
Engi, M., Lanari, P., and Kohn, M. J.: Significant ages – An introduction to
petrochronology, Rev. Mineral. Geochem., 83, 1–12, 2017.
Fairey, B., Tsikos, H., Corfu, F., and Polteau, S.: U–Pb systematics in
carbonates of the Postmasburg Group, Transvaal Supergroup, South Africa:
primary versus metasomatic controls, Precambrian Res., 231, 194–205, 2013.
Field, L. P., Milodowski, A. E., Evans, D., Palumbo-Roe, B., Hall, M. R.,
Marriott, A. L., Barlow, T., and Devez, A.: Determining constraints imposed by
salt fabrics on the morphology of solution-mined energy storage cavities,
through dissolution experiments using brine and seawater in
halite, Q. J. Eng. Geol. Hydroge., 52, 240–254, 2019.
Flude, S., Lee, M. R., Sherlock, S. C., and Kelley, S. P.: Cryptic microtextures
and geological histories of K-rich alkali feldspars revealed by charge
contrast imaging, Contrib. Mineral. Petr., 163, 983–994, 2012.
Foxford, K. A., Garden, I. R., Guscott, S. C., Burley, S. D., Lewis, J. J. M.,
Walsh, J. J., and Watterson, J.: The field geology of the Moab fault, in:
Geology and Resources of the Paradox Basin, Utah Geological Association, 25,
265–283, 1996.
Godeau, N., Deschamps, P., Guihou, A., Leonide, P., Tendil, A., Gerdes, A.,
Hamelin, B., and Girard, J. P.: U-Pb dating of calcite cement and diagenetic
history in microporous carbonate reservoirs: Case of the Urgonian Limestone,
France, Geology, 46, 247–250, 2018.
Goodfellow, B. W., Viola, G., Bingen, B., Nuriel, P., and Kylander-Clark,
A. R.: Palaeocene faulting in SE Sweden from U–Pb dating of slickenfibre
calcite, Terra Nova, 29, 321–328, 2017.
Grandia, F., Asmerom, Y., Getty, S., Cardellach, E., and Canals, A.: U–Pb
dating of MVT ore-stage calcite: implications for fluid flow in a Mesozoic
extensional basin from Iberian Peninsula, J. Geochem. Explor., 69, 377–380, 2000.
Gutiérrez, F.: Origin of the salt valleys in the Canyonlands section of the Colorado Plateau: Evaporite-dissolution collapse versus tectonic subsidence, Geomorphology, 57, 423–435, 2004.
Hansman, R. J., Albert, R., Gerdes, A., and Ring, U.: Absolute ages of
multiple generations of brittle structures by U-Pb dating of
calcite, Geology, 46, 207–210, 2018.
Hareyama, M., Tsuchiya, N., Takebe, M. and Chida, T.: Two dimensional
measurement of natural radioactivity of granitic rocks by photostimulated
luminescence technique, Geochem. J., 34, 1–9, 2000.
Hellwig, A., Voigt, S., Mulch, A., Frisch, K., Bartenstein, A., Pross, J.,
Gerdes, A., and Voigt, T.: Late Oligocene to early Miocene humidity change
recorded in terrestrial sequences in the Ili Basin (south-eastern
Kazakhstan, Central Asia), Sedimentology, 65, 517–539, 2018.
Hodson, K. R., Crider, J. G., and Huntington, K. W.: Temperature and composition
of carbonate cements record early structural control on cementation in a
nascent deformation band fault zone: Moab Fault, Utah,
USA, Tectonophysics, 690, 240–252, 2016.
Holdsworth, R. E., McCaffrey, K. J. W., Dempsey, E., Roberts, N. M. W., Hardman,
K., Morton, A., Feely, M., Hunt, J., Conway, A., and Robertson, A.: Natural
fracture propping and earthquake-induced oil migration in fractured basement
reservoirs, Geology, 47, 700–704, https://doi.org/10.1130/G46280.1, 2019.
Holdsworth, R. E., Trice, R., Hardman, K., McCaffrey, K. J. W., Morton, A., Frei, D., Dempsey, E., Bird, A., and Rogers, S.: The nature and age of basement host rocks and fissure fills in the Lancaster field fractured reservoir, West of Shetland, J. Geol. Soc., https://doi.org/10.1144/jgs2019-142, in press, 2020.
