Articles | Volume 4, issue 2
https://doi.org/10.5194/gchron-4-601-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-4-601-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Sep 2022
Research article |
| 06 Sep 2022
In situ LA-ICPMS U–Pb dating of sulfates: applicability of carbonate reference materials as matrix-matched standards
Aratz Beranoaguirre
CORRESPONDING AUTHOR
Institut für Angewandte Geowissenschaften, Karlsruher Institut für Technologie, Adenauerring 20b, 76131 Karlsruhe, Germany
Institut für Geowissenschaften, Goethe-Universität Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-Universität Frankfurt, 60438 Frankfurt am Main, Germany
Geologia Saila, Euskal Herriko Unibertsitatea UPV/EHU, Sarriena z/g, 48940 Leioa, Spain
Iuliana Vasiliev
Senckenberg Biodiversity and Climate Research Centre (BiK-F), Senckenberganlage 25, 60325 Frankfurt am Main, Germany
Axel Gerdes
Institut für Geowissenschaften, Goethe-Universität Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
Frankfurt Isotope and Element Research Center (FIERCE), Goethe-Universität Frankfurt, 60438 Frankfurt am Main, Germany
Related authors
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Wout Krijgsman, Iuliana Vasiliev, Anouk Beniest, Timothy Lyons, Johanna Lofi, Gabor Tari, Caroline P. Slomp, Namik Cagatay, Maria Triantaphyllou, Rachel Flecker, Dan Palcu, Cecilia McHugh, Helge Arz, Pierre Henry, Karen Lloyd, Gunay Cifci, Özgür Sipahioglu, Dimitris Sakellariou, and the BlackGate workshop participants
Sci. Dril., 31, 93–110, https://doi.org/10.5194/sd-31-93-2022, https://doi.org/10.5194/sd-31-93-2022, 2022
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BlackGate seeks to MSP drill a transect to study the impact of dramatic hydrologic change in Mediterranean–Black Sea connectivity by recovering the Messinian to Holocene (~ 7 Myr) sedimentary sequence in the North Aegean, Marmara, and Black seas. These archives will reveal hydrographic, biotic, and climatic transitions studied by a broad scientific community spanning the stratigraphic, tectonic, biogeochemical, and microbiological evolution of Earth’s most recent saline and anoxic giant.
Related subject area
Geochronological data analysis/statistics/modelling
Short communication: The Wasserstein distance as a dissimilarity metric for comparing detrital age spectra and other geological distributions
ChronoLorica: introduction of a soil–landscape evolution model combined with geochronometers
Technical note: colab_zirc_dims: a Google Colab-compatible toolset for automated and semi-automated measurement of mineral grains in laser ablation–inductively coupled plasma–mass spectrometry images using deep learning models
Calculation of uncertainty in the (U–Th) ∕ He system
Bayesian age–depth modelling applied to varve and radiometric dating to optimize the transfer of an existing high-resolution chronology to a new composite sediment profile from Holzmaar (West Eifel Volcanic Field, Germany)
Short communication: age2exhume – a MATLAB/Python script to calculate steady-state vertical exhumation rates from thermochronometric ages and application to the Himalaya
U and Th content in magnetite and Al spinel obtained by wet chemistry and laser ablation methods: implication for (U–Th) ∕ He thermochronometer
An algorithm for U–Pb geochronology by secondary ion mass spectrometry
Technical note: Rapid phase identification of apatite and zircon grains for geochronology using X-ray micro-computed tomography
Simulating sedimentary burial cycles – Part 2: Elemental-based multikinetic apatite fission-track interpretation and modelling techniques illustrated using examples from northern Yukon
sandbox – creating and analysing synthetic sediment sections with R
Improving age–depth relationships by using the LANDO (“Linked age and depth modeling”) model ensemble
How many grains are needed for quantifying catchment erosion from tracer thermochronology?
Short communication: Inverse isochron regression for Re–Os, K–Ca and other chronometers
Technical note: Analytical protocols and performance for apatite and zircon (U–Th) ∕ He analysis on quadrupole and magnetic sector mass spectrometer systems between 2007 and 2020
Simulating sedimentary burial cycles – Part 1: Investigating the role of apatite fission track annealing kinetics using synthetic data
The closure temperature(s) of zircon Raman dating
On the treatment of discordant detrital zircon U–Pb data
An evaluation of Deccan Traps eruption rates using geochronologic data
geoChronR – an R package to model, analyze, and visualize age-uncertain data
Development of a multi-method chronology spanning the Last Glacial Interval from Orakei maar lake, Auckland, New Zealand
Robust isochron calculation
Resolving the timescales of magmatic and hydrothermal processes associated with porphyry deposit formation using zircon U–Pb petrochronology
Seasonal deposition processes and chronology of a varved Holocene lake sediment record from Chatyr Kol lake (Kyrgyz Republic)
Unifying the U–Pb and Th–Pb methods: joint isochron regression and common Pb correction
Exploring the advantages and limitations of in situ U–Pb carbonate geochronology using speleothems
Alex Lipp and Pieter Vermeesch
Geochronology, 5, 263–270, https://doi.org/10.5194/gchron-5-263-2023, https://doi.org/10.5194/gchron-5-263-2023, 2023
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We propose using the Wasserstein-2 distance (W2) as an alternative to the widely used Kolmogorov–Smirnov (KS) statistic for analysing distributional data in geochronology. W2 measures the horizontal distance between observations, while KS measures vertical differences in cumulative distributions. Using case studies, we find that W2 is preferable in scenarios where the absolute age differences in observations provide important geological information. W2 has been added to the R package IsoplotR.
W. Marijn van der Meij, Arnaud J. A. M. Temme, Steven A. Binnie, and Tony Reimann
Geochronology, 5, 241–261, https://doi.org/10.5194/gchron-5-241-2023, https://doi.org/10.5194/gchron-5-241-2023, 2023
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We present our model ChronoLorica. We coupled the original Lorica model, which simulates soil and landscape evolution, with a geochronological module that traces cosmogenic nuclide inventories and particle ages through simulations. These properties are often measured in the field to determine rates of landscape change. The coupling enables calibration of the model and the study of how soil, landscapes and geochronometers change under complex boundary conditions such as intensive land management.
