Articles | Volume 6, issue 3
https://doi.org/10.5194/gchron-6-465-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-6-465-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note: RA138 calcite U–Pb LA-ICP-MS primary reference material
Marcel Guillong
CORRESPONDING AUTHOR
Department of Earth and Planetary Sciences, ETH Zürich, 8092 Zurich, Switzerland
Elias Samankassou
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Inigo A. Müller
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
Dawid Szymanowski
Department of Earth and Planetary Sciences, ETH Zürich, 8092 Zurich, Switzerland
Nathan Looser
Department of Earth and Planetary Sciences, ETH Zürich, 8092 Zurich, Switzerland
Lorenzo Tavazzani
Department of Earth and Planetary Sciences, ETH Zürich, 8092 Zurich, Switzerland
Óscar Merino-Tomé
Departamento de Geología, Universidad de Oviedo, Oviedo, Spain
Juan R. Bahamonde
Departamento de Geología, Universidad de Oviedo, Oviedo, Spain
Yannick Buret
Imaging and Analysis Centre, Natural History Museum, London, UK
Maria Ovtcharova
Department of Earth Sciences, University of Geneva, 1205 Geneva, Switzerland
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To improve U-Th zircon dating, we developed a U–Th–Pb double-dating strategy for young zircon (150–300 ka). We found that the overall U-Th age spectrum is consistent whether assuming a constant melt composition or a constant U/Th fractionation between zircon and melt, but testing the representability of the measured glass with the youngest isochron intercept proved essential. A Bayesian model with a uniform prior distribution gave the most accurate estimates of eruption timing for U-Th datasets.
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To improve U-Th zircon dating, we developed a U–Th–Pb double-dating strategy for young zircon (150–300 ka). We found that the overall U-Th age spectrum is consistent whether assuming a constant melt composition or a constant U/Th fractionation between zircon and melt, but testing the representability of the measured glass with the youngest isochron intercept proved essential. A Bayesian model with a uniform prior distribution gave the most accurate estimates of eruption timing for U-Th datasets.
Dawid Szymanowski, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Blair Schoene, Urs Schaltegger, Mark D. Schmitz, Ryan B. Ickert, Cyril Chelle-Michou, Kevin R. Chamberlain, James L. Crowley, Joshua H. F. L. Davies, Michael P. Eddy, Sean P. Gaynor, Alexandra Käßner, Michael T. Mohr, André N. Paul, Jahandar Ramezani, Simon Tapster, Marion Tichomirowa, Albrecht von Quadt, and Corey J. Wall
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We present the first community-wide evaluation of the reproducibility of U–Pb zircon geochronology by isotope dilution thermal ionisation mass spectrometry (ID-TIMS). Eleven labs analysed aliquots of the same, homogenised, pre-spiked solution of natural zircon, which removed geological bias inherent to using heterogeneous natural zircon grain populations. We discuss remaining sources of inter-lab bias and propose areas of improvement to analytical procedures.
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Geochronology, 7, 15–33, https://doi.org/10.5194/gchron-7-15-2025, https://doi.org/10.5194/gchron-7-15-2025, 2025
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We performed a statistical analysis of high-precision U–Pb zircon age distributions. This reveals that volcanic and porphyry zircon age distributions are skewed to younger ages, whereas plutonic age distributions are skewed to older ages. We show that this is caused by truncation of zircon crystallisation by magma evacuation rather than differences in magmatic flux. Our contribution has key implications for modelling of magma dynamics and eruption ages using zircon age distributions.
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Geochronology, 6, 621–638, https://doi.org/10.5194/gchron-6-621-2024, https://doi.org/10.5194/gchron-6-621-2024, 2024
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We present a pioneering method for high-precision U–Pb dating of individual growth zones in zircon. These micrometer zones in single grains can record key geological processes from magma priming prior to eruptions to planetary formation, yet dating them at high precision has so far been technically challenging. Our method employs two cutting-edge microbeam techniques to microsample these growth zones for high-precision dating, allowing us to tackle a number of outstanding research questions.