Hopley, P. J., Reade, H., Parrish, R., De Kock, M., and Adams, J. W.:
Speleothem evidence for C3 dominated vegetation during the Late Miocene
(Messinian) of South Africa, Rev. Palaeobot. Palyno., 264, 75–89, 2019.
Horstwood, M. S. A., Košler, J., Gehrels, G., Jackson, S. E., McLean, N. M.,
Paton, C., Pearson, N. J., Sircombe, K., Sylvester, P., Vermeesch, P., and
Bowring, J. F.: Community-derived standards for LA-ICP-MS U-(Th-) Pb
geochronology–Uncertainty propagation, age interpretation and data
reporting, Geostand. Geoanal. Res., 40, 311–332, 2016.
Incerpi, N., Martire, L., Manatschal, G., Bernasconi, S. M., Gerdes, A.,
Czuppon, G., Palcsu, L., Karner, G. D., Johnson, C. A., and Figueredo, P. H.:
Hydrothermal fluid flow associated to the extensional evolution of the
Adriatic rifted margin: Insights from the pre-to post-rift sedimentary
sequence (SE Switzerland, N Italy), Basin Res., 32, 91–115, 2020.
Jahn, B. M.: Pb–Pb dating of young marbles from Taiwan, Nature, 332, p. 429, 1988.
Jahn, B. M. and Cuvellier, H.: Pb-Pb and U-Pb geochronology of carbonate
rocks: an assessment, Chem. Geol., 115, 125–151, 1994.
Johansson, Å. and Rickard, D.: Isotopic composition of Phanerozoic
ore leads from the Swedish segment of the Fennoscandian Shield, Miner. Deposita, 19,
249–255, 1984.
Jones, C. E., Halliday, A. N., and Lohmann, K. C.: The impact of diagenesis on
high-precision U-Pb dating of ancient carbonates: An example from the Late
Permian of New Mexico, Earth Planet. Sc. Lett., 134, 409–423, 1995.
Kelly, S. D., Newville, M. G., Cheng, L., Kemner, K. M., Sutton, S. R., Fenter,
P., Sturchio, N. C., and Spötl, C.: Uranyl incorporation in natural
calcite, Environ. Sci. Technol., 37, 1284–1287, 2003.
Kreissl, S., Gerdes, A., Walter, B. F., Neumann, U., Wenzel, T., and Markl, G.:
Reconstruction of a >200 Ma multi-stage “five element”
Bi-Co-Ni-Fe-As-S system in the Penninic Alps, Switzerland, Ore Geol.
Revi., 95, 746–788, 2018.
Kronfeld, J., Vogel, J. C., and Talma, A. S.: A new explanation for extreme
234U∕238U disequilibria in a dolomitic aquifer, Earth Planet. Sc. Lett., 123, 81–93, 1994.
Kylander-Clark, A. R., Hacker, B. R., and Cottle, J. M.: Laser-ablation
split-stream ICP petrochronology, Chem. Geol., 345, 99–112, 2013.
Langmuir, D.: Uranium solution-mineral equilibria at low temperatures with
applications to sedimentary ore deposits, Geochim. Cosmochim. Ac., 42, 547–569, 1978.
Lawson, M., Shenton, B. ., Stolper, D. A., Eiler, J. M., Rasbury, E. T.,
Becker, T. P., Phillips-Lander, C. M., Buono, A. S., Becker, S. P., Pottorf, R.,
and Gray, G. G.: Deciphering the diagenetic history of the El Abra Formation
of eastern Mexico using reordered clumped isotope temperatures and U-Pb
dating, GSA Bulletin, 130, 617–629, 2018.
Lee, M. R., Hodson, M. E., and Langworthy, G.: Earthworms produce granules of
intricately zoned calcite, Geology, 36, 943–946, 2008.
Li, Q., Parrish, R. R., Horstwood, M. S. A., and McArthur, J. M.: U–Pb dating of
cements in Mesozoic ammonites, Chem. Geol., 376, 76–83, 2014.
