Articles | Volume 6, issue 3
https://doi.org/10.5194/gchron-6-475-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-6-475-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note: Optimizing the in situ cosmogenic 36Cl extraction and measurement workflow for geologic applications
Department of Earth Sciences, University of New Hampshire, Durham, NH 03824, USA
School of Earth and Environmental Sciences, Queens College, CUNY, Flushing, NY 11367, USA
Department of Earth and Environmental Sciences, The Graduate Center, CUNY, New York, NY 10016, USA
Joseph M. Licciardi
Department of Earth Sciences, University of New Hampshire, Durham, NH 03824, USA
Alan J. Hidy
Center for Accelerator Mass Spectrometry, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA
Tyler S. Anderson
Center for Accelerator Mass Spectrometry, Lawrence Livermore National Laboratory, Livermore, CA 94550, USA
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Caleb K. Walcott, Jason P. Briner, James F. Baichtal, Alia J. Lesnek, and Joseph M. Licciardi
Geochronology, 4, 191–211, https://doi.org/10.5194/gchron-4-191-2022, https://doi.org/10.5194/gchron-4-191-2022, 2022
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We present a record of ice retreat from the northern Alexander Archipelago, Alaska. During the last ice age (~ 26 000–19 000 years ago), these islands were covered by the Cordilleran Ice Sheet. We tested whether islands were ice-free during the last ice age for human migrants moving from Asia to the Americas. We found that these islands became ice-free between ~ 15 100 years ago and ~ 16 000 years ago, and thus these islands were not suitable for human habitation during the last ice age.
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This preprint is open for discussion and under review for Geochronology (GChron).
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Collision of cosmic rays with the atmosphere produces rare atoms, including beryllium-10, which falls out in precipitation and binds to soils. Measurements on glacial deposits from the last ice age in Colorado, USA show that millions of beryllium-10 atoms fall on each square centimeter of land each year. The rate of delivery increases with elevation and precipitation, which allowed us to make maps of the beryllium-10 flux for an entire watershed that will be used to measure erosion rates.
Greg Balco, Alan J. Hidy, William T. Struble, and Joshua J. Roering
Geochronology, 6, 71–76, https://doi.org/10.5194/gchron-6-71-2024, https://doi.org/10.5194/gchron-6-71-2024, 2024
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We describe a new method of reconstructing the long-term, pre-observational frequency and/or intensity of wildfires in forested landscapes using trace concentrations of the noble gases helium and neon that are formed in soil mineral grains by cosmic-ray bombardment of the Earth's surface.
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Antarctic permafrost processes are not widely studied or understood in the McMurdo Dry Valleys. Our data show that near-surface permafrost sediments were deposited ~180 000 years ago in Pearse Valley, while in lower Wright Valley sediments are either vertically mixed after deposition or were deposited < 25 000 years ago. Our data also record Taylor Glacier retreat from Pearse Valley ~65 000–74 000 years ago and support antiphase dynamics between alpine glaciers and sea ice in the Ross Sea.
Allie Balter-Kennedy, Joerg M. Schaefer, Roseanne Schwartz, Jennifer L. Lamp, Laura Penrose, Jennifer Middleton, Jean Hanley, Bouchaïb Tibari, Pierre-Henri Blard, Gisela Winckler, Alan J. Hidy, and Greg Balco
Geochronology, 5, 301–321, https://doi.org/10.5194/gchron-5-301-2023, https://doi.org/10.5194/gchron-5-301-2023, 2023
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Cosmogenic nuclides like 10Be are rare isotopes created in rocks exposed at the Earth’s surface and can be used to understand glacier histories and landscape evolution. 10Be is usually measured in the mineral quartz. Here, we show that 10Be can be reliably measured in the mineral pyroxene. We use the measurements to determine exposure ages and understand landscape processes in rocks from Antarctica that do not have quartz, expanding the use of this method to new rock types.
Benjamin J. Stoker, Martin Margold, John C. Gosse, Alan J. Hidy, Alistair J. Monteath, Joseph M. Young, Niall Gandy, Lauren J. Gregoire, Sophie L. Norris, and Duane Froese
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The Laurentide Ice Sheet was the largest ice sheet to grow and disappear in the Northern Hemisphere during the last glaciation. In northwestern Canada, it covered the Mackenzie Valley, blocking the migration of fauna and early humans between North America and Beringia and altering the drainage systems. We reconstruct the timing of ice sheet retreat in this region and the implications for the migration of early humans into North America, the drainage of glacial lakes, and past sea level rise.