Michael C. Sitar and Ryan J. Leary
Geochronology, 5, 109–126, https://doi.org/10.5194/gchron-5-109-2023, https://doi.org/10.5194/gchron-5-109-2023, 2023
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We developed code to automatically and semi-automatically measure dimensions of detrital mineral grains in reflected-light images saved at laser ablation–inductively coupled plasma–mass spectrometry facilities that use Chromium targeting software. Our code uses trained deep learning models to segment grain images with greater accuracy than is achievable using other segmentation techniques. We implement our code in Jupyter notebooks which can also be run online via Google Colab.
Peter E. Martin, James R. Metcalf, and Rebecca M. Flowers
Geochronology, 5, 91–107, https://doi.org/10.5194/gchron-5-91-2023, https://doi.org/10.5194/gchron-5-91-2023, 2023
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There is currently no standardized method of performing uncertainty propagation in the (U–Th) / He system, causing data interpretation difficulties. We present two methods of uncertainty propagation and describe free, open-source software (HeCalc) to apply them. Compilation of real data using only analytical uncertainty as well as 2 % and 5 % uncertainties in FT yields respective median relative date uncertainties of 2.9 %, 3.3 %, and 5.0 % for apatites and 1.7 %, 3.3 %, and 5.0 % for zircons.
Stella Birlo, Wojciech Tylmann, and Bernd Zolitschka
Geochronology, 5, 65–90, https://doi.org/10.5194/gchron-5-65-2023, https://doi.org/10.5194/gchron-5-65-2023, 2023
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Sediment cores from the volcanic lake Holzmaar provide a very precise chronology based on tree-ring-like annual laminations or varves. We statistically combine this varve chronology with radiometric dating and tested three different methods to upgrade the age–depth model. However, only one of the three methods tested improved the dating accuracy considerably. With this work, an overview of different age integration methods is discussed and made available for increased future demands.
Peter van der Beek and Taylor F. Schildgen
Geochronology, 5, 35–49, https://doi.org/10.5194/gchron-5-35-2023, https://doi.org/10.5194/gchron-5-35-2023, 2023
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Thermochronometric data can provide unique insights into the patterns of rock exhumation and the driving mechanisms of landscape evolution. Several well-established thermal models allow for a detailed exploration of how cooling rates evolved in a limited area or along a transect, but more regional analyses have been challenging. We present age2exhume, a thermal model that can be used to rapidly provide a synoptic overview of exhumation rates from large regional thermochronologic datasets.
Marianna Corre, Arnaud Agranier, Martine Lanson, Cécile Gautheron, Fabrice Brunet, and Stéphane Schwartz
Geochronology, 4, 665–681, https://doi.org/10.5194/gchron-4-665-2022, https://doi.org/10.5194/gchron-4-665-2022, 2022
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This study is focused on the accurate measurement of U and Th by wet chemistry and laser ablation methods to improve (U–Th)/He dating of magnetite and spinel. The low U–Th content and the lack of specific U–Th standards significantly limit the accuracy of (U–Th)/He dating. Obtained U–Th results on natural and synthetic magnetite and aluminous spinel samples analyzed by wet chemistry methods and LA-ICP-MS sampling have important implications for the (U–Th)/He method and dates interpretation.
Pieter Vermeesch
Geochronology, 4, 561–576, https://doi.org/10.5194/gchron-4-561-2022, https://doi.org/10.5194/gchron-4-561-2022, 2022
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Secondary ion mass spectrometry (SIMS) is the oldest and most sensitive analytical technique for in situ U–Pb geochronology. This paper introduces a new algorithm for SIMS data reduction that treats data as
compositional data, which means that the relative abundances of 204Pb, 206Pb, 207Pb, and 238Pb are processed within a tetrahedral data space or
simplex. The new method is implemented in an eponymous computer programme that is compatible with the two dominant types of SIMS instruments.
Emily H. G. Cooperdock, Florian Hofmann, Ryley M. C. Tibbetts, Anahi Carrera, Aya Takase, and Aaron J. Celestian
Geochronology, 4, 501–515, https://doi.org/10.5194/gchron-4-501-2022, https://doi.org/10.5194/gchron-4-501-2022, 2022
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Apatite and zircon are the most widely used minerals for dating rocks, but they can be difficult to identify in some crushed rock samples. Incorrect mineral identification results in wasted analytical resources and inaccurate data. We show how X-ray computed tomography can be used to efficiently and accurately distinguish apatite from zircon based on density variations, and provide non-destructive 3D grain-specific size, shape, and inclusion information for improved data quality.
Dale R. Issler, Kalin T. McDannell, Paul B. O'Sullivan, and Larry S. Lane
Geochronology, 4, 373–397, https://doi.org/10.5194/gchron-4-373-2022, https://doi.org/10.5194/gchron-4-373-2022, 2022
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Phanerozoic sedimentary rocks of northern Canada have compositionally heterogeneous detrital apatite with high age dispersion caused by differential thermal annealing. Discrete apatite fission track kinetic populations with variable annealing temperatures are defined using elemental data but are poorly resolved using conventional parameters. Inverse thermal modelling of samples from northern Yukon reveals a record of multiple heating–cooling cycles consistent with geological constraints.
Michael Dietze, Sebastian Kreutzer, Margret C. Fuchs, and Sascha Meszner
Geochronology, 4, 323–338, https://doi.org/10.5194/gchron-4-323-2022, https://doi.org/10.5194/gchron-4-323-2022, 2022
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The R package sandbox is a collection of functions that allow the creation, sampling and analysis of fully virtual sediment sections, like having a virtual twin of real-world deposits. This article introduces the concept, features, and workflows required to use sandbox. It shows how a real-world sediment section can be mapped into the model and subsequently addresses a series of theoretical and practical questions, exploiting the flexibility of the model framework.
Gregor Pfalz, Bernhard Diekmann, Johann-Christoph Freytag, Liudmila Syrykh, Dmitry A. Subetto, and Boris K. Biskaborn
Geochronology, 4, 269–295, https://doi.org/10.5194/gchron-4-269-2022, https://doi.org/10.5194/gchron-4-269-2022, 2022
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We use age–depth modeling systems to understand the relationship between age and depth in lake sediment cores. However, depending on which modeling system we use, the model results may vary. We provide a tool to link different modeling systems in an interactive computational environment and make their results comparable. We demonstrate the power of our tool by highlighting three case studies in which we test our application for single-sediment cores and a collection of multiple sediment cores.
