Articles | Volume 3, issue 1
https://doi.org/10.5194/gchron-3-103-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/gchron-3-103-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Feb 2021
Research article |
| 16 Feb 2021
| 16 Feb 2021
Tools for uranium characterization in carbonate samples: case studies of natural U–Pb geochronology reference materials
E. Troy Rasbury
CORRESPONDING AUTHOR
Department of Geosciences, FIRST, Stony Brook University, 100 Nichols
Rd, Stony Brook, NY 11794, USA
Theodore M. Present
Division of Geological and Planetary Sciences, California Institute of
Technology, 307 North Mudd Laboratory, Pasadena, CA 91125, USA
Paul Northrup
Department of Geosciences, FIRST, Stony Brook University, 100 Nichols
Rd, Stony Brook, NY 11794, USA
Ryan V. Tappero
NSLS-II, Brookhaven National Laboratory, Upton NY 11973, USA
Antonio Lanzirotti
Center for Advanced Radiation Sources, Randall, Chicago, IL 60637, USA
Jennifer M. Cole
Department of Science, West Los Angeles College, Culver City, CA
90230, USA
Lamont-Doherty Earth Observatory of Columbia University, 61 Route 9W,
Palisades, NY 10964, USA
Kathleen M. Wooton
Department of Geosciences, FIRST, Stony Brook University, 100 Nichols
Rd, Stony Brook, NY 11794, USA
Kevin Hatton
Department of Geosciences, FIRST, Stony Brook University, 100 Nichols
Rd, Stony Brook, NY 11794, USA
Related authors
Francis J. Sousa, Stephen E. Cox, E. Troy Rasbury, Sidney R. Hemming, Antonio Lanzirotti, and Matthew Newville
Geochronology, 6, 553–570, https://doi.org/10.5194/gchron-6-553-2024, https://doi.org/10.5194/gchron-6-553-2024, 2024
Short summary
Short summary
We have discovered a new way of measuring the three-dimensional distribution of radioactive elements in individual crystals by shining a very bright light on apatite crystals at the Advanced Photon Source at Argonne National Laboratory. This allows us to learn about the rates and timing of geologic processes and to help resolve problems that previously were unsolvable because we had no way to make this type of measurement.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
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Short summary
We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Gavin Piccione, Terrence Blackburn, Paul Northrup, Slawek Tulaczyk, and Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-1359, https://doi.org/10.5194/egusphere-2024-1359, 2024
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Growth of microorganisms in the Southern Ocean is limited by low iron levels. Iron delivered from beneath the Antarctic Ice Sheet is one agent that fertilizes these ecosystems, but it is unclear how this nutrient source changes through time. Here, we measured the age and chemistry of a rock that records the iron concentration of Antarctic basal water. We show that increased dissolution of iron from rocks below the ice sheet can substantially enhance iron discharge during cold climate periods.
Xianghui Li, Jingyu Wang, Troy Rasbury, Min Zhou, Zhen Wei, and Chaokai Zhang
Clim. Past, 16, 2055–2074, https://doi.org/10.5194/cp-16-2055-2020, https://doi.org/10.5194/cp-16-2055-2020, 2020
Short summary
Short summary
This work presents the observation of the Early Jurassic terrestrial climate from the Sichuan paleobasin, southeastern China. Results manifest a (semi)arid climate in the study area, where the climate pattern is similar to the Colorado Plateau. The estimated atmospheric carbon dioxide concentration is 980–2610 ppmV with a mean of 1660 ppmV. The change of carbon dioxide concentration is compatible with the excursions of stable isotopes and seawater temperature from the coeval marine sediments.
Francis J. Sousa, Stephen E. Cox, E. Troy Rasbury, Sidney R. Hemming, Antonio Lanzirotti, and Matthew Newville
Geochronology, 6, 553–570, https://doi.org/10.5194/gchron-6-553-2024, https://doi.org/10.5194/gchron-6-553-2024, 2024
Short summary
Short summary
We have discovered a new way of measuring the three-dimensional distribution of radioactive elements in individual crystals by shining a very bright light on apatite crystals at the Advanced Photon Source at Argonne National Laboratory. This allows us to learn about the rates and timing of geologic processes and to help resolve problems that previously were unsolvable because we had no way to make this type of measurement.