Mae Kate Campbell, Paul R. Bierman, Amanda H. Schmidt, Rita Sibello Hernández, Alejandro García-Moya, Lee B. Corbett, Alan J. Hidy, Héctor Cartas Águila, Aniel Guillén Arruebarrena, Greg Balco, David Dethier, and Marc Caffee
Geochronology, 4, 435–453, https://doi.org/10.5194/gchron-4-435-2022, https://doi.org/10.5194/gchron-4-435-2022, 2022
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We used cosmogenic radionuclides in detrital river sediment to measure erosion rates of watersheds in central Cuba; erosion rates are lower than rock dissolution rates in lowland watersheds. Data from two different cosmogenic nuclides suggest that some basins may have a mixed layer deeper than is typically modeled and could have experienced significant burial after or during exposure. We conclude that significant mass loss may occur at depth through chemical weathering processes.
Caleb K. Walcott, Jason P. Briner, James F. Baichtal, Alia J. Lesnek, and Joseph M. Licciardi
Geochronology, 4, 191–211, https://doi.org/10.5194/gchron-4-191-2022, https://doi.org/10.5194/gchron-4-191-2022, 2022
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We present a record of ice retreat from the northern Alexander Archipelago, Alaska. During the last ice age (~ 26 000–19 000 years ago), these islands were covered by the Cordilleran Ice Sheet. We tested whether islands were ice-free during the last ice age for human migrants moving from Asia to the Americas. We found that these islands became ice-free between ~ 15 100 years ago and ~ 16 000 years ago, and thus these islands were not suitable for human habitation during the last ice age.
Leah A. VanLandingham, Eric W. Portenga, Edward C. Lefroy, Amanda H. Schmidt, Paul R. Bierman, and Alan J. Hidy
Geochronology, 4, 153–176, https://doi.org/10.5194/gchron-4-153-2022, https://doi.org/10.5194/gchron-4-153-2022, 2022
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This study presents erosion rates of the George River and seven of its tributaries in northeast Tasmania, Australia. These erosion rates are the first measures of landscape change over millennial timescales for Tasmania. We demonstrate that erosion is closely linked to a topographic rainfall gradient across George River. Our findings may be useful for efforts to restore ecological health to Georges Bay by determining a pre-disturbance level of erosion and sediment delivery to this estuary.
Brendon J. Quirk, Elizabeth Huss, Benjamin J. C. Laabs, Eric Leonard, Joseph Licciardi, Mitchell A. Plummer, and Marc W. Caffee
Clim. Past, 18, 293–312, https://doi.org/10.5194/cp-18-293-2022, https://doi.org/10.5194/cp-18-293-2022, 2022
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Glaciers in the northern Rocky Mountains began retreating 17 000 to 18 000 years ago, after the end of the most recent global ice volume maxima. Climate in the region during this time was likely 10 to 8.5° colder than modern with less than or equal to present amounts of precipitation. Glaciers across the Rockies began retreating at different times but eventually exhibited similar patterns of retreat, suggesting a common mechanism influencing deglaciation.
Sandra M. Braumann, Joerg M. Schaefer, Stephanie M. Neuhuber, Christopher Lüthgens, Alan J. Hidy, and Markus Fiebig
Clim. Past, 17, 2451–2479, https://doi.org/10.5194/cp-17-2451-2021, https://doi.org/10.5194/cp-17-2451-2021, 2021
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Glacier reconstructions provide insights into past climatic conditions and elucidate processes and feedbacks that modulate the climate system both in the past and present. We investigate the transition from the last glacial to the current interglacial and generate beryllium-10 moraine chronologies in glaciated catchments of the eastern European Alps. We find that rapid warming was superimposed by centennial-scale cold phases that appear to have influenced large parts of the Northern Hemisphere.
Cited articles
Anderson, T. S., Hidy, A. J., Boyce, J. W., McCubbin, F. M., Tumey, S., Dudley, J. M., Haney, N. C., Bardoux, G., and Bonifacie, M.: Development towards stable chlorine isotope measurements of astromaterials using the modified Middleton source of an accelerator mass spectrometer, Int. J. Mass Spectrom., 477, 116849, https://doi.org/10.1016/J.IJMS.2022.116849, 2022.
Arnold, M., Merchel, S., Bourlès, D. L., Braucher, R., Benedetti, L., Finkel, R. C., Aumaître, G., Gottdang, A., and Klein, M.: The French accelerator mass spectrometry facility ASTER: improved performance and developments, Nucl. Instrum. Meth. B, 268, 1954–1959, 2010.