Andrea Madella, Christoph Glotzbach, and Todd A. Ehlers
Geochronology, 4, 177–190, https://doi.org/10.5194/gchron-4-177-2022, https://doi.org/10.5194/gchron-4-177-2022, 2022
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Cooling ages date the time at which minerals cross a certain isotherm on the way up to Earth's surface. Such ages can be measured from bedrock material and river sand. If spatial variations in bedrock ages are known in a river catchment, the spatial distribution of erosion can be inferred from the distribution of the ages measured from the river sand grains. Here we develop a new tool to help such analyses, with particular emphasis on quantifying uncertainties due to sample size.
Yang Li and Pieter Vermeesch
Geochronology, 3, 415–420, https://doi.org/10.5194/gchron-3-415-2021, https://doi.org/10.5194/gchron-3-415-2021, 2021
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A conventional isochron is a straight-line fit to two sets of isotopic ratios, D/d and P/d, where P is the radioactive parent, D is the radiogenic daughter, and d is a second isotope of the daughter element. The slope of this line is proportional to the age of the system. An inverse isochron is a linear fit through d/D and P/D. The horizontal intercept of this line is inversely proportional to the age. The latter approach is preferred when d<D, which is the case in Re–Os and K–Ca geochronology.
Cécile Gautheron, Rosella Pinna-Jamme, Alexis Derycke, Floriane Ahadi, Caroline Sanchez, Frédéric Haurine, Gael Monvoisin, Damien Barbosa, Guillaume Delpech, Joseph Maltese, Philippe Sarda, and Laurent Tassan-Got
Geochronology, 3, 351–370, https://doi.org/10.5194/gchron-3-351-2021, https://doi.org/10.5194/gchron-3-351-2021, 2021
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Apatite and zircon (U–Th) / He thermochronology is now a mainstream tool to reconstruct Earth's evolution through the history of cooling and exhumation over the first dozen kilometers. The geological implications of these data rely on the precision of measurements of He, U, Th, and Sm contents in crystals. This technical note documents the methods for He thermochronology developed at the GEOPS laboratory, Paris-Saclay University, that allow (U–Th) / He data to be obtained with precision.
Kalin T. McDannell and Dale R. Issler
Geochronology, 3, 321–335, https://doi.org/10.5194/gchron-3-321-2021, https://doi.org/10.5194/gchron-3-321-2021, 2021
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We generated a synthetic dataset applying published kinetic models and distinct annealing kinetics for the apatite fission track and (U–Th)/He methods using a predetermined thermal history. We then tested how well the true thermal history could be recovered under different data interpretation schemes and geologic constraint assumptions using the Bayesian QTQt software. Our results demonstrate that multikinetic data increase time–temperature resolution and can constrain complex thermal histories.
Birk Härtel, Raymond Jonckheere, Bastian Wauschkuhn, and Lothar Ratschbacher
Geochronology, 3, 259–272, https://doi.org/10.5194/gchron-3-259-2021, https://doi.org/10.5194/gchron-3-259-2021, 2021
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We carried out thermal annealing experiments between 500 and 1000 °C to determine the closure temperature of radiation-damage annealing in zircon (ZrSiO4). Our results show that the different Raman bands of zircon respond differently to annealing. The repair is highest for the external rotation Raman band near 356.6 cm−1. The closure temperature estimates range from 250 to 370 °C for different bands. The differences in closure temperatures offer the prospect of multi-T zircon Raman dating.
Pieter Vermeesch
Geochronology, 3, 247–257, https://doi.org/10.5194/gchron-3-247-2021, https://doi.org/10.5194/gchron-3-247-2021, 2021
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This paper shows that the current practice of filtering discordant U–Pb data based on the relative difference between the 206Pb/238U and 207Pb/206Pb ages is just one of several possible approaches to the problem and demonstrably not the best one. An alternative approach is to define discordance in terms of isotopic composition, as a log ratio distance between the measurement and the concordia line. Application to real data indicates that this reduces the positive bias of filtered age spectra.
Blair Schoene, Michael P. Eddy, C. Brenhin Keller, and Kyle M. Samperton
Geochronology, 3, 181–198, https://doi.org/10.5194/gchron-3-181-2021, https://doi.org/10.5194/gchron-3-181-2021, 2021
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We compare two published U–Pb and 40Ar / 39Ar geochronologic datasets to produce eruption rate models for the Deccan Traps large igneous province. Applying the same approach to each dataset, the resulting models agree well, but the higher-precision U–Pb dataset results in a more detailed eruption model than the lower-precision 40Ar / 39Ar data. We explore sources of geologic uncertainty and reiterate the importance of systematic uncertainties in comparing U–Pb and 40Ar / 39Ar datasets.
Nicholas P. McKay, Julien Emile-Geay, and Deborah Khider
Geochronology, 3, 149–169, https://doi.org/10.5194/gchron-3-149-2021, https://doi.org/10.5194/gchron-3-149-2021, 2021
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This paper describes geoChronR, an R package that streamlines the process of quantifying age uncertainties, propagating uncertainties through several common analyses, and visualizing the results. In addition to describing the structure and underlying theory of the package, we present five real-world use cases that illustrate common workflows in geoChronR. geoChronR is built on the Linked PaleoData framework, is open and extensible, and we welcome feedback and contributions from the community.
Leonie Peti, Kathryn E. Fitzsimmons, Jenni L. Hopkins, Andreas Nilsson, Toshiyuki Fujioka, David Fink, Charles Mifsud, Marcus Christl, Raimund Muscheler, and Paul C. Augustinus
Geochronology, 2, 367–410, https://doi.org/10.5194/gchron-2-367-2020, https://doi.org/10.5194/gchron-2-367-2020, 2020
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Orakei Basin – a former maar lake in Auckland, New Zealand – provides an outstanding sediment record over the last ca. 130 000 years, but an age model is required to allow the reconstruction of climate change and volcanic eruptions contained in the sequence. To construct a relationship between depth in the sediment core and age of deposition, we combined tephrochronology, radiocarbon dating, luminescence dating, and the relative intensity of the paleomagnetic field in a Bayesian age–depth model.