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
Short summary
Short summary
We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
Gavin Piccione, Terrence Blackburn, Paul Northrup, Slawek Tulaczyk, and Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-1359, https://doi.org/10.5194/egusphere-2024-1359, 2024
Short summary
Short summary
Growth of microorganisms in the Southern Ocean is limited by low iron levels. Iron delivered from beneath the Antarctic Ice Sheet is one agent that fertilizes these ecosystems, but it is unclear how this nutrient source changes through time. Here, we measured the age and chemistry of a rock that records the iron concentration of Antarctic basal water. We show that increased dissolution of iron from rocks below the ice sheet can substantially enhance iron discharge during cold climate periods.
Xianghui Li, Jingyu Wang, Troy Rasbury, Min Zhou, Zhen Wei, and Chaokai Zhang
Clim. Past, 16, 2055–2074, https://doi.org/10.5194/cp-16-2055-2020, https://doi.org/10.5194/cp-16-2055-2020, 2020
Short summary
Short summary
This work presents the observation of the Early Jurassic terrestrial climate from the Sichuan paleobasin, southeastern China. Results manifest a (semi)arid climate in the study area, where the climate pattern is similar to the Colorado Plateau. The estimated atmospheric carbon dioxide concentration is 980–2610 ppmV with a mean of 1660 ppmV. The change of carbon dioxide concentration is compatible with the excursions of stable isotopes and seawater temperature from the coeval marine sediments.
Related subject area
SIMS, LA-ICP-MS
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On the viability of detrital biotite Rb–Sr geochronology
Late Neogene terrestrial climate reconstruction of the central Namib Desert derived by the combination of U–Pb silcrete and terrestrial cosmogenic nuclide exposure dating
Examination of the accuracy of SHRIMP U–Pb geochronology based on samples dated by both SHRIMP and CA-TIMS
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Short communication: On the potential use of materials with heterogeneously distributed parent and daughter isotopes as primary standards for non-U–Pb geochronological applications of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS)
In situ Lu–Hf geochronology of calcite
Calcite U–Pb dating of altered ancient oceanic crust in the North Pamir, Central Asia
Towards in situ U–Pb dating of dolomite
Uranium incorporation in fluorite and exploration of U–Pb dating
U − Pb geochronology of epidote by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) as a tool for dating hydrothermal-vein formation
Direct U–Pb dating of carbonates from micron-scale femtosecond laser ablation inductively coupled plasma mass spectrometry images using robust regression
Technical note: LA–ICP-MS U–Pb dating of unetched and etched apatites
The use of ASH-15 flowstone as a matrix-matched reference material for laser-ablation U − Pb geochronology of calcite
Expanding the limits of laser-ablation U–Pb calcite geochronology
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Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb carbonate geochronology: strategies, progress, and limitations
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Geochronology, 6, 337–363, https://doi.org/10.5194/gchron-6-337-2024, https://doi.org/10.5194/gchron-6-337-2024, 2024
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Zircon is a mineral where uranium decays to lead. Some radiation damage lets lead escape. A method called chemical abrasion (CA) dissolves out the damaged portions of zircon so that remaining zircon retains lead. We compare ion beam analyses of untreated and chemically abraded zircons. The ion beam ages for untreated zircons match the reference values for untreated zircon. The ion beam ages for CA zircon match CA reference ages. Other elements are unaffected by the chemical abrasion process.
Kyle P. Larson, Brendan Dyck, Sudip Shrestha, Mark Button, and Yani Najman
Geochronology, 6, 303–312, https://doi.org/10.5194/gchron-6-303-2024, https://doi.org/10.5194/gchron-6-303-2024, 2024
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This study demonstrates the utility of laser-ablation-based detrital biotite Rb–Sr geochronology to investigate the rates of exhumation and burial in active mountain-building systems. It is further demonstrated that additional chemical data collected during spot analyses can be used to determine temperatures recorded in biotite. The method used has advantages over traditional methods in speed, ease of acquisition, and the ability to collect additional chemical information.
