Articles | Volume 6, issue 3
https://doi.org/10.5194/gchron-6-475-2024
https://doi.org/10.5194/gchron-6-475-2024
Short communication/technical note
 | 
12 Aug 2024
Short communication/technical note |  | 12 Aug 2024

Technical note: Optimizing the in situ cosmogenic 36Cl extraction and measurement workflow for geologic applications

Alia J. Lesnek, Joseph M. Licciardi, Alan J. Hidy, and Tyler S. Anderson

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Cited articles

Anderson, T. S., Hidy, A. J., Boyce, J. W., McCubbin, F. M., Tumey, S., Dudley, J. M., Haney, N. C., Bardoux, G., and Bonifacie, M.: Development towards stable chlorine isotope measurements of astromaterials using the modified Middleton source of an accelerator mass spectrometer, Int. J. Mass Spectrom., 477, 116849, https://doi.org/10.1016/J.IJMS.2022.116849, 2022. 
Arnold, M., Merchel, S., Bourlès, D. L., Braucher, R., Benedetti, L., Finkel, R. C., Aumaître, G., Gottdang, A., and Klein, M.: The French accelerator mass spectrometry facility ASTER: improved performance and developments, Nucl. Instrum. Meth. B, 268, 1954–1959, 2010. 
Barth, A. M., Marcott, S. A., Licciardi, J. M., and Shakun, J. D.: Deglacial Thinning of the Laurentide Ice Sheet in the Adirondack Mountains, New York, USA, Revealed by 36Cl Exposure Dating, Paleoceanogr. Paleoclimatol., 34, 946–953, https://doi.org/10.1029/2018PA003477, 2019. 
Ben-Asher, M., Haviv, I., Crouvi, O., Roering, J. J., and Matmon, A.: The convexity of carbonate hilltops: 36Cl constraints on denudation and chemical weathering rates and implications for hillslope curvature, GSA Bulletin, 133, 1930–1946, https://doi.org/10.1130/B35658.1, 2021. 
Benedetti, L., Finkel, R., Papanastassiou, D., King, G., Armijo, R., Ryerson, F., Farber, D., and Flerit, F.: Post-glacial slip history of the Sparta fault (Greece) determined by 36Cl cosmogenic dating: Evidence for non-periodic earthquakes, Geophys. Res. Lett., 29, 87-1–87-4, https://doi.org/10.1029/2001GL014510, 2002. 
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Short summary
We present an improved workflow for extracting and measuring chlorine isotopes in rocks and minerals. Experiments on seven geologic samples demonstrate that our workflow provides reliable results while offering several distinct advantages over traditional methods. Most notably, our workflow reduces the amount of isotopically enriched chlorine spike used per rock sample by up to 95 %, which will allow researchers to analyze more samples using their existing laboratory supplies.