Roger Powell, Eleanor C. R. Green, Estephany Marillo Sialer, and Jon Woodhead
Geochronology, 2, 325–342, https://doi.org/10.5194/gchron-2-325-2020, https://doi.org/10.5194/gchron-2-325-2020, 2020
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The standard approach to isochron calculation assumes that the distribution of uncertainties on the data arising from isotopic analysis is strictly Gaussian. This excludes datasets that have more scatter, even though many appear to have age significance. Our new approach requires only that the central part of the uncertainty distribution of the data defines a "spine" in the trend of the data. A robust statistics approach is used to locate the spine, and an implementation in Python is given.
Simon J. E. Large, Jörn-Frederik Wotzlaw, Marcel Guillong, Albrecht von Quadt, and Christoph A. Heinrich
Geochronology, 2, 209–230, https://doi.org/10.5194/gchron-2-209-2020, https://doi.org/10.5194/gchron-2-209-2020, 2020
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The integration of zircon geochemistry and U–Pb geochronology (petrochronology) allows us to improve our understanding of magmatic processes. Here we could reconstruct the ~300 kyr evolution of the magma reservoir that sourced the magmas, fluids and metals to form the Batu Hijau porphyry Cu–Au deposit. The application of in situ LA-ICP-MS and high-precision CA–ID–TIMS geochronology to the same zircons further allowed an assessment of the strengths and limitations of the different techniques.
Julia Kalanke, Jens Mingram, Stefan Lauterbach, Ryskul Usubaliev, Rik Tjallingii, and Achim Brauer
Geochronology, 2, 133–154, https://doi.org/10.5194/gchron-2-133-2020, https://doi.org/10.5194/gchron-2-133-2020, 2020
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Our study presents the first seasonally laminated (varved) sediment record covering almost the entire Holocene in high mountainous arid Central Asia. The established floating varve chronology is confirmed by two terrestrial radiocarbon dates, whereby aquatic radiocarbon dates reveal decreasing reservoir ages up core. Changes in seasonal deposition characteristics are attributed to changes in runoff and precipitation and/or to evaporative summer conditions.
Pieter Vermeesch
Geochronology, 2, 119–131, https://doi.org/10.5194/gchron-2-119-2020, https://doi.org/10.5194/gchron-2-119-2020, 2020
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The U–Pb method is one of the most powerful and versatile methods in the geochronological toolbox. With two isotopes of uranium decaying to two different isotopes of lead, the U–Pb method offers an internal quality control that is absent from most other geochronological techniques. U-bearing minerals often contain significant amounts of Th, which decays to a third Pb isotope. This paper presents an algorithm to jointly process all three chronometers at once.
Jon Woodhead and Joseph Petrus
Geochronology, 1, 69–84, https://doi.org/10.5194/gchron-1-69-2019, https://doi.org/10.5194/gchron-1-69-2019, 2019
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Recently developed methods for in situ U–Pb age determination in carbonates have found widespread application, but the benefits and limitations of the method over bulk analysis approaches have yet to be fully explored. Here we use speleothems – cave carbonates such as stalagmites and flowstones – to investigate the utility of these in situ dating methodologies for challenging matrices with low U and Pb contents and predominantly late Cenozoic ages.
Cited articles
Andreetto, F., Matsubara, K., Beets, C. J., Fortuin, A. R., Flecker, R., and
Krijgsman, W.: High Mediterranean water-level during the Lago-Mare
phase of the Messinian Salinity Crisis: insights from the Sr isotope records
of Spanish marginal basins (SE Spain), Paleogeogr. Paleocl., 562, 110139, https://doi.org/10.1016/j.palaeo.2020.110139, 2021.
Astilleros, J. M., Godelitsas, A., Rodríguez-Blanco, J. D.,
Fernández-Díaz, L., Prieto, M., Lagoyannis, A., and Harissopulos, S.: Interaction of gypsum with Pb – bearing aqueous solutions, Appl. Geochem., 25, 1008–1016, https://doi.org/10.1016/j.apgeochem.2010.04.007, 2010.
Babel, M. and Schreiber, B. C.: Geochemistry of evaporites and evolution of
seawater, in: Treatise on Geochemistry, 2nd edn., edited by: Turekian,
K. and Holland, H., Elsevier, Oxford, UK, 483–560, https://doi.org/10.1016/B978-0-08-095975-7.00718-X, 2014.
Brannon, J. C., Cole, S. C., Podosek, F. A., Ragan, V. M., Coveney, R. M.,
Wallace, M. W., and Bradley, A. J.: Th-Pb and U–Pb dating of ore-stage
calcite and Paleozoic fluid flow, Science, 271, 491–493,
https://doi.org/10.1126/science.271.5248.491, 1996.
Burisch, M., Walter, B. F., and Markl, G.: Silicification of Hydrothermal
Gangue Minerals in Pb-Zn-Cu-Fluorite-Quartz-595 Baryte Veins, Can. Mineral., 55, 501–514, https://doi.org/10.3749/canmin.1700005, 2017.
Burisch, M., Gerdes, A., Meinert, L., Albert, R., Seifert, T., and Gutzmer,
J.: The essence of time – fertile skarn formation in the Variscan Orogenic
Belt, Earth Planet. Sc. Lett., 519, 165–170, https://doi.org/10.1016/j.epsl.2019.05.015, 2019.
CIESM: The Messinian salinity crisis from mega-deposits to microbiology, in:
A consensus report. 33ème CIESM Workshop Monographs 33, edited by:
Briand, F., CIESM Publisher, Monaco, 91–96, 2008.
Clauer, N., Chaudhuri, S., Toulkeridis, T., and Blanc, G.: Fluctuations of
Caspian Sea level: beyond climatic variations?, Geology, 28, 1015–1018,
https://doi.org/10.1130/0091-7613(2000)28<1015:FOCSLB>2.0.CO;2, 2000.
Conley, R. F. and Bundy, W. M.: Mechanism of gypsification, Geochim.
Cosmochim. Ac., 15, 57–72, https://doi.org/10.1016/0016-7037(58)90010-3, 1958.
Costanzo, A., Cipriani, M., Feely, M., Cianfione, G., and Dominici, R.:
Messinian twinned selenite from the Catanzaro Trough, Calabria, Southern
Italy: field, petrographic and fluid inclusion perspectives, Carbonate.
Evaporite., 34, 743–756, https://doi.org/10.1007/s13146-019-00516-0, 2019.