Benedikt Ritter, Richard Albert, Aleksandr Rakipov, Frederik M. Van der Wateren, Tibor J. Dunai, and Axel Gerdes
Geochronology, 5, 433–450, https://doi.org/10.5194/gchron-5-433-2023, https://doi.org/10.5194/gchron-5-433-2023, 2023
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Chronological information on the evolution of the Namib Desert is scarce. We used U–Pb dating of silcretes formed by pressure solution during calcrete formation to track paleoclimate variability since the Late Miocene. Calcrete formation took place during the Pliocene with an abrupt cessation at 2.9 Ma. The end took place due to deep canyon incision which we dated using TCN exposure dating. With our data we correct and contribute to the Neogene history of the Namib Desert and its evolution.
Charles W. Magee Jr., Simon Bodorkos, Christopher J. Lewis, James L. Crowley, Corey J. Wall, and Richard M. Friedman
Geochronology, 5, 1–19, https://doi.org/10.5194/gchron-5-1-2023, https://doi.org/10.5194/gchron-5-1-2023, 2023
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SHRIMP (Sensitive High Resolution Ion MicroProbe) is an instrument that for decades has used the radioactive decay of uranium into lead to measure geologic time. The accuracy and precision of this instrument has not been seriously reviewed in almost 20 years. This paper compares several dozen SHRIMP ages in our database with more accurate and precise methods to assess SHRIMP accuracy and precision. Analytical and geological complications are addressed to try to improve the method.
Romain Tartèse and Ian C. Lyon
Geochronology, 4, 683–690, https://doi.org/10.5194/gchron-4-683-2022, https://doi.org/10.5194/gchron-4-683-2022, 2022
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Absolute chronological constraints are crucial in Earth and planetary sciences. In recent years, U–Pb dating of carbonates has provided information on the timing of, for example, diagenesis, faulting, or hydrothermalism. These studies have targeted relatively young terrestrial carbonates up to 300 million years old. By dating 3.9 billion-year-old martian carbonates in situ using the U–Pb chronometer, we show that this system is robust in ancient samples that have had a relatively simple history.
Darwinaji Subarkah, Angus L. Nixon, Monica Jimenez, Alan S. Collins, Morgan L. Blades, Juraj Farkaš, Sarah E. Gilbert, Simon Holford, and Amber Jarrett
Geochronology, 4, 577–600, https://doi.org/10.5194/gchron-4-577-2022, https://doi.org/10.5194/gchron-4-577-2022, 2022
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Advancements in technology have introduced new techniques to more quickly and cheaply date rocks with little sample preparation. A unique use of this method is to date shales and constrain when these rocks were first deposited. This approach can also time when such sequences were subsequently affected by heat or fluids after they were deposited. This is useful, as the formation of precious-metal-bearing systems or petroleum source rocks is commonly associated with such processes.
Daniil V. Popov
Geochronology, 4, 399–407, https://doi.org/10.5194/gchron-4-399-2022, https://doi.org/10.5194/gchron-4-399-2022, 2022
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This work provides equations allowing the use of minerals with variable concentrations of parent and daughter isotopes as primary standards to correct for elemental fractionation during the analysis by laser ablation inductively coupled plasma mass spectrometry.
Alexander Simpson, Stijn Glorie, Martin Hand, Carl Spandler, Sarah Gilbert, and Brad Cave
Geochronology, 4, 353–372, https://doi.org/10.5194/gchron-4-353-2022, https://doi.org/10.5194/gchron-4-353-2022, 2022
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The article demonstrates a new technique that can be used to determine the age of calcite crystallisation using the decay of 176Lu to 176Hf. The technique is novel because (a) Lu–Hf radiometric dating is rarely applied to calcite and (b) this is the first instance where analysis has been conducted by ablating the sample with a laser beam rather than bulk dissolution. By using laser ablation the original context of the sample is preserved.