Barth, A. M., Marcott, S. A., Licciardi, J. M., and Shakun, J. D.: Deglacial Thinning of the Laurentide Ice Sheet in the Adirondack Mountains, New York, USA, Revealed by 36Cl Exposure Dating, Paleoceanogr. Paleoclimatol., 34, 946–953, https://doi.org/10.1029/2018PA003477, 2019.
Ben-Asher, M., Haviv, I., Crouvi, O., Roering, J. J., and Matmon, A.: The convexity of carbonate hilltops: 36Cl constraints on denudation and chemical weathering rates and implications for hillslope curvature, GSA Bulletin, 133, 1930–1946, https://doi.org/10.1130/B35658.1, 2021.
Benedetti, L., Finkel, R., Papanastassiou, D., King, G., Armijo, R., Ryerson, F., Farber, D., and Flerit, F.: Post-glacial slip history of the Sparta fault (Greece) determined by 36Cl cosmogenic dating: Evidence for non-periodic earthquakes, Geophys. Res. Lett., 29, 87-1–87-4, https://doi.org/10.1029/2001GL014510, 2002.
Eberlein, G. D., Churkin, M., Carter, C., Berg, H. C., and Ovenshine, A. T.: Geology of the Craig quadrangle, Alaska, US Geological Survey, https://doi.org/10.3133/ofr8391, 1983.
Faure, G. and Mensing, T. M.: Isotopes: Principles and Applications, 3rd Edn., John Wiley and Sons, Hoboken, New Jersey, ISBN 978-0-471-38437-3, 2005.
Finkel, R., Arnold, M., Aumaître, G., Benedetti, L., Bourlès, D., Keddadouche, K., and Merchel, S.: Improved 36Cl performance at the ASTER HVE 5 MV accelerator mass spectrometer national facility, Nucl. Instrum. Meth. B, 294, 121–125, 2013.
Gosse, J. C. and Phillips, F. M.: Terrestrial in situ cosmogenic nuclides: Theory and application, Quaternary Sci. Rev., 20, 1475–1560, https://doi.org/10.1016/S0277-3791(00)00171-2, 2001.
Ivy-Ochs, S., Poschinger, A. V., Synal, H.-A., and Maisch, M.: Surface exposure dating of the Flims landslide, Graubünden, Switzerland, Geomorphology, 103, 104–112, 2009.
Kozaci, O., Dolan, J., Finkel, R., and Hartleb, R.: Late Holocene slip rate for the North Anatolian fault, Turkey, from cosmogenic 36Cl geochronology: Implications for the constancy of fault loading and strain release rates, Geology, 35, 867–870, 2007.
Licciardi, J. M. and Pierce, K. L.: History and dynamics of the Greater Yellowstone Glacial System during the last two glaciations, Quaternary Sci. Rev., 200, 1–33, 2018.
Licciardi, J. M., Denoncourt, C. L., and Finkel, R. C.: Cosmogenic 36Cl production rates from Ca spallation in Iceland, Earth Planet. Sc. Lett., 267, 365–377, https://doi.org/10.1016/J.EPSL.2007.11.036, 2008.
Marrero, S. M., Phillips, F. M., Caffee, M. W., and Gosse, J. C.: CRONUS-Earth cosmogenic 36Cl calibration, Quat. Geochronol., 31, 199–219, 2016.
Marrero, S. M., Hein, A. S., Naylor, M., Attal, M., Shanks, R., Winter, K., Woodward, J., Dunning, S., Westoby, M., and Sugden, D.: Controls on subaerial erosion rates in Antarctica, Earth Planet. Sc. Lett., 501, 56–66, https://doi.org/10.1016/J.EPSL.2018.08.018, 2018.
Mitchell, S. G., Matmon, A., Bierman, P. R., Enzel, Y., Caffee, M., and Rizzo, D.: Displacement history of a limestone normal fault scarp, northern Israel, from cosmogenic 36Cl, J. Geophys. Res.-Sol. Ea., 106, 4247–4264, https://doi.org/10.1029/2000JB900373, 2001.
Pánek, T., Lenart, J., Hradecký, J., Hercman, H., Braucher, R., Šilhán, K., and Škarpich, V.: Coastal cliffs, rock-slope failures and Late Quaternary transgressions of the Black Sea along southern Crimea, Quaternary Sci. Rev., 181, 76–92, 2018.
Parmelee, D. E. F., Kyle, P. R., Kurz, M. D., Marrero, S. M., and Phillips, F. M.: A new Holocene eruptive history of Erebus volcano, Antarctica using cosmogenic 3He and 36Cl exposure ages, Quat. Geochronol., 30, 114–131, 2015.