Craig, G., Managh A. J., Stremtan, C., Lloyd, N. S., and Horstwood, M. S. A.:
Doubling Sensitivity in Multicollector ICPMS Using High-Efficiency, Rapid
Response Laser Ablation Technology, Anal. Chem., 90, 11564–11571,
https://doi.org/10.1021/acs.analchem.8b02896, 2018.
Craig, G., Bracciali, L., and Lloyd, N.: LA-ICP-MS for U-(Th)-Pb
geochronology: Which analytical capability is right for my laboratory?,
Thermo Fisher Scientific, Smart. Note 30581, 2020.
Cruset, D., Verges, J., Rodrigues, N., Belenguer, J., Pascual-Cebrian, E.,
Almar, Y., Perez-Caceres, I., Macchiavelli, C., Trave, A., Beranoaguirre,
A., Albert, R., Gerdes, A., and Messager, G.: U–Pb dating of carbonate
veins constraining timing of beef growth and oil generation within Vaca
Muerta Formation and compression history in the Neuquen Basin along the
Andean fold and thrust belt, Mar. Petrol. Geol., 132, 10520,
https://doi.org/10.1016/j.marpetgeo.2021.105204, 2021.
Deng, X. D., Li, J. W., Luo, T., and Wang, H. Q.: Dating magmatic and
hydrothermal processes using andradite-rich garnet U–Pb geochronometry,
Contrib. Mineral. Petr., 172, 71, https://doi.org/10.1007/s00410-017-1389-2, 2017.
Elisha, B., Nuriel, P., Kylander-Clark, A., and Weinberger, R.: Towards in situ U–Pb dating of dolomite, Geochronology, 3, 337–349, https://doi.org/10.5194/gchron-3-337-2021, 2021.
Evans, N. P., Turchyn, A. V., Gázquez, F., Bontognali, R. R., Chapman,
H. J., and Hodell, D. A.: Coupled measurements of δ18O and
δD of hydration water and salinity of fluid inclusions in gypsum
from the Messinian Yesares Member, Sorbas Basin (SE Spain), Earth Planet.
Sc. Lett., 430, 499–510, https://doi.org/10.1016/j.epsl.2015.07.071, 2015.
Flecker, R. and Ellam, R. M.: Identifying Late Miocene episodes of
connection and isolation in the Mediterranean–Paratethyan realm using Sr
isotopes, Sediment. Geol., 188–189, 189–203, https://doi.org/10.1016/j.sedgeo.2006.03.005, 2006.
Flecker, R., Krijgsman, W., Capella, W., de Castro Martíns, C.,
Dmitrieva, E., Mayser, J. P., Marzocchi, A., Modestu, S., Lozano, D. O.,
Simon, D., Tulbure, M., van den Berg, B., van der Schee, M., de Lange, G.,
Ellam, R., Govers, R., Gutjahr, M., Hilgen, F., Kouwenhoven, T., Lofi, J.,
Meijer, P., Sierro, F. J., Bachiri, N., Barhoun, N., Alami, A. C., Chacon, B., Flores, Jose A., Gregory, J., Howard, J., Lunt, D., Ochoa, M., Pancost, R., Vincent, S., and Yousfi, M. Z.: Evolution of the Late Miocene Mediterranean Atlantic gateways and their impact on regional and global environmental change, Earth-Sci. Rev., 150, 365–392, https://doi.org/10.1016/j.earscirev.2015.08.007, 2015.
Gerdes, A. and Zeh, A.: Combined U–Pb and Hf isotope LA-(MC-)ICP-MS
analyses of detrital zircons: comparison with SHRIMP and new constraints for
the provenance and age of an Armorican metasediment in Central Germany,
Earth Planet. Sc. Lett., 249, 47–61, https://doi.org/10.1016/j.epsl.2006.06.039, 2006.
Gerdes, A. and Zeh, A.: Zircon formation versus zircon alteration – new
insights from combined U–Pb and Lu-Hf in-situ LA-ICP-MS analyses, and
consequences for the interpretation of Archean zircon from the Central Zone
of the Limpopo Belt, Chem. Geol., 261, 230–243, https://doi.org/10.1016/j.chemgeo.2008.03.005, 2009.
Grandia, F., Asmerom, Y., Getty, S., Cardellach, E., and Canals, A.: U–Pb
dating of MVT ore-stage calcite: implications for fluid flow in a Mesozoic
extensional basin from Iberian Peninsula, J. Geochem. Explor., 69, 377–380, https://doi.org/10.1016/S0375-6742(00)00030-3, 2000.
Grothe, A., Andreetto, F., Reichart, G. J., Wolthers, M., Van Baak, C. G.,
Vasiliev, I., Stoica, M., Sangiorgi, F., Middelburg, J. J., Davies, G. R., and Krijgsman, W.: Paratethys pacing of the Messinian Salinity Crisis: low
salinity waters contributing to gypsum precipitation?, Earth Planet. Sc.
Lett., 532, 116029, https://doi.org/10.1016/j.epsl.2019.116029,
2020.
Guillong, M., Wotzlaw, J.-F., Looser, N., and Laurent, O.: Evaluating the reliability of U–Pb laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) carbonate geochronology: matrix issues and a potential calcite validation reference material, Geochronology, 2, 155–167, https://doi.org/10.5194/gchron-2-155-2020, 2020.
Horstwood, M. S. A., Košler, J., Gehrels, G., Jackson, S. E., McLean, N.
M., Paton, C., Pearson, N. J., Sircombe, K., Sylvester, P., Vermeesch, P.,
and Bowring, J. F.: Community-derived standards for LA-ICP-MS U-(Th-)Pb
geochronology-Uncertainty propagation, age interpretation and data
reporting, Geostand. Geoanal. Res., 40, 311–332, https://doi.org/10.1111/j.1751-908X.2016.00379.x, 2016.
Hsü, K. J., Ryan, W. B. F., and Cita, M. B.: Late Miocene desiccation of the
Mediterranean, Nature, 242, 240–244, https://doi.org/10.1038/242240a0, 1973.
Hsü, K. J., Montadert, L., Ross, D. A., and Neprochnov, Y. P.: Annotated
record of the detailed examination of Mn deposits from DSDP Leg 42 (Holes
372 and 379A), Pangaea [data set], https://doi.org/10.1594/PANGAEA.871889, 1978.