Johannes Rembe, Renjie Zhou, Edward R. Sobel, Jonas Kley, Jie Chen, Jian-Xin Zhao, Yuexing Feng, and Daryl L. Howard
Geochronology, 4, 227–250, https://doi.org/10.5194/gchron-4-227-2022, https://doi.org/10.5194/gchron-4-227-2022, 2022
Short summary
Short summary
Calcite is frequently formed during alteration processes in the basaltic, uppermost layer of juvenile oceanic crust. Weathered oceanic basalts are hard to date with conventional radiometric methods. We show in a case study from the North Pamir, Central Asia, that calcite U–Pb age data, supported by geochemistry and petrological microscopy, have potential to date sufficiently old oceanic basalts, if the time span between basalt extrusion and latest calcite precipitation (~ 25 Myr) is considered.
Bar Elisha, Perach Nuriel, Andrew Kylander-Clark, and Ram Weinberger
Geochronology, 3, 337–349, https://doi.org/10.5194/gchron-3-337-2021, https://doi.org/10.5194/gchron-3-337-2021, 2021
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Distinguishing between different dolomitization processes is challenging yet critical for resolving some of the issues and ambiguities related to the formation of dolomitic rocks. Accurate U–Pb absolute dating of dolomite by LA-ICP-MS could contribute to a better understanding of the dolomitization process by placing syngenetic, early diagenetic, and/or epigenetic events in the proper geological context.
Louise Lenoir, Thomas Blaise, Andréa Somogyi, Benjamin Brigaud, Jocelyn Barbarand, Claire Boukari, Julius Nouet, Aurore Brézard-Oudot, and Maurice Pagel
Geochronology, 3, 199–227, https://doi.org/10.5194/gchron-3-199-2021, https://doi.org/10.5194/gchron-3-199-2021, 2021
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To explore the U–Pb geochronometer in fluorite, the spatial distribution of uranium and other substituted elements in natural crystals is investigated using induced fission-track and synchrotron radiation X-ray fluorescence mapping. LA-ICP-MS U–Pb dating on four crystals, which preserve micrometer-scale variations in U concentrations, yields identical ages within analytical uncertainty. Our results show that fluorite U–Pb geochronology has potential for dating distinct crystal growth stages.
Veronica Peverelli, Tanya Ewing, Daniela Rubatto, Martin Wille, Alfons Berger, Igor Maria Villa, Pierre Lanari, Thomas Pettke, and Marco Herwegh
Geochronology, 3, 123–147, https://doi.org/10.5194/gchron-3-123-2021, https://doi.org/10.5194/gchron-3-123-2021, 2021
Short summary
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This work presents LA-ICP-MS U–Pb geochronology of epidote in hydrothermal veins. The challenges of epidote dating are addressed, and a protocol is proposed allowing us to obtain epidote U–Pb ages with a precision as good as 5 % in addition to the initial Pb isotopic composition of the epidote-forming fluid. Epidote demonstrates its potential to be used as a U–Pb geochronometer and as a fluid tracer, allowing us to reconstruct the timing of hydrothermal activity and the origin of the fluid(s).
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Christian Paroissin, Pierre-Alexandre Grignard, Geoffrey Motte, Olivier Chailan, and Jean-Pierre Girard
Geochronology, 3, 67–87, https://doi.org/10.5194/gchron-3-67-2021, https://doi.org/10.5194/gchron-3-67-2021, 2021
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A new methodology for the micron-scale uranium–lead dating of carbonate minerals is proposed. It is based on the extraction of ages directly from pixel images (< 1 mm2) obtained by laser ablation coupled to a mass spectrometer. The ages are calculated with a robust linear regression through the pixel values. This methodology is compared to existing approaches.
Fanis Abdullin, Luigi A. Solari, Jesús Solé, and Carlos Ortega-Obregón
Geochronology, 3, 59–65, https://doi.org/10.5194/gchron-3-59-2021, https://doi.org/10.5194/gchron-3-59-2021, 2021
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Unetched and etched apatite grains from five samples were dated by U–Pb method using laser ablation inductively coupled plasma mass spectrometry. Our experiment indicates that etching needed for apatite fission track dating has insignificant effects on obtaining accurate U–Pb ages; thus, the laser ablation-based technique may be used for apatite fission track and U–Pb double dating.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
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This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
Andrew R. C. Kylander-Clark
Geochronology, 2, 343–354, https://doi.org/10.5194/gchron-2-343-2020, https://doi.org/10.5194/gchron-2-343-2020, 2020
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This paper serves as a guide to those interested in dating calcite by laser ablation. Within it are theoretical and practical limits of U and Pb concentrations (and U / Pb ratios), which would allow viable extraction of ages from calcite (and other minerals with moderate U / Pb ratios), and which type of instrumentation would be appropriate for any given sample. The method described uses a new detector array, allowing for lower detection limits and thereby expanding the range of viable samples.