Liivamägi, S., Šrodon, J., Bojanowski, M., Gerdes, A., Stanek, J. J., Williams,
L., and Szczerba, M.: Paleosols on the Ediacaran basalts of the East European
Craton: a unique record of paleoweathering with minimum diagenetic
overprint, Precambrian Res., 316, 66–82, 2018.
MacDonald, J. M., Faithfull, J. W., Roberts, N. M. W., Davies, A. J., Holdsworth,
C. M., Newton, M., Williamson, S., Boyce, A., and John, C. M.: Clumped-isotope
palaeothermometry and LA-ICP-MS U–Pb dating of lava-pile hydrothermal
calcite veins, Contrib. Mineral. Petr., 174, 63, https://doi.org/10.1007/s00410-019-1599-x, 2019.
Machel, H. G.: Cathodoluminescence in calcite and dolomite and its chemical
interpretation, Geosci. Can., 12, 139–147, 1985.
Machel, H. G.: Application of cathodoluminescence to carbonate diagenesis,
in: Cathodoluminescence in geosciences, edited by: Pagel, M., Barbin, V., Blanc, P., and Ohnenstetter, D., Springer,
Berlin, Heidelberg, Germany, 271–301, 2000.
Mangenot, X., Gasparrini, M., Gerdes, A., Bonifacie, M., and Rouchon, V.: An
emerging thermochronometer for carbonate-bearing rocks: Δ47/(U-Pb), Geology, 46, 1067–1070, 2018.
Maskenskaya, O. M., Drake, H., Broman, C., Hogmalm, J. K., Czuppon, G., and
Åström, M. E.: Source and character of syntaxial hydrothermal calcite
veins in Paleoproterozoic crystalline rocks revealed by fine-scale
investigations, Geofluids, 14, 495–511, 2014.
Mazurek, M., Davis, D. W., Madritsch, H., Rufer, D., Villa, I. M., Sutcliffe,
C. N., De Haller, A., and Traber, D.: Veins in clay-rich aquitards as records
of deformation and fluid-flow events in northern Switzerland, Appl.
Geochem., 95, 57–70, 2018.
Methner, K., Mulch, A., Fiebig, J., Wacker, U., Gerdes, A., Graham, S. A., and
Chamberlain, C. P.: Rapid middle Eocene temperature change in western North
America, Earth Planet. Sc. Lett., 450, 132–139, 2016.
Milodowski, A. E., Bath, A., and Norris, S.: Palaeohydrogeology using
geochemical, isotopic and mineralogical analyses: Salinity and redox
evolution in a deep groundwater system through Quaternary glacial
cycles, Appl. Geochem., 97, 40–60, 2018.
Milton, G. M. and Brown, R. M.: Adsorption of uranium from groundwater by
common fracture secondary minerals, Can. J. Earth Sci., 24, 1321–1328, 1987.
Moorbath, S., Taylor, P. N., Orpen, J. L., Treloar, P., and Wilson, J. F.: First
direct radiometric dating of Archaean stromatolitic
limestone, Nature, 326, 865–867, 1987.
Neymark, L. A., Holm-Denoma, C. S., and Moscati, R. J.: In situ LA-ICPMS U–Pb
dating of cassiterite without a known-age matrix-matched reference material:
Examples from worldwide tin deposits spanning the Proterozoic to the
Tertiary, Chem. Geol., 483, 410–425, 2018.
Nicholson, S. L., Pike, A. W., Hosfield, R., Roberts, N. M. W., Sahy, D.,
Woodhead, J., Cheng, H., Edwards, R. L., Affolter, S., Leuenberger, M., and
Burns, S. J.: Pluvial periods in Southern Arabia over the last 1.1
million-years, Quaternary Sci. Rev., 229, 106112, https://doi.org/10.1016/j.quascirev.2019.106112, 2020.
Nuriel, P., Weinberger, R., Kylander-Clark, A. R. C., Hacker, B. R., and
Craddock, J. P.: The onset of the Dead Sea transform based on calcite
age-strain analyses, Geology, 45, 587–590, 2017.