Jochum, K. P., Weis, U., Stoll, B., Kuzmin, D., Yang, Q., Raczek, I., Jacob,
D. E., Stracke, A., Birbaum, K., Frick, D. A., Günther, D., and Enzweiler, J.: Determination of reference values for NIST SRM 610–617 glasses following ISO guidelines, Geostand. Geoanal. Res., 35, 97–429, https://doi.org/10.1111/j.1751-908X.2011.00120.x, 2011.
Kameda, K., Hashimoto, Y., Wang., S.-L., Hirai, Y., and Miyahara, H.:
Simultaneous and continuous stabilization of As and Pb in contaminated
solution and soil by a ferrihydrite-gypsum sorbent, J. Hazard. Mater., 327,
171–179, https://doi.org/10.1016/j.jhazmat.2016.12.039, 2017.
Krijgsman, W., Hilgen, F. J., Raffi, I., Sierro, F. J., and Wilson, D. S.:
Chronology, causes and progression of the Messinian Salinity Crisis, Nature,
400, 652–655, https://doi.org/10.1038/23231, 1999.
Krijgsman, W., Stoica, M., Vasiliev, I., and Popov, V. V.: Rise and fall of
the Paratethys Sea during the Messinian Salinity Crisis, Earth Planet. Sc.
Lett., 290, 183–191, https://doi.org/10.1016/j.epsl.2009.12.020, 2010.
Krijgsman, W., Capella, W., Simon, D., Hilgen, F. J., Kouwenhoven, T. J.,
Meijer, P. T., Sierro, F. J., Tulbure, M. A., van den Berg, B. C. J., van der
Schee, M., and Flecker, R.: The Gibraltar Corridor: watergate of the
Messinian Salinity Crisis, Mar. Geol., 403, 238–246, https://doi.org/10.1016/j.margeo.2018.06.008, 2018.
Laskar, J.: The limits of Earth orbital calculations for geological
time-scale use, in: Astronomical (Milankovitch) Calibration of the
Geological Time-Scale, edited by: Shackleton, N. J., McCave, I. N., and
Graham, P. W., Philos. T. Roy. Soc. A., 357, 1735–1759, https://doi.org/10.1098/rsta.1999.0399, 1999.
Lenoir, L., Blaise, T., Somogyi, A., Brigaud, B., Barbarand, J., Boukari, C., Nouet, J., Brézard-Oudot, A., and Pagel, M.: Uranium incorporation in fluorite and exploration of U–Pb dating, Geochronology, 3, 199–227, https://doi.org/10.5194/gchron-3-199-2021, 2021.
Lin, J., Sun, W., Desmarais, J., Chen, N., Feng, R., Zhang, P., Li, D.,
Lieu, A., Tse, J. S., and Pan, Y.: Uptake and speciation of uranium in
synthetic gypsum (CaSO4⋅ 2H2O): applications to
radioactive mine tailings, J. Environ. Radioactiv., 181, 8–17, https://doi.org/10.1016/j.jenvrad.2017.10.010, 2018.
Liu, D. J. and Hendry, M. J.: Controls on 226Ra during raffinate
neutralization at the Key Lake uranium mill, Saskatchewan, Canada, Appl.
Geochem., 26, 2113–2120, https://doi.org/10.1016/j.apgeochem.2011.07.009, 2011.
Ludwig, K. R.: User's Manual for Isoplot Version 3.75-4.15: a
Geochronological Toolkit for Microsoft Excel, Berkeley Geochronological
Center Special Publication, no. 5, 2012.
Lugli, S., Bassetti, M. A., Manzi, V., Barbieri, M., Longinelli, A., and
Roveri, M.: The Messinian “Vena del Gesso” evaporites revisited:
characterization of isotopic composition and organic matter, J. Geol. Soc.
Lond., 285, 179–190, https://doi.org/10.1144/SP285.11, 2007.
Lugli, S., Manzi, V., Roveri, M., and Schreiber, B. C.: The primary Lower
Gypsum in the Mediterranean: a new facies interpretation for the first stage
of the Messinian salinity crisis, Palaeogeogr. Palaeocl., 297, 83–99, https://doi.org/10.1016/j.palaeo.2010.07.017, 2010.
Mangenot, X., Gasparrini, M., Rouchon, V., and Bonifacie, M.: Basin-scale
thermal and fluid flow histories revealed by carbonate clumped isotopes
(Δ47) – Middle Jurassic carbonates of the Paris Basin depocentre,
Sedimentology, 65, 123–150, https://doi.org/10.1111/sed.12427, 2018.
Manzi, V., Gennari, R., Lugli, S., Roveri, M., and Schreiber, B. C.: The
Messinian “Calcare di Base” (Sicily, Italy) revisited, Geol. Soc. Am. Bull., 123, 347–370, https://doi.org/10.1130/B30262.1, 2011.
Manzi, V., Gennari, R., Hilgen, F., Krijgsman, W., Lugli, S., Roveri, M.,
and Sierro, F. J.: Age refinement of the Messinian salinity crisis onset in
the Mediterranean, Terra Nova, 25, 315–322, https://doi.org/10.1111/ter.12038, 2013.
Manzi, V., Gennari, R., Lugli, S., Persico, D., Reghizzi, M., Roveri, M.,
Schreiber, B. C., Calvo, R., Gavrieli, I., and Gvirtzman, Z.: The onset of
the Messinian salinity crisis in the deep Eastern Mediterranean basin, Terra
Nova, 30, 189–198, https://doi.org/10.1111/ter.12325, 2018.
Meilijson, A., Hilgen, F., Sepúlveda, J., Steinberg, J., Fairbank, V.,
Flecker, R., Waldmann, N. D., Spaulding, S. A., Bialik, O. M., and Boudinot,
F. G.: Chronology with a pinch of salt: integrated stratigraphy of Messinian
evaporites in the deep Eastern Mediterranean reveals long-lasting halite
deposition during Atlantic connectivity, Earth-Sci. Rev., 194, 374–398, https://doi.org/10.1016/j.earscirev.2019.05.011, 2019
Millonig, L. J., Albert, R., Gerdes, A., Avigad, D., and Dietsch, C.:
Exploring laser ablation U–Pb dating of regional metamorphic garnet – The
Straits Schist, Connecticut, USA, Earth Planet. Sc. Lett., 552, 116589,
https://doi.org/10.1016/j.epsl.2020.116589, 2020.