Hugo K. H. Olierook, Kai Rankenburg, Stanislav Ulrich, Christopher L. Kirkland, Noreen J. Evans, Stephen Brown, Brent I. A. McInnes, Alexander Prent, Jack Gillespie, Bradley McDonald, and Miles Darragh
Geochronology, 2, 283–303, https://doi.org/10.5194/gchron-2-283-2020, https://doi.org/10.5194/gchron-2-283-2020, 2020
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Using a relatively new dating technique, in situ Rb–Sr geochronology, we constrain the ages of two generations of mineral assemblages from the Tropicana Zone, Western Australia. The first, dated at ca. 2535 Ma, is associated with exhumation of an Archean craton margin and gold mineralization. The second, dated at ca. 1210 Ma, has not been previously documented in the Tropicana Zone. It is probably associated with Stage II of the Albany–Fraser Orogeny and additional gold mineralization.
George Gehrels, Dominique Giesler, Paul Olsen, Dennis Kent, Adam Marsh, William Parker, Cornelia Rasmussen, Roland Mundil, Randall Irmis, John Geissman, and Christopher Lepre
Geochronology, 2, 257–282, https://doi.org/10.5194/gchron-2-257-2020, https://doi.org/10.5194/gchron-2-257-2020, 2020
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U–Pb ages of zircon crystals are used to determine the provenance and depositional age of strata of the Triassic Chinle and Moenkopi formations and the Permian Coconino Sandstone of northern Arizona. Primary source regions include the Ouachita orogen, local Precambrian basement rocks, and Permian–Triassic magmatic arcs to the south and west. Ages from fine-grained strata provide reliable depositional ages, whereas ages from sandstones are compromised by zircon grains recycled from older strata.
Marcel Guillong, Jörn-Frederik Wotzlaw, Nathan Looser, and Oscar Laurent
Geochronology, 2, 155–167, https://doi.org/10.5194/gchron-2-155-2020, https://doi.org/10.5194/gchron-2-155-2020, 2020
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The dating of carbonates by laser ablation inductively coupled plasma mass spectrometry is improved by an additional, newly characterised reference material and adapted data evaluation protocols: the shape (diameter to depth) of the ablation crater has to be as similar as possible in the reference material used and the unknown samples to avoid an offset. Different carbonates have different ablation rates per laser pulse. With robust uncertainty propagation, precision can be as good as 2–3 %.
Nick M. W. Roberts, Kerstin Drost, Matthew S. A. Horstwood, Daniel J. Condon, David Chew, Henrik Drake, Antoni E. Milodowski, Noah M. McLean, Andrew J. Smye, Richard J. Walker, Richard Haslam, Keith Hodson, Jonathan Imber, Nicolas Beaudoin, and Jack K. Lee
Geochronology, 2, 33–61, https://doi.org/10.5194/gchron-2-33-2020, https://doi.org/10.5194/gchron-2-33-2020, 2020
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Here we review current progress in LA-ICP-MS U–Pb carbonate geochronology and present strategies for acquisition and interpretation of carbonate U–Pb dates. We cover topics from imaging techniques and U and Pb incorporation into calcite to potential limitations of the method – disequilibrium and isotope mobility. We demonstrate the incorporation of imaging and compositional data to help refine and interpret U–Pb dates. We expect this paper to become a
go-toreference paper for years to come.
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Short summary
We characterize three natural carbonate samples with elevated uranium/lead (U/Pb) ratios to demonstrate techniques improving the understanding of U incorporation in carbonates for U/Pb dating. With the rapidly accelerating application of laser ablation analyses, there is a great need for well-characterized reference materials that can serve multiple functions. Strontium (Sr) isotope analyses and U XANES demonstrate that these samples could be used as reference materials.
We characterize three natural carbonate samples with elevated uranium/lead (U/Pb) ratios to...
Special issue