Alyssa J. McKanna, Blair Schoene, and Dawid Szymanowski
Geochronology, 6, 1–20, https://doi.org/10.5194/gchron-6-1-2024, https://doi.org/10.5194/gchron-6-1-2024, 2024
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Acid leaching is used to remove radiation-damaged portions of zircon crystals prior to U–Pb dating to improve the accuracy of datasets. We test how the temperature and duration of acid leaching affect geochronological and geochemical outcomes. We build a framework that relates radiation damage, zircon solubility, and Pb loss.
Pieter Vermeesch, Yuntao Tian, Jae Schwanethal, and Yannick Buret
Geochronology, 5, 323–332, https://doi.org/10.5194/gchron-5-323-2023, https://doi.org/10.5194/gchron-5-323-2023, 2023
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The U–Th–He method is a technique to determine the cooling history of minerals. Traditional approaches to U–Th–He dating are time-consuming and require handling strong acids and radioactive solutions. This paper presents an alternative approach in which samples are irradiated with protons and subsequently analysed by laser ablation mass spectrometry. Unlike previous in situ U–Th–He dating attempts, the new method does not require any absolute concentration measurements of U, Th, or He.
Giulio Viola, Giovanni Musumeci, Francesco Mazzarini, Lorenzo Tavazzani, Manuel Curzi, Espen Torgersen, Roelant van der Lelij, and Luca Aldega
Solid Earth, 13, 1327–1351, https://doi.org/10.5194/se-13-1327-2022, https://doi.org/10.5194/se-13-1327-2022, 2022
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A structural-geochronological approach helps to unravel the Zuccale Fault's architecture. By mapping its internal structure and dating some of its fault rocks, we constrained a deformation history lasting 20 Myr starting at ca. 22 Ma. Such long activity is recorded by now tightly juxtaposed brittle structural facies, i.e. different types of fault rocks. Our results also have implications on the regional evolution of the northern Apennines, of which the Zuccale Fault is an important structure.
Luca Smeraglia, Nathan Looser, Olivier Fabbri, Flavien Choulet, Marcel Guillong, and Stefano M. Bernasconi
Solid Earth, 12, 2539–2551, https://doi.org/10.5194/se-12-2539-2021, https://doi.org/10.5194/se-12-2539-2021, 2021
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In this paper, we dated fault movements at geological timescales which uplifted the sedimentary successions of the Jura Mountains from below the sea level up to Earth's surface. To do so, we applied the novel technique of U–Pb geochronology on calcite mineralizations that precipitated on fault surfaces during times of tectonic activity. Our results document a time frame of the tectonic evolution of the Jura Mountains and provide new insight into the broad geological history of the Western Alps.
Perach Nuriel, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Anton Vaks, Ciprian Stremtan, Martin Šala, Nick M. W. Roberts, and Andrew R. C. Kylander-Clark
Geochronology, 3, 35–47, https://doi.org/10.5194/gchron-3-35-2021, https://doi.org/10.5194/gchron-3-35-2021, 2021
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This contribution presents a new reference material, ASH-15 flowstone with an age of 2.965 ± 0.011 Ma (95 % CI), to be used for in situ U–Pb dating of carbonate material. The new age analyses include the use of the EARTHTIME isotopic tracers and a large number of sub-samples (n = 37) with small aliquots (1–7 mg) each that are more representative of laser-ablation spot analysis. The new results could improve the propagated uncertainties on the final age with a minimal value of 0.4 %.
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Wu, S. T., Yang, Y. H., Roberts, N. M. W., Yang, M., Wang, H., Lan, Z. W., Xie, B. H., Li, T. Y., Xu, L., Huang, C., Xie, L. W., Yang, J. H., and Wu, F. Y.: In situ calcite U-Pb geochronology by high-sensitivity single-collector LA-SF-ICP-MS, Sci. China-Earth Sci., 65, 1146–1160, https://doi.org/10.1007/s11430-021-9907-1, 2022.
Short summary
RA138 is a new reference material for U–Pb dating of carbonate samples via laser ablation inductively coupled plasma mass spectrometry. RA138 exhibits variable U–Pb ratios and consistent U content, resulting in a precise isochron with low uncertainty. Isotope dilution thermal ionization mass spectrometry analyses fix a reference age of 321.99 ± 0.65 Ma. This research advances our ability to date carbonate samples accurately, providing insights into geological processes and historical timelines.
RA138 is a new reference material for U–Pb dating of carbonate samples via laser ablation...