Montano, D., Gasparrini, M., Gerdes, A., Albert, R., Rohais, S., and Della
Porta, G.: In-situ carbonate U–Pb analysis by LA-ICP-MS: From absolute
dating to understanding the U–Pb partitioning in lacustrine systems,
Goldschmidt 2019 Abstracts, Abstract no, 2323, 2019.
Montano, D., Gasparrini, M., Gerdes, A., Della Porta, G., and Albert, R.:
In-situ U–Pb dating of Ries Crater lacustrine carbonates (Miocene,
South-West Germany): implications for continental carbonate
chronostratigraphy, Earth Planet. Sc. Lett., 568, 117011, https://doi.org/10.1016/j.epsl.2021.117011, 2021.
Montano, D., Gasparrini, M., Rohais, S., Albert, R., and Gerdes, A.:
Depositional age models in lacustrine systems from zircon and carbonate U–Pb
geochronology, Sedimentology, in press,
https://doi.org/10.1111/sed.13000, 2022.
Morales, J., Astilleros, J. M., Jiménez, A., Göttlicher, J.,
Steininger, R., and Fernández-Díaz, L.: Uptake of dissolved lead by
anhydrite surfaces, Appl. Geochem., 40, 89–96,
https://doi.org/10.1016/j.apgeochem.2013.11.002, 2014.
Murray, R. C.: Origin and diagenesis of gypsum and anhydrite, SEPM Journal of Sedimentary Research, 34, 512–523,
https://doi.org/10.1306/74D710D2-2B21-11D7-8648000102C1865D, 1964.
Natalicchio, M., Dela Pierre, F., Lugli, S., Lowenstein, T. K., Feiner, S. J., Ferrando, S., Manzi, V., Roveri, M., and Clari, P.: Did Late Miocene
(Messinian) gypsum precipitate from evaporated marine brines? Insights from
the Piedmont Basin (Italy), Geology, 42, 179–182, https://doi.org/10.1130/G34986.1, 2014.
Nuriel, P., Wotzlaw, J.-F., Ovtcharova, M., Vaks, A., Stremtan, C., Šala, M., Roberts, N. M. W., and Kylander-Clark, A. R. C.: The use of ASH-15 flowstone as a matrix-matched reference material for laser-ablation U–Pb geochronology of calcite, Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, 2021.
Ossorio, M., Van Driessche, A. E. S., Pérez, P., and García-Ruiz,
J. M.: The gypsum-anhydrite paradox revisited, Chem. Geol., 386, 16–21, https://doi.org/10.1016/j.chemgeo.2014.07.026, 2014.
Pagel, M., Bonifacie, M., Schneider, D. A., Gautheron, C., Brigaud, B.,
Calmels, D., Cros, A., Saint-Bezar, B., Landrein, P., Sutcliffe, C., and
Davis, D.: Improving paleohydrological and diagenetic reconstructions in
calcite veins and breccia of a sedimentary basin by combining Δ47
temperature, δ18O water and U-Pb age, Chem. Geol., 481, 1–17, https://doi.org/10.1016/j.chemgeo.2017.12.026, 2018.
Parrish, R. R., Parrish, C. M., and Lasalle, S.: Vein calcite dating reveals
Pyrenean orogen as cause of Paleogene deformation in southern England, J.
Geol. Soc., 175, 425–442, https://doi.org/10.1144/jgs2017-107, 2018.
Petrash, D. A., Bialik, O. M., Bontognali, T. R. R., Vasconcelos, C., Roberts, J. A., McKenzie, J. A., and Konhauser, K. O.: Microbially catalyzed dolomite formation: From near-surface to burial, Earth-Sci. Rev., 171, 558–582, https://doi.org/10.1016/j.earscirev.2017.06.015, 2017.
Piccione, G., Rasbury, E. T., Elliott, B. A., Kyle, J. R., Jaret, S. J., Acerbo, A. S., Lanzirotti, A., Northrup, P., Wooton, K., and Parrish, R. R.: Vein fluorite U-Pb dating demonstrates post-6.2 Ma rare-earth element
mobilization associated with Rio Grande rifting, Geosphere, 15, 1958–1972, https://doi.org/10.1130/GES02139.1, 2019.
Rasbury, E. T. and Cole, J. M.: Directly dating geologic events: U-Pb
dating of carbonates, Reviews of Geophysics, 47, RG3001, https://doi.org/10.1029/2007RG000246, 2009.
Ring, U. and Gerdes, A.: Kinematics of the Alpenrhein-Bodensee graben system
in the Central Alps: Oligocene/Miocene transtension due to formation of the
Western Alps arc, Tectonics, 35, 1367–1391, https://doi.org/10.1002/2015TC004085, 2016.
Roberts, N. M. W., Rasbury, E. T., Parrish, R. R., Smith, C. J., Horstwood,
M. S. A., and Condon, D. J.: A calcite reference material for LA-ICP-MS U–Pb
geochronology, Geochem. Geophy. Geosy., 18, 2807–2814, https://doi.org/10.1002/2016GC006784, 2017.
Roberts, N. M. W., Drost, K., Horstwood, M. S. A., Condon, D. J., Chew, D., Drake, H., Milodowski, A. E., McLean, N. M., Smye, A. J., Walker, R. J., Haslam, R., Hodson, K., Imber, J., Beaudoin, N., and Lee, J. K.: Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb carbonate geochronology: strategies, progress, and limitations, Geochronology, 2, 33–61, https://doi.org/10.5194/gchron-2-33-2020, 2020.
Rouchy, J. M. and Caruso, A.: The Messinian salinity crisis in the
Mediterranean basin: a reassessment of the data and an integrated scenario,
Sediment. Geol., 188–189, 35–67, https://doi.org/10.1016/j.sedgeo.2006.02.005, 2006.
Roveri, M., Lugli, S., Manzi, V., and Schreiber, B. C.: The Messinian
Sicilian stratigraphy revisited: toward a new scenario for the Messinian
salinity crisis, Terra Nova, 20, 483–488, https://doi.org/10.1111/j.1365-3121.2008.00842.x, 2008a.
Roveri, M., Bertini, A., Cosentino, D., Di Stefano, A., Gennari, R.,
Gliozzi, E., Grossi, F., Iaccarino, S. M., Lugli, S., Manzi, V., and Taviani,
M.: A high-resolution stratigraphic framework for the latest Messinian
events in the Mediterranean area, Stratigraphy, 5, 323–342, 2008b.