Nuriel, P., Craddock, J., Kylander-Clark, A. R., Uysal, T., Karabacak, V.,
Dirik, R. K., Hacker, B. R., and Weinberger, R.: Reactivation history of the
North Anatolian fault zone based on calcite age-strain analyses, Geology,
47, 465–469, 2019.
Osmond, J. K. and Cowart, J. B.: The theory and uses of natural uranium
isotopic variations in hydrology, Atom. Energy Rev., 14, 621–679, 1976.
Osmond, J. K. and Cowart, J. B.: Ground water, in: Uranium-series
Disequilibrium: Applications to Earth, Marine, and Environmental Sciences,
Second Edition, edited by: Ivanovich, M. and Harmon, R. S., Clarendon Press,
Oxford, UK, 290–330, 1992.
Osmond, J. K. and Cowart, J. B.: U-series nuclides as tracers in groundwater
hydrology, in: Environmental tracers in subsurface hydrology, edited by: Cook, P. G. and Herczeg, A. L., Springer, Boston, MA, USA,
145–173, 2000.
Osmond, J. K., Rydell, H. S., and Kaufman, M. I.: Uranium disequilibrium in
groundwater: an isotope dilution approach in hydrologic
investigations, Science, 162, 997–999, 1968.
Palin, R. M., Searle, M. P., Waters, D. J., Parrish, R. R., Roberts, N. M. W.,
Horstwood, M. S. A., Yeh, M. W., Chung, S. L., and Anh, T. T.: A geochronological
and petrological study of anatectic paragneiss and associated granite dykes
from the Day Nui C on Voi metamorphic core complex, North Vietnam:
constraints on the timing of metamorphism within the Red River shear
zone, J. Metamorph. Geol., 31, 359–387, 2013.
Pagel, M., Bonifacie, M., Schneider, D. A., Gautheron, C., Brigaud, B.,
Calmels, D., Cros, A., Saint-Bezar, B., Landrein, P., Sutcliffe, C., and
Davis, D.: Improving paleohydrological and diagenetic reconstructions in
calcite veins and breccia of a sedimentary basin by combining Δ47
temperature, δ18Owater and U-Pb age, Chem.
Geol., 481, 1–17, 2018.
Paquette, J. and Reeder, R. J.: Relationship between surface structure,
growth mechanism, and trace element incorporation in calcite, Geochim. Cosmochim. Ac., 59, 735–749,
1995.
Parrish, R. R., Parrish, C. M., and Lasalle, S.: Vein calcite dating reveals
Pyrenean orogen as cause of Paleogene deformation in southern
England, J. Geol. Soc., 175, 425–442, 2018.
Paton, C., Woodhead, J. D., Hellstrom, J. C., Hergt, J. M., Greig, A., and Maas,
R.: Improved laser ablation U-Pb zircon geochronology through robust
downhole fractionation correction, Geochem. Geophy. Geosy., 11, Q0AA06, https://doi.org/10.1029/2009GC002618,
2010.
Paton, C., Hellstrom, J., Paul, B., Woodhead, J., and Hergt, J.: Iolite:
Freeware for the visualisation and processing of mass spectrometric
data, J. Anal. Atom. Spectrom., 26, 2508–2518, 2011.
Perrette, Y., Delannoy, J. J., Desmet, M., Lignier, V., and Destombes, J. L.:
Speleothem organic matter content imaging. The use of a Fluorescence Index
to characterise the maximum emission wavelength, Chem. Geol., 214, 193–208, 2005.
Petrus, J. A., Chew, D. M., Leybourne, M. I., and Kamber, B. S.: A new approach
to laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICP-MS)
using the flexible map interrogation tool “Monocle”, Chem. Geol., 463, 76–93, 2017.
Pevear, D. R., Vrolijk, P. J., Longstaffe, F. J., Hendry, J., Carey, P.,
Parnell, J., Ruffell, A., and Worden, R.: Timing of Moab fault displacement
and fluid movement integrated with burial history using radiogenic and
stable isotopes, Geofluids II, 97, 42–45, 1997.
