Articles | Volume 7, issue 3
https://doi.org/10.5194/gchron-7-265-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-7-265-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Aug 2025
Research article |
| 05 Aug 2025
| 05 Aug 2025
The quantification of down-hole fractionation for laser ablation mass spectrometry
Jarred C. Lloyd
CORRESPONDING AUTHOR
Department of Earth Science, The University of Adelaide, Adelaide, Australia
Geological Survey of South Australia, Department for Energy and Mining, Government of South Australia, Adelaide, Australia
Carl Spandler
Department of Earth Science, The University of Adelaide, Adelaide, Australia
Sarah E. Gilbert
Adelaide Microscopy, The University of Adelaide, Adelaide, Australia
Derrick Hasterok
Department of Earth Science, The University of Adelaide, Adelaide, Australia
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Radiometric dating methods, involving laser ablation as the sample introduction, require robust calibrations to reference materials with similar ablation properties to the analysed samples. In the case of the rubidium–strontium dating method, calibrations are often conducted to nano powder with different ablation characteristics than the crystalline minerals. We describe the limitations of this approach and recommend an alternative calibration method involving natural minerals.
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This study presents new methodology for combined in-situ analysis of Rb-Sr and K-Ca in K-rich micas and feldspars. Simultaneous analysis is especially beneficial for small grains and/or detrital minerals where sample material is limited. This technique has the potential for identifying decoupling between the isotope systems, to further understanding of cooling and alteration processes in micas and feldspars, and increase knowledge of element diffusivity in these minerals.
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In this contribution, we demonstrate in situ monazite lutetium–hafnium dating and compare results with uranium–lead dating. We present data from monazite reference materials and complex samples to demonstrate the viability of this method. We show that in situ lutetium–hafnium dating of monazite can resolve multiple age populations and may find use in scenarios where the uranium–lead system has been compromised.
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Radiometric dating methods, involving laser ablation as the sample introduction, require robust calibrations to reference materials with similar ablation properties to the analysed samples. In the case of the rubidium–strontium dating method, calibrations are often conducted to nano powder with different ablation characteristics than the crystalline minerals. We describe the limitations of this approach and recommend an alternative calibration method involving natural minerals.
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Advancements in technology have introduced new techniques to more quickly and cheaply date rocks with little sample preparation. A unique use of this method is to date shales and constrain when these rocks were first deposited. This approach can also time when such sequences were subsequently affected by heat or fluids after they were deposited. This is useful, as the formation of precious-metal-bearing systems or petroleum source rocks is commonly associated with such processes.
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The article demonstrates a new technique that can be used to determine the age of calcite crystallisation using the decay of 176Lu to 176Hf. The technique is novel because (a) Lu–Hf radiometric dating is rarely applied to calcite and (b) this is the first instance where analysis has been conducted by ablating the sample with a laser beam rather than bulk dissolution. By using laser ablation the original context of the sample is preserved.
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Short summary
Laser-based dating of rocks and minerals is invaluable in geoscience. This study significantly advances our ability to model and correct for a process called down-hole fractionation (DHF) that impacts the accuracy and uncertainty of dates. We develop an algorithm that quantitatively models DHF patterns but can be used on other geoscientific data. The implications are far-reaching: improved accuracy, reduced uncertainty, and easier comparisons between different samples and laboratories.
Laser-based dating of rocks and minerals is invaluable in geoscience. This study significantly...