Roveri, M., Flecker, R., Krijgsman, W., Lofi, J., Lugli, S., Manzi, V.,
Sierro, F. J., Bertini, A., Camerlenghi, A., De Lange, G., Govers, R.,
Hilgen, F. J., Hübscher, C., Meijer, P. T., and Stoica, M.: The Messinian
Salinity Crisis: past and future of a great challenge for marine sciences,
Mar. Geol., 352, 25–58, https://doi.org/10.1016/j.margeo.2014.02.002, 2014a.
Roveri, M., Lugli, S., Manzi, V., Gennari, R., and Schreiber, B. C.: High-resolution strontium isotope stratigraphy of the Messinian deep
Mediterranean basins: implications for marginal to central basins
correlation, Mar. Geol., 349, 113–125, https://doi.org/10.1016/j.margeo.2014.01.002, 2014b.
Ryan, W. B.: Decoding the Mediterranean salinity crisis, Sedimentology, 56, 95–136, https://doi.org/10.1111/j.1365-3091.2008.01031.x, 2009.
Schaltegger, U., Schmitt, A. K., and Horstwood, M. S. A.: U–Th–Pb zircon
geochronology by ID-TIMS, SIMS, and laser ablation ICP-MS: Recipes,
interpretations, and opportunities, Chem. Geol., 402, 89–110, https://doi.org/10.1016/j.chemgeo.2015.02.028, 2015.
Selli, R.: Il Messiniano Mayer-Eymar 1867. Proposta di un neostratotipo,
Giornale di Geologia, 28, 1–33, 1960.
Seman, S., Stockli, D. F., and McLean, N. M.: U-Pb geochronology of
grossular-andradite garnet, Chem. Geol., 460, 106–116,
https://doi.org/10.1016/j.chemgeo.2017.04.020, 2017.
Sindern, S., Havenith, V., Gerdes, A., Meyer, F. M., Adelmann, D., and
Hellmann, A.: Dating of anatase-forming diagenetic reactions in Rotliegend
sandstones of the North German Basin, Int. J. Earth Sci., 108, 1275–1292, https://doi.org/10.1007/s00531-019-01705-x, 2019.
Sylvester, P. (Ed.): Matrix effects in Laser ablation-ICP-MS, in: Laser
Ablation-ICP-MS in the Earth Sciences: Current Practices and Outstanding
Issues, Mineralogical association of Canada, 67–78, 2008.
Van Driessche, A. E. S., Stawski, T., and Kellermeier, M.: Calcium sulfate
precipitation pathways in natural and engineering environments, Chem. Geol.,
530, 119274, https://doi.org/10.1016/j.chemgeo.2019.119274, 2019.
Vasiliev, I., Mezger, E. M., Lugli, S., Reichart, G. J., Manzi, V., and
Roveri, M.: How dry was the Mediterranean during the Messinian salinity
crisis?, Paleogeogr. Paleocl., 471, 120–133,
https://doi.org/10.1016/j.palaeo.2017.01.032, 2017.
Wafforn, S., Seman, S., Kyle, J. R., Stockli, D., Leys, C., Sonbait, D., and
Cloos, M.: Andradite garnet U–Pb geochronology of the big Gossan skarn,
Ertsberg-Grasberg mining district, Indonesia, Econ. Geol., 113, 769–778, https://doi.org/10.5382/econgeo.2018.4569, 2018.
Warren, J. K.: Evaporites: A Geological Compendium, Springer, Berlin, https://doi.org/10.1007/978-3-319-13512-0, 2016.
Warthmann, R., van Lith, Y., Vasconcelos, C., McKenzie, J. A., and Karpoff,
A. M.: Bacterially induced dolomite precipitation in anoxic culture
experiments, Geology, 28, 1091–1094, https://doi.org/10.1130/0091-7613(2000)28<1091:BIDPIA>2.0.CO;2, 2000.
Woodhead, J., Hellstrom, J., Maas, R., Drysdale, R., Zanchetta, G., Devine,
P., and Taylor, E.: U–Pb geochronology of speleothems by MC-ICPMS, Quat.
Geochronol., 1, 208–221, https://doi.org/10.1016/j.quageo.2006.08.002, 2006.
Woodhead, J., Hellstrom, J., Pickering, R., Drysdale, R., Paul, B., and
Bajo, P.: U and Pb variability in older speleothems and strategies for their
chronology, Quat. Geochronol., 14, 105–113, https://doi.org/10.1016/j.quageo.2012.02.028, 2012.
Yan, S., Zhou, R. J., Niu, H. C., Feng, Y. X., Nguyen, A. D., Zhao, Z. H., Yang, W. B., Qian, D., and Zhao, J. X.: LA-MC-ICP-MS U–Pb dating of low-U garnets reveals multiple episodes of skarn formation in the volcanic-hosted iron mineralization system, Awulale belt, Central Asia, Geol. Soc. Am. Bull., 132, 1031–1045, https://doi.org/10.1130/B35214.1, 2020.
Yang, Y. H., Wu, F. Y., Yang, J. H., Mitchell, R. H., Zhao, Z. F., Xie, L. W., Huang, C., Ma, Q., Yang, M., and Zhao, H.: U–Pb age determination of
schorlomite garnet by laser ablation inductively coupled plasma mass
spectrometry, J. Anal. Atom. Spectrom., 33, 231–239, https://doi.org/10.1039/c7ja00315c, 2018.
Zachariasse, W. J., van Hinsbergen, D. J. J., and Fortuin, A. R.: Mass wasting and uplift on Crete and Karpathos during the early Pliocene related to initiation of south Aegean left-lateral, strike-slip tectonics, Geol. Soc.
Am. Bull., 120, 976–993, https://doi.org/10.1130/B26175.1, 2008.
Short summary
U–Pb dating by the in situ laser ablation mass spectrometry (LA-ICPMS) technique requires reference materials of the same nature as the samples to be analysed. Here, we have explored the suitability of using carbonate materials as a reference for sulfates, since there is no sulfate reference material. The results we obtained are satisfactory, and thus, from now on, the sulfates can also be analysed.
U–Pb dating by the in situ laser ablation mass spectrometry (LA-ICPMS) technique requires...