Pickering, R., Kramers, J. D., Partridge, T., Kodolanyi, J., and Pettke, T.:
U–Pb dating of calcite–aragonite layers in speleothems from hominin sites
in South Africa by MC-ICP-MS, Quat. Geochronol., 5, 544–558, 2010.
Porcelli, D. and Swarzenski, P. W.: The behavior of U-and Th-series nuclides
in groundwater, Rev. Mineral. Geochem., 52, 317–361, 2003.
Quade, J., Rasbury, E. T., Huntington, K. W., Hudson, A. M., Vonhof, H.,
Anchukaitis, K., Betancourt, J., Latorre, C., and Pepper, M.: Isotopic
characterization of late Neogene travertine deposits at Barrancas Blancas in
the eastern Atacama Desert, Chile, Chem. Geol., 466, 41–56, 2017.
Rasbury, E. T. and Cole, J. M.: Directly dating geologic events: U-Pb dating
of carbonates, Rev. Geophys., 47, RG3001, https://doi.org/10.1029/2007RG000246, 2009.
Rasbury, E. T., Hanson, G. N., Meyers, W. J., and Saller, A. H.: Dating of the
time of sedimentation using U-Pb ages for paleosol calcite, Geochim. Cosmochim. Ac., 61, 1525–1529,
1997.
Ray, J. S., Veizer, J., and Davis, W. J.: C, O, Sr and Pb isotope systematics
of carbonate sequences of the Vindhyan Supergroup, India: age, diagenesis,
correlations and implications for global events, Precambrian Res., 121, 103–140, 2003.
Reeder, R. J.: Interaction of divalent cobalt, zinc, cadmium, and barium with
the calcite surface during layer growth, Geochim. Cosmochim. Ac., 60, 1543–1552, 1996.
Reeder, R. J., Nugent, M., Lamble, G. M., Tait, C. D., and Morris, D. E.: Uranyl
incorporation into calcite and aragonite: XAFS and luminescence
studies, Environ. Sci. Technol., 34, 638–644, 2000.
Reeder, R. J., Nugent, M., Tait, C. D., Morris, D. E., Heald, S. M., Beck, K. M.,
Hess, W. P., and Lanzirotti, A.: Coprecipitation of uranium (VI) with calcite:
XAFS, micro-XAS, and luminescence characterization, Geochim. Cosmochim. Ac., 65, 3491–3503, 2001.
Regis, D., Warren, C. J., Mottram, C. M., and Roberts, N. M. W.: Using monazite
and zircon petrochronology to constrain the P–T–t evolution of the middle
crust in the Bhutan Himalaya, J. Metamorph. Geol., 34, 617–639, 2016.
Richards, D. A., Bottrell, S. H., Cliff, R. A., Ströhle, K., and Rowe, P. J.:
U-Pb dating of a speleothem of Quaternary age, Geochim. Cosmochim. Ac., 62, 3683–3688, 1998.
Richter, D. K., Götte, T., Götze, J., and Neuser, R. D.: Progress in
application of cathodoluminescence (CL) in sedimentary
petrology, Mineral. Petrol., 79, 127–166, 2003.
Ring, U. and Gerdes, A.: Kinematics of the Alpenrhein-Bodensee graben system
in the Central Alps: Oligocene/Miocene transtension due to formation of the
Western Alps arc, Tectonics, 35, 1367–1391, 2016.
Roberts, N. M. W. and Walker, R. J.: U-Pb geochronology of calcite-mineralized
faults: Absolute timing of rift-related fault events on the northeast
Atlantic margin, Geology, 44, 531–534, 2016.
Roberts, N. M. W., Rasbury, E. T., Parrish, R. R., Smith, C. J., Horstwood,
M. S. A., and Condon, D. J.: A calcite reference material for LA-ICP-MS U-Pb
geochronology. Geochem. Geophy., Geosy., 18, 2807–2814, 2017.
Robertson, K., Gauvin, R., and Finch, J.: Application of charge contrast
imaging in mineral characterization, Miner. Eng., 18, 343–352, 2005.
Romer, R. L. and Wright, J. E.: Lead mobilization during tectonic
reactivation of the western Baltic Shield, Geochim. Cosmochim. Ac., 57, 2555–2570, 1993.