Phillips, F. M., Zreda, M. G., Gosse, J. C., Klein, J., Evenson, E. B., Hall, R. D., Chadwick, O. A., and Sharma, P.: Cosmogenic 36Cl and 10Be ages of Quaternary glacial and fluvial deposits of the Wind River Range, Wyoming, Geol. Soc. Am. Bull., 109, 1453–1463, 1997.
Price, B. N., Stansell, N. D., Fernández, A., Licciardi, J. M., Lesnek, A. J., Muñoz, A., Sorensen, M. K., Jaque Castillo, E., Shutkin, T., Ciocca, I., and Galilea, I.: Chlorine-36 Surface Exposure Dating of Late Holocene Moraines and Glacial Mass Balance Modeling, Monte Sierra Nevada, South-Central Chilean Andes (38° S), Front. Earth Sci., 10, 848652, https://doi.org/10.3389/feart.2022.848652, 2022.
Riehle, J. R., Brew, D. A., and Lanphere, M. A.: Geologic map of the Mount Edgecumbe volcanic field, Kruzof Island, southeastern Alaska, U.S. Geological Survey Miscellaneous Investigations Series Map 1983, 1 sheet, scale 1:63, 360, 1989.
Robertson, J., Meschis, M., Roberts, G. P., Ganas, A., and Gheorghiu, D. M.: Temporally constant Quaternary uplift rates and their relationship with extensional upper-plate faults in south Crete (Greece), constrained with 36Cl cosmogenic exposure dating, Tectonics, 38, 1189–1222, 2019.
Schlagenhauf, A., Manighetti, I., Benedetti, L., Gaudemer, Y., Finkel, R., Malavieille, J., and Pou, K.: Earthquake supercycles in Central Italy, inferred from 36Cl exposure dating, Earth Planet. Sc. Lett., 307, 487–500, https://doi.org/10.1016/J.EPSL.2011.05.022, 2011.
Sharma, P., Kubik, P. W., Fehn, U., Gove, H. E., Nishiizumi, K., and Elmore, D.: Development of 36Cl standards for AMS, Nucl. Instrum. Meth. B, 52, 410–415, https://doi.org/10.1016/0168-583X(90)90447-3, 1990.
Singer, B. S., Le Mével, H., Licciardi, J. M., Córdova, L., Tikoff, B., Garibaldi, N., Andersen, N. L., Diefenbach, A. K., and Feigl, K. L.: Geomorphic expression of rapid Holocene silicic magma reservoir growth beneath Laguna del Maule, Chile, Sci. Adv., 4, eaat1513, https://doi.org/10.1126/sciadv.aat1513, 2018.
Small, D., Rinterknecht, V., Austin, W. E. N., Bates, R., Benn, D. I., Scourse, J. D., Bourlès, D. L., Hibbert, F. D., and ASTER Team: Implications of 36Cl exposure ages from Skye, northwest Scotland for the timing of ice stream deglaciation and deglacial ice dynamics, Quaternary Sci. Rev., 150, 130–145, 2016.
Stone, J. O.: University of Washington Cosmogenic Isotope Laboratory Procedures, http://depts.washington.edu/cosmolab/chem.shtml (last access: 30 May 2024), 2001.
Stone, J. O., Allan, G. L., Fifield, L. K., and Cresswell, R. G.: Cosmogenic chlorine-36 from calcium spallation, Geochim. Cosmochim. Ac., 60, 679–692, 1996.
Walcott, C. K., Briner, J. P., Baichtal, J. F., Lesnek, A. J., and Licciardi, J. M.: Cosmogenic ages indicate no MIS 2 refugia in the Alexander Archipelago, Alaska, Geochronology, 4, 191–211, https://doi.org/10.5194/gchron-4-191-2022, 2022.
Wilcken, K. M., Freeman, S., Schnabel, C., Binnie, S. A., Xu, S., and Phillips, R. J.: 36Cl accelerator mass spectrometry with a bespoke instrument, Nucl. Instrum. Meth. B, 294, 107–114, 2013.
Zerathe, S., Lebourg, T., Braucher, R., and Bourlès, D.: Mid-Holocene cluster of large-scale landslides revealed in the Southwestern Alps by 36Cl dating. Insight on an Alpine-scale landslide activity, Quaternary Sci. Rev., 90, 106–127, 2014.
Short summary
We present an improved workflow for extracting and measuring chlorine isotopes in rocks and minerals. Experiments on seven geologic samples demonstrate that our workflow provides reliable results while offering several distinct advantages over traditional methods. Most notably, our workflow reduces the amount of isotopically enriched chlorine spike used per rock sample by up to 95 %, which will allow researchers to analyze more samples using their existing laboratory supplies.
We present an improved workflow for extracting and measuring chlorine isotopes in rocks and...