Russell, J., Chadwick, B., Rao, B. K., and Vasudev, V. N.: Whole-rock PbPb
isotopic ages of Late Archaean limestones, Karnataka, India, Precambrian Res., 78, 261–272,
1996.
Sarangi, S., Gopalan, K., and Kumar, S.: Pb–Pb age of earliest megascopic,
eukaryotic alga bearing Rohtas Formation, Vindhyan Supergroup, India:
implications for Precambrian atmospheric oxygen evolution, Precambrian Res., 132, 107–121,
2004.
Savard, M. M., Veizer, J., and Hinton, R.: Cathodoluminescene at low Fe and Mn
concentrations; a SIMS study of zones in natural calcites, J. Sediment. Res., 65, 208–213,
1995.
Scardia, G., Parenti, F., Miggins, D. P., Gerdes, A., Araujo, A. G., and Neves,
W. A.: Chronologic constraints on hominin dispersal outside Africa since 2.48
Ma from the Zarqa Valley, Jordan, Quaternary Sci. Rev., 219, 1–19, 2019.
Shopov, Y. Y., Ford, D. C., and Schwarcz, H. P.: Luminescent microbanding in
speleothems: high-resolution chronology and paleoclimate, Geology, 22, 407–410, 1994.
Smeraglia, L., Aldega, L., Billi, A., Carminati, E., Di Fiore, F., Gerdes,
A., Albert, R., Rossetti, F., and Vignaroli, G.: Development of an
intra-wedge tectonic mélange by out-of-sequence thrusting, buttressing,
and intraformational rheological contrast, Mt. Massico ridge, Apennines,
Italy, Tectonics, 38, 1223–1249, 2019.
Smith, P. E. and Farquhar, R. M.: Direct dating of Phanerozoic sediments by
the 238U–206Pb method, Nature, 341, p. 518, 1989.
Smith, P. E., Farquhar, R. M., and Hancock, R. G.: Direct radiometric age
determination of carbonate diagenesis using U-Pb in secondary
calcite, Earth Planet. Sc. Lett., 105, 474–491, 1991.
Solum, J. G., van der Pluijm, B. A., and Peacor, D. R.: Neocrystallization,
fabrics and age of clay minerals from an exposure of the Moab Fault,
Utah, J. Struct. Geol., 27, 1563–1576, 2005.
Stacey, J. T. and Kramers, J.: Approximation of terrestrial lead isotope
evolution by a two-stage model, Earth Planet. Sc. Lett., 26, 207–221, 1975.
Stübner, K., Grujic, D., Parrish, R. R., Roberts, N. M., Kronz, A.,
Wooden, J., and Ahmad, T.: Monazite geochronology unravels the timing of
crustal thickening in NW Himalaya, Lithos, 210, 111–128, 2014.
Sturchio, N. C., Antonio, M. R., Soderholm, L., Sutton, S. R., and Brannon,
J. C.: Tetravalent uranium in calcite, Science, 281, 971–973, 1998.
Suksi, J., Rasilainen, K., and Pitkänen, P.: Variations in 234U∕238U
activity ratios in groundwater – A key to flow system
characterisation, Phys. Chem. Earth, Pt. A/B/C, 31, 556–571, 2006.
Sumner, D. Y. and Bowring, S. A.: U-Pb geochronologic constraints on
deposition of the Campbellrand Subgroup, Transvaal Supergroup, South
Africa, Precambrian Res., 79, 25–35, 1996.
Taylor, P. N. and Kalsbeek, F.: Dating the metamorphism of Precambrian
marbles: Examples from Proterozoic mobile belts in Greenland, Chem. Geol., 86, 21–28,
1990.
Tullborg, E. L., Drake, H., and Sandström, B.: Palaeohydrogeology: a
methodology based on fracture mineral studies, Appl. Geochem., 23, 1881–1897, 2008.
Ukar, E. and Laubach, S. E.: Syn-and postkinematic cement textures in
fractured carbonate rocks: Insights from advanced cathodoluminescence
imaging, Tectonophysics, 690, 190–205, 2016.
Uysal, I. T., Feng, Y. X., Zhao, J. X., Bolhar, R., Işik, V., Baublys,
K. A., Yago, A., and Golding, S. D.: Seismic cycles recorded in late Quaternary
calcite veins: geochronological, geochemical and microstructural
evidence, Earth Planet. Sc. Lett., 303, 84–96, 2011.
Walter, B. F., Gerdes, A., Kleinhanns, I. C., Dunkl, I., von Eynatten, H.,
Kreissl, S., and Markl, G.: The connection between hydrothermal fluids,
mineralization, tectonics and magmatism in a continental rift setting:
Fluorite Sm-Nd and hematite and carbonates U-Pb geochronology from the
Rhinegraben in SW Germany, Geochim. Cosmochim. Ac., 240, 11–42,
2018.
Warren, C. J., Singh, A. K., Roberts, N. M. W., Regis, D., Halton, A. M., and
Singh, R. B.: Timing and conditions of peak metamorphism and cooling across
the Zimithang Thrust, Arunachal Pradesh, India, Lithos, 200, 94–110, 2014.
Watt, G. R., Griffin, B. J., and Kinny, P. D.: Charge contrast imaging of
geological materials in the environmental scanning electron
microscope, Am. Mineral., 85, 1784–1794, 2000.
Wendt, I. and Carl, C.: The statistical distribution of the mean squared
weighted deviation, Chem. Geol., 86, 275–285, 1991.
Weremeichik, J. M., Gabitov, R. I., Thien, B. M., and Sadekov, A.: The effect of
growth rate on uranium partitioning between individual calcite crystals and
fluid, Chem. Geol., 450, 145–153, 2017.
Whitehouse, M. J. and Russell, J.: Isotope systematics of Precambrian marbles
from the Lewisian complex of northwest Scotland: implications for Pb Pb
dating of metamorphosed carbonates, Chem. Geol., 136, 295–307, 1997.
Williams, R. T., Goodwin, L. B., Sharp, W. D., and Mozley, P. S.: Reading a
400,000-year record of earthquake frequency for an intraplate
fault, P. Natl. Acad. Sci. USA, 114, 4893–4898, 2017.
Woodhead, J. and Petrus, J.: Exploring the advantages and limitations of in situ U–Pb carbonate geochronology using speleothems, Geochronology, 1, 69–84, https://doi.org/10.5194/gchron-1-69-2019, 2019.
Woodhead, J., Hellstrom, J., Maas, R., Drysdale, R., Zanchetta, G., Devine,
P., and Taylor, E.: U–Pb geochronology of speleothems by
MC-ICPMS, Quatern. Geochronol., 1, 208–221, 2006.
Woodhead, J., Hellstrom, J., Pickering, R., Drysdale, R., Paul, B., and Bajo,
P.: U and Pb variability in older speleothems and strategies for their
chronology, Quatern. Geochronol., 14, 105–113, 2012.
Woodhead, J. D., Sniderman, J. K., Hellstrom, J., Drysdale, R. N., Maas, R.,
White, N., White, S., and Devine, P.: The antiquity of Nullarbor speleothems
and implications for karst palaeoclimate archives, Sci. Rep., 9, 603, https://doi.org/10.1038/s41598-018-37097-2, 2019.
Yokoyama, T., Kimura, J. I., Mitsuguchi, T., Danhara, T., Hirata, T., Sakata,
S., Iwano, H., Maruyama, S., Chang, Q., Miyazaki, T., and Murakami, H.: U-Pb
dating of calcite using LA-ICP-MS: Instrumental setup for non-matrix-matched
age dating and determination of analytical areas using elemental
imaging, Geochem. J., 52, 531–540, 2018.
Short summary
Here we review current progress in LA-ICP-MS U–Pb carbonate geochronology and present strategies for acquisition and interpretation of carbonate U–Pb dates. We cover topics from imaging techniques and U and Pb incorporation into calcite to potential limitations of the method – disequilibrium and isotope mobility. We demonstrate the incorporation of imaging and compositional data to help refine and interpret U–Pb dates. We expect this paper to become a
go-toreference paper for years to come.
Here we review current progress in LA-ICP-MS U–Pb carbonate geochronology and present strategies...
Special issue